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Syntheses, structure and properties of a 3d-4d/2-ptz heterometallic organic chain-modified POM-based framework

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Abstract

A novel polyoxometalate-based hybrid modified by 3d-4d/2-ptz heterometallic organic chains[n-ptz= 5-(n-pyridyl)-tetrazolate], Ag2[Cu(2-ptz)2][β-Mo8O26]0.5·H2O(1)[2-ptz=5-(2-pyridyl)-tetrazolate], was synthesized under hydrothermal conditions. The 3D framework structure of compound 1 was constructed from 1D novel 3d-4d heterometallic organic chains [CuAg2(2-ptz)2]2+ as cationic complexes and [β-Mo8O26]4– polyoxoanions via Cu―O and Ag―O bonds, in which each [β-Mo8O26]4– polyoxoanion was surrounded by six such chains. The electrochemical and photocatalytic properties of compound 1 were investigated.

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Authors and Affiliations

  1. Faculty of Chemistry and Chemical Engineering, Bohai University, Jinzhou, 121000, P. R. China

    Xiang Wang, Lin Lin, Hongyan Lin & Guocheng Liu

Authors
  1. Xiang Wang
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  2. Lin Lin
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  3. Hongyan Lin
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  4. Guocheng Liu
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Corresponding author

Correspondence to Xiang Wang.

Additional information

Supported by the General Program Fund from the Education Department of Liaoning Province, China(No.L2014449).

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Wang, X., Lin, L., Lin, H. et al. Syntheses, structure and properties of a 3d-4d/2-ptz heterometallic organic chain-modified POM-based framework. Chem. Res. Chin. Univ. 33, 7–11 (2017). https://doi.org/10.1007/s40242-017-6293-9

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  • DOI: https://doi.org/10.1007/s40242-017-6293-9

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