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Benzohydrazide Derivatives: Gelation and Application in Oil Spill Recovery

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Abstract

The synthesis and gelation properties of a series of organogelators containing a benzohydrazide unit and two alkoxy chains(oBn) were reported herein. oBn(n=8, 10, 12) could form stable gels in commercial fuels(e.g., diesel), which were characterized by low critical gelation concentrations(CGCs) and good mechanical properties (G′>105 Pa). The gelation process was further studied by field-emission scanning electron microscopy(FE-SEM), Fourier transform infrared spectroscopy(FTIR) and X-ray diffraction(XRD), etc. It was demonstrated that in these organogels, molecules self-assembled into fibrils 3D-network, where hydrogen bonding, van der Waals force and π-π interaction were confirmed as the driving forces. As compounds oBn(n=8, 10, 12) show very good gelation properties in diesel, their applications in oil spill treatment have also been tested. It was found that oBn could achieve rapid (<30 s) and effective oil removal at room temperature, being good candidates for oil spill treatment in the future. Also, the removal efficiency could be as high as 95%.

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Authors and Affiliations

  1. Key Laboratory for Automobile Materials, Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun, 130012, P. R. China

    Tianren Zhang, Chunxue Zhang, Xiangyang Che, Min Li & Haitao Wang

  2. College of Physics, Jilin University, Changchun, 130012, P. R. China

    Binglian Bai

Authors
  1. Tianren Zhang
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  2. Chunxue Zhang
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  3. Xiangyang Che
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  4. Binglian Bai
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  5. Min Li
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  6. Haitao Wang
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Corresponding authors

Correspondence to Min Li or Haitao Wang.

Additional information

Supported by the Science and Technology Development Programme of Jilin Province, China(No.20170520127JH), the Postdoctoral Science Foundation of China(No.2012T50294) and the Fundamental Research Funds for the Central Universities of China.

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Zhang, T., Zhang, C., Che, X. et al. Benzohydrazide Derivatives: Gelation and Application in Oil Spill Recovery. Chem. Res. Chin. Univ. 35, 874–878 (2019). https://doi.org/10.1007/s40242-019-9089-2

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  • DOI: https://doi.org/10.1007/s40242-019-9089-2

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