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Investigation into experimental conditions and factors for cyclohexane oxidation with VO(acac)2

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Abstract

The catalytic activity of VO(acac)2 for the cyclohexane(Cy) oxidation was studied. The effects of various parameters, such as the amounts of H2O2, HNO3, H2O and Cy were investigated. The highest total turnover number(TON) is 234, which can be increased to 353, 342 and 403, respectively with the adding of o-phthalic, m-phthalic or p-phthalic acid. A reaction mechanism was also supposed primarily.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, P. R. China

    Xitong Ma, Na Xing, Qiong Wu, Liting Xu & Yongheng Xing

Authors
  1. Xitong Ma
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  2. Na Xing
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  3. Qiong Wu
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  4. Liting Xu
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  5. Yongheng Xing
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Corresponding authors

Correspondence to Na Xing or Yongheng Xing.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21306073, 21371086), and the Science and Technology Fund for Outstanding Young Talents in Dalian, China(No.2012J21DW007).

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Ma, X., Xing, N., Wu, Q. et al. Investigation into experimental conditions and factors for cyclohexane oxidation with VO(acac)2 . Chem. Res. Chin. Univ. 30, 991–996 (2014). https://doi.org/10.1007/s40242-014-4188-6

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  • DOI: https://doi.org/10.1007/s40242-014-4188-6

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