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A Triformylphloroglucinol-based Covalent Organic Polymer: Synthesis, Characterization and Its Application in Visible-light-driven Oxidative Coupling Reactions of Primary Amines

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Abstract

A triformylphloroglucinol-based A3B2-typed covalent organic polymer(TFG-BPTH) was successfully constructed by the condensation reaction of triformylphloroglucinol(TFG) and 2,5-bis(2-propynyloxy)terephthalo-hydrazide(BPTH) under solvothermal conditions. The structure of the TFG-BPTH was confirmed by spectra techniques including FTIR and solid-state 13C CP/MAS NMR spectroscopy. The mophological features of TFG-BPTH were analyzed using scanning electron microscopy(SEM) and transmission electron microscopy(TEM). The TFG-BPTH possessed good thermal and chemical stability, and exhibited good photocatalytic activity as a metal-free heterogeneous catalyst for oxidation of amines to valuable imines under visible light irradiation using O2 as green oxidant. In addition, the catalyst could be readily recovered from the reaction mixture by simple filtration and reused for at least five cycles without any observable change in structure and catalytic activity.

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Xiaodong Li, Qing Su, Ziqian Liu, Kexin Luo & Qiaolin Wu

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, P. R. China

    Guanghua Li

Authors
  1. Xiaodong Li
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  2. Qing Su
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  3. Ziqian Liu
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  4. Kexin Luo
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  5. Guanghua Li
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  6. Qiaolin Wu
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Corresponding authors

Correspondence to Qing Su or Qiaolin Wu.

Additional information

Supported by the National Natural Science Foundation of China(No.51703076).

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40242_2020_8008_MOESM1_ESM.pdf

A Triformylphloroglucinol-based Covalent Organic Polymer: Synthesis, Characterization and Its Application in Visible-light-driven Oxidative Coupling Reactions of Primary Amines

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Li, X., Su, Q., Liu, Z. et al. A Triformylphloroglucinol-based Covalent Organic Polymer: Synthesis, Characterization and Its Application in Visible-light-driven Oxidative Coupling Reactions of Primary Amines. Chem. Res. Chin. Univ. 36, 1017–1023 (2020). https://doi.org/10.1007/s40242-020-8008-x

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  • DOI: https://doi.org/10.1007/s40242-020-8008-x

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