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A Green Conversion Coating on a Magnesium Alloy for Corrosion Protection

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Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

A novel coating on the Mg1Mn alloy was produced by anodic polarization combined with hydrothermal treatment (AP + H) in 0.1 M Na2CO3 solution. The microstructure and protection of the coating were evaluated. The coating consisted of MgCO3, Mg(OH)2 and MgO, and provided satisfactory protection in 3.5 wt% NaCl with a corrosion rate of 0.07 mm y−1 in 72 h. However, after that period, the corrosion rate of the specimen increased due to the damage of the coating. The failure of the coating was strongly related to the second phase particles (e.g. Zr particles) or impurities in the matrix. The AP + H coating is supposed to be used as a primer coating for Mg applications in kitchen ware, biomedical areas or industry.

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References

  1. M. Esmaily, J.E. Svensson, S. Fajardo, N. Birbilis, G.S. Frankel, S. Virtanen, R. Arrabal, S. Thomas, L.G. Johansson, Prog. Mater. Sci. 89, 92 (2017)

    Article  CAS  Google Scholar 

  2. T. Zhang, Y. Shao, G. Meng, Z. Cui, F. Wang, Corros. Sci. 53, 1960 (2011)

    Article  CAS  Google Scholar 

  3. L.Y. Chen, J.Q. Xu, H. Choi, M. Pozuelo, X. Ma, S. Bhowmick, J.M. Yang, S. Mathaudhu, X.C. Li, Nature 528, 539 (2015)

    Article  CAS  Google Scholar 

  4. M.S. Song, R.C. Zeng, Y.F. Ding, R.W. Li, M. Easton, I. Cole, N. Birbilis, X.B. Chen, J. Mater. Sci. Technol. 35, 535 (2019)

    Article  CAS  Google Scholar 

  5. P.P. Wu, G.L. Song, Y.X. Zhu, Y.J. Deng, D.J. Zheng, Compos. Pt B -Eng. 243, 110165 (2022)

    Article  CAS  Google Scholar 

  6. J.F. Song, J. She, D.L. Chen, F.S. Pan, J. Magnes, Alloys 8, 1 (2020)

    Article  CAS  Google Scholar 

  7. Z.Z. Yin, W.C. Qi, R.C. Zeng, X.B. Chen, C.D. Gu, S.K. Guan, Y.F. Zheng, J. Magnes, Alloys 8, 42 (2020)

    Article  CAS  Google Scholar 

  8. P. Li, Z. Shao, W. Fu, W. Ma, K. Yang, H. Zhou, M. Gao, Corros. Commun. 9, 44 (2023)

    Article  Google Scholar 

  9. L. Liu, Q. Deng, P. White, S. Dong, I.S. Cole, J. Dong, X.B. Chen, Corros. Commun. 8, 40 (2022)

    Article  Google Scholar 

  10. X. Zhang, Y. Zhang, Y. Lv, Z. Dong, T. Hashimoto, X. Zhou, Corros. Commun. 6, 67 (2022)

    Article  Google Scholar 

  11. A. Zaffora, F. Di Franco, D. Virtù, F. Carfì Pavia, G. Ghersi, S. Virtanen, M. Santamaria, ACS Appl. Mater. Interfaces 13, 12866 (2021)

    Article  CAS  Google Scholar 

  12. J.R. Liu, H. Wang, Q.X. Yuan, X.P. Song, J. Power Sources 395, 8 (2018)

    Article  CAS  Google Scholar 

  13. C. Hu, M.J. Xu, J. Zhang, B.N. Hu, G. Yu, J. Alloy. Compd. 770, 48 (2019)

    Article  CAS  Google Scholar 

  14. X. Wei, P.D. Liu, S.J. Ma, Z.C. Li, X.B. Peng, R.P. Deng, Q. Zhao, Corros. Sci. 173, 108729 (2020)

    Article  CAS  Google Scholar 

  15. X. Wang, C. Jing, Y.X. Chen, X.S. Wang, G. Zhao, X. Zhang, W. Liang, B.Q. Liu, B.Q. Dong, Y.X. Zhang, J. Magnes. Alloy. 8, 291 (2020)

    Article  CAS  Google Scholar 

  16. D.D. Zhang, F. Peng, X.Y. Liu, J. Alloy. Compd. 853, 157010 (2021)

    Article  CAS  Google Scholar 

  17. C. Ke, M.S. Song, R.C. Zeng, Y. Qiu, Y. Zhang, R.F. Zhang, R.L. Liu, I. Cole, N. Birbilis, X.B. Chen, Corros. Sci. 151, 143 (2019)

