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A gas chromatographic stationary of homochiral metal-peptide framework material and its applications

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Abstract

Homochiral metal-organic frameworks(HMOFs) have special properties, such as high surface area, fasci-nating structures and excellent chemical and thermal stability and they have broad application prospects. In this work, we reported the use of HMOF Co-L-GG(L-GG, dipeptide H-Gly-L-Glu) as the stationary phase for separating race-mates in gas chromatography. Co-L-GG coated fused silica capillary column(10 m×250 μm i.d.) was prepared via a dynamic coating method. Thirty racemates belonging to different classes of organic compounds were resolved in-cluding halohydrocarbons, ketones, esters, ethers, organic acids, epoxyalkanes, alcohols and sulfoxides. When com-pared with the previously reported chiral MOFs-coated capillary columns, the Co-L-GG coated column exhibited broader chiral resolution ability towards chiral compounds.

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Authors and Affiliations

  1. Department of Chemistry, Yunnan Normal University, Kunming, 650500, P. R. China

    Lang Li, Shengming Xie, Junhui Zhang, Ling Chen, Pengjing Zhu & Liming Yuan

Authors
  1. Lang Li
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  2. Shengming Xie
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  3. Junhui Zhang
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  4. Ling Chen
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  5. Pengjing Zhu
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  6. Liming Yuan
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Corresponding author

Correspondence to Liming Yuan.

Additional information

Supported by the National Natural Science Foundation of China(No.21275126).

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Li, L., Xie, S., Zhang, J. et al. A gas chromatographic stationary of homochiral metal-peptide framework material and its applications. Chem. Res. Chin. Univ. 33, 24–30 (2017). https://doi.org/10.1007/s40242-017-6270-3

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  • DOI: https://doi.org/10.1007/s40242-017-6270-3

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