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Smart Multiple Wetting Control on ZnO Coated Shape Memory Polymer Arrays

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Chemical Research in Chinese Universities Aims and scope

Abstract

Recently, surfaces with intelligent wetting controllability have aroused increased attention. Endowing the surface with stimuli-responsive surface chemistry and tunable surface microstructure can achieve a surface with smart wetting performances. However, almost all existing surfaces only focused on single surface chemistry or micromorphology, thus to achieve smart multiple wetting regulation is still difficult. Herein, we report a ZnO coated shape memory polymer(SMP) surface, and the surface chemistry and micromorphology can be synergistically regulated. ZnO can provide adjustable surface chemistry under UV irradiation, and SMP can offer tunable micromorphology due to its shape memory effect(SME). Based on the combined effect between the above two features, surface wetting performance can be smartly regulated among multiple states. Moreover, due to the excellent controllability of the surface, the application in directional droplet transportation was also demonstrated. This paper offers a new surface with tunability in both surface chemistry and micromorphology, and given the excellent wetting controllability, the surface is believed to be applied in a lot of fields, such as droplet manipulation, fluidic devices and selective catalysis.

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References

  1. Wang S., Liu K., Yao X., Jiang L., Chem. Rev., 2015, 115, 8230

    Article  CAS  Google Scholar 

  2. Lou X., Huang Y., Yang X., Zhu H., Heng L., Xia F., Adv. Funct. Mater., 2020, 30, 1901130

    Article  CAS  Google Scholar 

  3. Cui Z., Wang Y., Liu M., Zhang H., Jiang Z., Chem. Res. Chinese Universities, 2020, 36(6), 1320

    Article  CAS  Google Scholar 

  4. Pan T., Yang K., Han Y., Chem. Res. Chinese Universities, 2020, 36(1), 33

    Article  CAS  Google Scholar 

  5. Wang B., Liang W., Guo Z., Liu W., Chem. Soc. Rev., 2015, 44, 336

    Article  Google Scholar 

  6. Sun M., Feng W., Wang B., Han B., Zou J., Yang C., Liu Z., Chem. Res. Chinese Universities, 2019, 35(4), 700

    Article  CAS  Google Scholar 

  7. Yohe S. T., Colson Y. L., Grinstaff M. W., J. Am. Chem. Soc., 2012, 134, 2016

    Article  CAS  Google Scholar 

  8. Wang L., Zhao Y., Tian Y., Jiang L., Angew. Chem. Int. Ed., 2015, 54, 14732

    Article  CAS  Google Scholar 

  9. Cheng M., Liu Q., Ju G., Zhang Y., Jiang L., Shi F., Adv. Mater., 2014, 26, 306

    Article  CAS  Google Scholar 

  10. Sun T., Wang G., Feng L., Liu B., Ma Y., Jiang L., Zhu D., Angew. Chem. Int. Ed., 2004, 43, 357

    Article  CAS  Google Scholar 

  11. Qu R., Zhang W., Li X., Liu Y., Shih T., Wei Y., Feng L., J. Mater. Chem. A, 2018, 6, 18003

    Article  CAS  Google Scholar 

  12. Zong C., Hu M., Azhar U., Chen X., Zhang Y., Zhang S., Lu C., ACS Appl. Mater. Interfaces, 2019, 11, 25436

    Article  CAS  Google Scholar 

  13. Lim H. S., Lee S. G., Lee D. H., Lee D. Y., Lee S., Cho K., Adv. Mater., 2008, 20, 4438

    Article  CAS  Google Scholar 

  14. Tian D., Zhang N., Zheng X., Hou G., Tian Y., Du Y., Jiang L., Dou S., ACS Nano, 2016, 10, 6220

    Article  CAS  Google Scholar 

  15. Grigoryev A., Tokarev I., Kornev K G., Luzinov I., Minko S., J. Am. Chem. Soc., 2012, 134, 12916

    Article  CAS  Google Scholar 

  16. Gao W., Wang J., Zhang X., Sun L., Chen Y., Zhao Y., Chem. Eng. J., 2020, 381, 122612

    Article  CAS  Google Scholar 

  17. Zhao S., Xia H., Wu D., Lv C., Chen Q., Ariga K., Liu L., Sun H., Soft. Matter., 2013, 9, 4236

    Article  CAS  Google Scholar 

  18. Lee S. G., Lee D. Y., Lim H. S., Lee D. H., Lee S., Cho K., Adv. Mater., 2010, 22, 5013