    Article  CAS  Google Scholar 

  18. D. Merachtsaki, E.C. Tsardaka, E. Anastasiou, A. Zouboulis, Constr. Build. Mater. 312, 125441 (2021)

    Article  CAS  Google Scholar 

  19. S. Pommiers Belin, J. Frayret, A. Uhart, J.B. Ledeuil, J.C. Dupin, A. Castetbon, M. Potin Gautier, Appl. Surf. Sci. 298, 199 (2014)

    Article  CAS  Google Scholar 

  20. M. Ali, M. Elsherif, A.E. Salih, A. Ul-Hamid, M.A. Hussein, S. Park, A.K. Yetisen, H. Butt, J. Alloy. Compd. 825, 154140 (2020)

    Article  CAS  Google Scholar 

  21. S. Pommiers, J. Frayret, A. Castetbon, M. Potin Gautier, Corros Sci. 84, 135 (2014)

    Article  CAS  Google Scholar 

  22. X. Yang, L.H. Liu, M.Z. Zhang, W.F. Tan, G.H. Qiu, L.R. Zheng, J. Hazard. Mater. 374, 26 (2019)

    Article  CAS  Google Scholar 

  23. F. Witte, J. Fischer, J. Nellesen, C. Vogt, J. Vogt, T. Donath, F. Beckmann, Acta Biomater. 6, 1792 (2010)

    Article  CAS  Google Scholar 

  24. R.Y. Zhang, S. Cai, G.H. Xu, H. Zhao, Y. Li, X.X. Wang, K. Huang, M.G. Ren, X.D. Wu, Appl. Surf. Sci. 313, 896 (2014)

    Article  CAS  Google Scholar 

  25. L. Liu, Q.Y. Yang, L. Huang, X.M. Liu, Y.Q. Liang, Z.D. Cui, X.J. Yang, S.L. Zhu, Z.Y. Li, Y.F. Zheng, K.W.K. Yeung, S.L. Wu, Appl. Surf. Sci. 484, 511 (2019)

    Article  CAS  Google Scholar 

  26. R.C. Zeng, X.X. Sun, Y.W. Song, F. Zhang, S.Q. Li, H.Z. Cui, E.H. Han, Trans. Nonferrous Met. Soc. China 23, 3293 (2013)

    Article  CAS  Google Scholar 

  27. K.R. Hallam, P.C. Minshall, P.J. Heard, P.E.J. Flewitt, Corros. Sci. 112, 347 (2016)

    Article  CAS  Google Scholar 

  28. M. Shahabi Navid, M. Esmaily, J.E. Svensson, M. Halvarsson, L. Nyborg, Y. Cao, L.G. Johansson, J. Electrochem. Soc. 161, C277 (2014)

    Article  CAS  Google Scholar 

  29. Y.C. Wang, B.Y. Liu, X.A. Zhao, X.H. Zhang, Y.C. Miao, N. Yang, B. Yang, L.Q. Zhang, W.J. Kuang, J. Li, E. Ma, Z.W. Shan, Nat. Commun. 9, 4058 (2018)

