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Self-assembly Palladacycle Thiophene Imine Monolayer—Investigating on Catalytic Activity and Mechanism for Coupling Reaction

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Abstract

An ordered cyclopallated thiophene imine self-assembly monolayer(Si@Pd3TI) was designed and fabricated. It was characterized by water contact angle(WCA), ultraviolet-visible spectroscopy(UV), cyclic voltammetry(CV), infrared(IR) spectrum, atomic force microscopy(AFM) and X-ray photoelectron spectroscopy(XPS). Its catalytic performance for Suzuki coupling reaction and catalytic mechanism were systematic investigated. Si@Pd3TI was validated as a heterogeneous catalyst identified by poisoning tests, hot filtration test and three-phase test. The heterogeneous catalytic mechanism was investigated by WCA, UV, Raman spectrum(RS), AFM, XPS and density functional theory(DFT). The catalytic mechanism proceeded via surface-catalysis process, on which the Pd(II)/Pd(I)/Pd(0) synergistic active center acted likely as “multimetallic cluster”. It played a great role for catalyzing coupling reaction, in which the real active species was Pd(I).

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Acknowledgements

The authors gratefully thank Prof. MAO Luyuan(College of Materials Science and Engineering, Zhengzhou University, China) for AFM measurement.

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Author notes

  1. Contributed equally to this work.

Authors and Affiliations

  1. College of Chemistry, Zhengzhou University, Zhengzhou, 450001, P. R. China

    Lun Li, Xiaoxia Xue, Yimeng Sun, Wuduo Zhao, Tiesheng Li & Yangjie Wu

  2. Henan Institute of Advanced Technology, Zhengzhou University, Zhengzhou, 450001, P. R. China

    Yimeng Sun & Minghua Liu

  3. Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China

    Minghua Liu

Authors
  1. Lun Li
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  2. Xiaoxia Xue
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  3. Yimeng Sun
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  4. Wuduo Zhao
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  5. Tiesheng Li
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  6. Minghua Liu
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  7. Yangjie Wu
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Corresponding authors

Correspondence to Tiesheng Li, Minghua Liu or Yangjie Wu.

Additional information

Supported by the National Natural Science Foundation of China(No.21861132002) and the Natural Science Foundation of Henan Province, China(No.192102210046).

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40242_2020_9087_MOESM1_ESM.pdf

Self-assembly Palladacycle Thiophene Imine Monolayer—Investigating on Catalytic Activity and Mechanism for Coupling Reaction

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Li, L., Xue, X., Sun, Y. et al. Self-assembly Palladacycle Thiophene Imine Monolayer—Investigating on Catalytic Activity and Mechanism for Coupling Reaction. Chem. Res. Chin. Univ. 36, 821–828 (2020). https://doi.org/10.1007/s40242-020-9087-4

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  • DOI: https://doi.org/10.1007/s40242-020-9087-4

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