    Article  CAS  Google Scholar 

  19. Wu D., Wu S., Chen Q., Zhang Y., Yao J., Yao X., Niu L., Wang J., Jiang L., Sun H., Adv. Mater., 2011, 23, 545

    Article  CAS  Google Scholar 

  20. Zhu Y., Antao D. S, Xiao R., Wang E. N., Adv. Mater., 2014, 26, 6442

    Article  CAS  Google Scholar 

  21. Chen C. M., Yang S., Adv. Mater., 2014, 26, 1283

    Article  CAS  Google Scholar 

  22. Zhang D., Cheng Z., Kang H., Yu J., Liu Y., Jiang L., Angew. Chem. Int. Ed., 2018, 57, 3701

    Article  CAS  Google Scholar 

  23. Zhang D., Xia Q., Lai H., Cheng Z., Liu P., Zhang H., Liu Y., Jiang L., Sci. China. Mater., 2021, 64, 1801

    Article  CAS  Google Scholar 

  24. Lv T., Cheng Z., Zhang D., Zhang E., Zhao Q., Liu Y., Jiang L., ACS Nano, 2016, 10, 9379

    Article  CAS  Google Scholar 

  25. Song J., Gao M., Zhao C., Lu Y., Huang L., Liu X., Carmalt C. J., Deng X., Parkin I. P., ACS Nano, 2017, 11, 9259

    Article  CAS  Google Scholar 

  26. Shao Y., Zhao J., Fan Y., Wan Z., Lu L., Zhang Z., Ming W., Ren L., Chem. Eng. J., 2020, 382, 122989

    Article  CAS  Google Scholar 

  27. Huo J., Bai X., Yong J., Fang Y., Yang Q., Hou X., Chen F., Chem. Eng. J., 2021, 414, 128694

    Article  CAS  Google Scholar 

  28. Wang J., Sun L., Zou M., Gao W., Liu C., Shang L., Gu Z., Zhao Y., Sci. Adv., 2017, 3, e1700004

    Article  Google Scholar 

  29. Song Y., Lai H., Jiao X., Cheng Z., Kang H., Zhang D., Fan Z., Xie Z., Wang Y., Liu Y., Adv. Compos. Hybrid. Mater., 2022, 5, 788

    Article  CAS  Google Scholar 

  30. Sun R., Nakajima A., Fujishima A., Watanabe T., Hashimoto K., J. Phys. Chem. B, 2001, 105, 1984

    Article  CAS  Google Scholar 

  31. Xie T., Polymer, 2011, 52, 4985

    Article  CAS  Google Scholar 

  32. Zhao Q., Qi H. J., Xie T., Prog. Polym. Sci., 2015, 49/50, 79

    Article  Google Scholar 

  33. Feng X., Feng L., Jin M., Zhai J., Jiang L., Zhu D., J. Am. Chem. Soc., 2004, 126, 62

    Article  CAS  Google Scholar 

  34. Sun W., Zhou S., You B., Wu L., J. Mater. Chem. A, 2013, 1, 3146

    Article  CAS  Google Scholar 

  35. Xu Q. F., Liu Y., Lin F. J., Mondal B., Lyons A. M., ACS Appl. Mater. Interfaces, 2013, 5, 8915

    Article  CAS  Google Scholar 

  36. Cassie A. B. D., Baxter S., Trans. Faraday. Soc., 1944, 40, 546

    Article  CAS  Google Scholar 

  37. Wenzel R. N., Ind. Eng. Chem., 1936, 28, 988

    Article  CAS  Google Scholar 

  38. Wang, R., Sakai N., Fujishima A., Watanabe T., Hashimoto K., J. Phys. Chem. B, 1999, 103, 2188

    Article  CAS  Google Scholar 

  39. Zubkov T., Stahl D., Thompson T. L., Panayotov D., Diwald O., Yates J. T., J. Phys. Chem. B, 2005, 109, 15454

    Article  CAS  Google Scholar 

  40. Kang H., Liu Y., Lai H., Yu X., Cheng Z., Jiang L., ACS Nano, 2018, 12, 1074

    Article  CAS  Google Scholar 

  41. Hashimoto K., Irir H., Fujishima A., Jpn. J. Appl. Phys., 2005, 44, 8269

    Article  CAS  Google Scholar 

  42. Ju J., Bai H., Zheng Y., Zhao T., Fang R., Jiang L., Nat. Commun., 2012, 3, 1247

    Article  Google Scholar 

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No.22075061) and the Project of the State Key Laboratory of Urban Water Resource and Environment(Harbin Institute of Technology) of China (No.2022TS37).

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Correspondence to Hua Lai or Zhongjun Cheng.

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Wang, X., Wang, B., Lai, H. et al. Smart Multiple Wetting Control on ZnO Coated Shape Memory Polymer Arrays. Chem. Res. Chin. Univ. 39, 151–158 (2023). https://doi.org/10.1007/s40242-022-2265-9

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  • DOI: https://doi.org/10.1007/s40242-022-2265-9

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