    Article  Google Scholar 

  30. L.C. Li, J.C. Gao, Y. Wang, Surf. Coat. Technol. 185, 92 (2004)

    Article  CAS  Google Scholar 

  31. J.L. Zhang, C.D. Gu, W. Yan, J.P. Tu, X.D. Ding, Surf. Coat. Technol. 344, 702 (2018)

    Article  CAS  Google Scholar 

  32. J.S. Xie, J.H. Zhang, S.J. Liu, Z.H. Li, L. Zhang, R.Z. Wu, L.G. Hou, M.L. Zhang, Coatings 9, 160 (2019)

    Article  Google Scholar 

  33. F. Cao, Z. Shi, G.L. Song, M. Liu, A. Atrens, Corros. Sci. 76, 60 (2013)

    Article  CAS  Google Scholar 

  34. Z. Shi, F. Cao, G.L. Song, M. Liu, A. Atrens, Corros. Sci. 76, 98 (2013)

    Article  CAS  Google Scholar 

  35. S.A. Khan, Y. Miyashita, Y. Mutoh, Z. Bin Sajuri, Mater. Sci. Eng. 420, 315 (2006)

    Article  Google Scholar 

  36. L.N. Zhang, Z.T. Hou, X. Ye, Z.B. Xu, X.L. Bai, P. Shang, Front. Mater. Sci. 7, 227 (2013)

    Google Scholar 

  37. A. Prasad, P.J. Uggowitzer, Z.M. Shi, A. Atrens, Adv. Eng. Mater. 14, 477 (2012)

    Article  CAS  Google Scholar 

  38. Z.M. Shi, A. Atrens, Corros. Sci. 53, 226 (2011)

    Article  CAS  Google Scholar 

  39. F. Cao, C. Zhao, G.L. Song, D. Zheng, Corros. Sci. 150, 161 (2019)

    Article  CAS  Google Scholar 

  40. F. Cao, Z.M. Shi, J. Hofstetter, P.J. Uggowitzer, G.L. Song, M. Liu, A. Atrens, Corros. Sci. 75, 78 (2013)

    Article  CAS  Google Scholar 

  41. P.J. Burke, Z. Bayindir, G.J. Kipouros, Appl. Spectrosc. 66, 510 (2012)

    Article  CAS  Google Scholar 

  42. L. Wang, T. Shinohara, B.P. Zhang, Appl. Surf. Sci. 256, 5807 (2010)

    Article  CAS  Google Scholar 

  43. S. Li, H.A. Khan, L.H. Hihara, H. Cong, J. Li, Corros. Sci. 132, 300 (2018)

    Article  CAS  Google Scholar 

  44. Q.S. Yao, Z.C. Li, Z.M. Qiu, F. Zhang, X.B. Chen, D.C. Chen, S.K. Guan, R.C. Zeng, Rare Met. 38, 629 (2019)

    Article  CAS  Google Scholar 

  45. F. Cao, C. Zhao, J. You, J.J. Hu, D.J. Zheng, G.L. Song, Adv. Eng. Mater. 21, 1900363 (2019)

    Article  Google Scholar 

  46. S. Fajardo, I. Llorente, J.A. Jiménez, J.M. Bastidas, D.M. Bastidas, Corros. Sci. 154, 246 (2019)

    Article  CAS  Google Scholar 

  47. Z. Li, Z. Ba, T. Wang, J. Kuang, Y. Jia, Mater. Res. Express 6, 116440 (2019)

    Article  Google Scholar 

  48. R.C. Zeng, L.J. Liu, T.T. Pang, F. Zhang, W.W. Zhang, S.Q. Li, H.Z. Cui, E.H. Han, Acta Metall. Sin. -Engl. Lett. 28, 373 (2015)

    Article  CAS  Google Scholar 

  49. Y.F. Zhang, S.W. Tang, T.G. Lin, G.Y. Liu, J. Hu, Acta Metall. Sin. -Engl. Lett. 32, 1111 (2019)

    Article  CAS  Google Scholar 

  50. I. Kozina, H. Krawiec, M. Starowicz, M. Kawalec, Int. J. Mol. Sci. 22, 8301 (2021)

    Article  CAS  Google Scholar 

  51. Z.Z. Yin, Z.Q. Zhang, X.J. Tian, Z.L. Wang, R.C. Zeng, Acta Metall. Sin. -Engl. Lett. 34, 25 (2021)

    Article  CAS  Google Scholar 

  52. Y. Shao, R.C. Zeng, S.Q. Li, L.Y. Cui, Y.H. Zou, S.K. Guan, Y.F. Zheng, Acta Metall. Sin. -Engl. Lett. 33, 615 (2020)

    Article  CAS  Google Scholar 

  53. F. Tong, X. Chen, J. Wang, S. Wei, W. Gao, A.C.S. Appl, Energy Mater. 5, 9657 (2022)

    CAS  Google Scholar 

  54. Q.S. Dong, Z.X. Ba, Z.Z. Wang, J. Kuang, Z.Y. Cai, C. Yuan, Acta Metall. Sin. -Engl. Lett. 29, 993 (2016)

    Article  CAS  Google Scholar 

  55. J. Chen, Y. Song, D. Shan, E.H. Han, Corros. Sci. 53, 3281 (2011)

    Article  CAS  Google Scholar 

  56. R. Lindström, L.G. Johansson, G.E. Thompson, P. Skeldon, J.E. Svensson, Corros. Sci. 46, 1141 (2004)

    Article  Google Scholar 

  57. M.C. Zhao, M. Liu, G.L. Song, A. Atrens, Corros. Sci. 50, 3168 (2008)

    Article  CAS  Google Scholar 

  58. H.R. Bakhsheshi Rad, M.H. Idris, M.R. Abdul Kadir, A. Ourdjini, M. Medraj, M. Daroonparvar, E. Hamzah, Mater Des. 53, 283 (2014)

    Article  CAS  Google Scholar 

  59. X.N. Gu, Y.F. Zheng, Front. Mater. Sci. China 4, 111 (2010)

    Article  Google Scholar 

  60. H. Miao, H. Huang, Y. Shi, H. Zhang, J. Pei, G. Yuan, Corros. Sci. 122, 90 (2017)

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 51801168).

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Correspondence to Fuyong Cao.

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Bu, T., Jia, R., Ying, T. et al. A Green Conversion Coating on a Magnesium Alloy for Corrosion Protection. Acta Metall. Sin. (Engl. Lett.) 36, 1630–1648 (2023). https://doi.org/10.1007/s40195-023-01582-z

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