Skip to main content
SpringerLink
Log in

Designing Rules of Laser-Clad High-Entropy Alloy Coatings with Simple Solid Solution Phases

  • Published:
Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

The criteria of process parameters (µ ≤ 4), atomic size difference (ε ≤ 5.8, δ ≤ 11 and α ≤ 2), thermodynamic (− 14.5 ≤ ∆Hmix ≤ 6.5 and Ω ≥ 1.8) in the prediction of the phase stability for laser-clad high-entropy alloy coatings are studied in detail. Besides, the criteria of valence electron concentration (VEC) applied to distinguish the stability of different solid solution phases are as follows: VEC < 7.65 for simple BCC, VEC ≥ 7.65 for simple face-centered cubic (FCC), 7.14 < VEC < 7.78 for dual-phase BCC and FCC. Among them, µ and ε proposed firstly separate the phase stability of laser-clad high-entropy alloy coatings quite precisely. The other modified criteria (δ, α, ∆Hmix, Ω, VEC) are proved to be different from those of the high-entropy alloys synthesized by the traditional casting and smelting processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, Adv. Eng. Mater. 6, 299 (2004)

    CAS  Google Scholar 

  2. A.M. Li, X.Y. Zhang, Acta Metall. Sin. -Engl. Lett. 22, 219 (2019)

    Google Scholar 

  3. Z.M. Li, K.G. Pradeep, Y. Deng, D. Raabe, C.C. Tasan, Nature 534, 227 (2016)

    CAS  Google Scholar 

  4. M. Wang, Z.M. Li, D. Raabe, In-situ Acta Mater. 147, 236 (2018)

    CAS  Google Scholar 

  5. Q.H. Fang, Y. Chen, J. Lia, C. Jiang, B. Liu, Y. Liu, P.K. Liaw, Int. J. Plast. 114, 161 (2019)

    CAS  Google Scholar 

  6. X.L. Shang, Z.J. Wang, Q.F. Wu, J.C. Wang, J.J. Li, Acta Metall. Sin. -Engl. Lett. 32, 41 (2019)

    CAS  Google Scholar 

  7. D.B. Miracle, O.N. Senkov, Acta Mater. 122, 448 (2017)

    CAS  Google Scholar 

  8. E.J. Pickering, N.G. Jones, Int. Mater. Rev. 61, 183 (2016)

    CAS  Google Scholar 

  9. Y.T. Wang, J.B. Li, Y.C. Xin, X.H. Chen, M. Rashad, B. Liu, Y. Liu, Acta Metall. Sin. -Engl. Lett. 32, 932 (2019)

    CAS  Google Scholar 

  10. B. Chanda, J. Das, J. Alloys Compd. 798, 167 (2019)

    CAS  Google Scholar 

  11. D.X. Qiao, H. Jiang, W.N. Jiao, Y.P. Lu, Z.Q. Cao, T.J. Li, Acta Metall. Sin. -Engl. Lett. 32, 925 (2019)

    CAS  Google Scholar 

  12. R.L. Carlyn, S. Mulaine, V. Céline, G. Maryam, Mater. Charact. 151, 310 (2019)

    Google Scholar 

  13. Z.W. Tang, S. Zhang, R.P. Cai, Q. Zhou, H.F. Wang, Metall. Mater. Trans. A 50, 1888 (2019)

    CAS  Google Scholar 

  14. Y.F. Juan, J. Li, Y.Q. Jiang, W.L. Jia, Z.J. Lu, Appl. Surf. Sci. 465, 700 (2019)

    CAS  Google Scholar 

  15. Y.M. Tan, J.S. Li, S.W. Tang, J. Wang, H.C. Kou, J. Alloys Compd. 742, 430 (2018)

    CAS  Google Scholar 

  16. E. Huang, C.M. Lin, J. Juang, Y.J. Chang, Y.W. Chang, C.S. Wu, C.W. Tsai, A.C. Yeh, S.R. Shieh, C.P. Wang, Y.C. Chuang, Y.F. Liao, D. Zhang, T. Huang, T.N. Lam, Y.H. Chen, J. Alloys Compd. 792, 116 (2019)

    CAS  Google Scholar 

  17. C. Xiang, Z.M. Zhang, H.M. Fu, E.H. Han, J.Q. Wang, H.F. Zhang, G.D. Hu, Acta Metall. Sin. -Engl. Lett. 32, 1053 (2019)

    CAS  Google Scholar 

  18. N. Ishizu, J. Kitagawa, Results Phys. 13, 102274 (2019)

    Google Scholar 

  19. Y.Y. Zhao, H.W. Chen, Z.P. Lu, T.G. Nieh, Acta Mater. 147, 184 (2018)

    CAS  Google Scholar 

  20. Y.F. Wang, S.G. Ma, X.H. Chen, J.Y. Shi, Y. Zhang, J.W. Qiao, Acta Metall. Sin. -Engl. Lett. 26, 277 (2019)

    Google Scholar 

  21. B. Kombaiah, K. Jin, H. Bei, P.D. Edmondson, Y. Zhang, Mater. Des. 160, 1208 (2018)

    CAS  Google Scholar 

  22. H. Jones, Proc. Phys. Soc. 49, 250 (2002)

    Google Scholar 

  23. Y. Zhang, Y.J. Zhou, J.P. Lin, G.L. Chen, K.L. Peter, Adv. Eng. Mater. 10, 534 (2008)

    CAS  Google Scholar 

  24. Z.J. Wang, Y.H. Huang, Y. Yang, J.C. Wang, C.T. Liu, Scr. Mater. 94, 28 (2015)

    CAS  Google Scholar 

  25. Z.J. Wang, W.F. Qiu, Y. Yang, C.T. Liu, Intermetallics 64, 63 (2015)

    CAS  Google Scholar 

  26. X. Yang, Y. Zhang, Mater. Chem. Phys. 132, 233 (2012)

    CAS  Google Scholar 

  27. S. Guo, C.T. Liu, Prog. Nat. Sci.: Mater. Int. 21, 433 (2011)

    Google Scholar 

  28. S. Guo, C. Ng, J. Lu, C.T. Liu, J. Appl. Phys. 109, 213 (2011)

    Google Scholar 

  29. M.C. Troparevsky, R.M. James, M. Daene, Y. Wang, R.L. Andrew, M. Stocks, JOM. 67, 2350 (2015)

    CAS  Google Scholar 

  30. W.M. Choi, Y.H. Jo, D.G. Kim, S.S. Sohn, S. Lee, B.J. Lee, J. Phase Equilib. Diffus. 39, 694 (2018)

    CAS  Google Scholar 

  31. W.J. Huang, P. Martin, H.L. Zhuang, Acta Mater. 169, 225 (2019)

    CAS  Google Scholar 

  32. Y. Tian, C.Y. Lu, Y.F. Shen, X.M. Feng, Surf. Interfaces 15, 135 (2019)

    CAS  Google Scholar 

  33. G. Muvvala, D.P. Karmakar, A.K. Nath, Mater. Des. 121, 310 (2017)

    CAS  Google Scholar 

  34. Q.H. Fang, Y. Chen, J. Li, Y.B. Liu, Y. Liu, Phys. B. 550, 112 (2018)

    CAS  Google Scholar 

  35. S. Yin, W.Y. Li, B. Song, X.C. Yan, M. Kuang, Y.X. Xu, K. Wen, R. Lupoia, J. Mater. Sci. Technol. 35, 1003 (2019)

    Google Scholar 

  36. P.V. Kiryukhantsev-Korneev, A.N. Sheveyko, N.V. Shvindina, E.A. Levashov, D.V. Shtansky, Ceram. Int. 44, 7637 (2018)

    CAS  Google Scholar 

  37. X.Q. Liu, H. Cheng, Z.J. Li, H. Wang, F. Chang, W.G. Wang, Q.H. Tang, P.Q. Dai, Vacuum 165, 297 (2019)

    CAS  Google Scholar 

  38. X.F. Li, Y.H. Feng, B. Liu, D.H. Yi, X.H. Yang, W.D. Zhang, G. Chen, Y. Liu, P.K. Bai, J. Alloys Compd. 788, 485 (2019)

    CAS  Google Scholar 

  39. J. Liu, H. Liu, P.J. Chen, J.B. Hao, Surf. Coat. Technol. 361, 63 (2019)

    CAS  Google Scholar 

  40. T. Chen, W.N. Wu, W.P. Li, D.F. Liu, Opt. Laser Technol. 116, 345 (2019)

    CAS  Google Scholar 

  41. B.A. Khamidullin, I.V. Tsivilskiy, A.I. Gorunov, A.K. Gilmutdinov, Surf. Coat. Technol. 364, 430 (2019)

    CAS  Google Scholar 

  42. A. Riquelme, P. Rodrigo, M.D. Escalera-Rodríguez, J. Rams, Opt. Laser. Eng. 78, 165 (2016)

    Google Scholar 

  43. N. Tamanna, R. Crouch, S. Naher, Opt. Laser. Eng. 122, 151 (2019)

    Google Scholar 

  44. M.N. Fesharaki, R.S. Razavi, H.A. Mansouri, H. Jamali, Surf. Coat. Technol. 353, 25 (2018)

    Google Scholar 

  45. S.T. Peng, T. Li, J.L. Zhao, S.P. Lv, G.Z. Tan, M.M. Dong, H.C. Zhang, J. Clean. Prod. 227, 58 (2019)

    Google Scholar 

  46. L. Reddy, S.P. Preston, P.H. Shipway, C. Davis, T. Hussain, Surf. Coat. Technol. 349, 198 (2018)

    CAS  Google Scholar 

  47. Z.I. Mahmoud Ibrahim, A.D.S. Ahmed, T.Y. Kuo, F. Yusof, M. Hamdi, Mater. Chem. Phys. 235, 1 (2019)

    Google Scholar 

  48. C. Zhang, G.J. Chen, P.Q. Dai, Heat Treat. Met. 40, 146 (2015)

    Google Scholar 

  49. M.H. Sha, L. Zhang, J.W. Zhang, N. Li, T.Z. Li, N. Wang, Rare Met. Mater. Eng. 46, 1237 (2017)

    Google Scholar 

  50. R.D. Li, P.D. Niu, T.C. Yuan, P. Cao, C. Chen, K.C. Zhou, J. Alloys Compd. 746, 125 (2018)

    CAS  Google Scholar 

  51. Z.C. Qiu, C.W. Yao, K. Feng, Z.G. Li, P.K. Chu, Int. J. Lightweight Mater. Manuf. 1, 33 (2018)

    Google Scholar 

  52. M. Li, J. Gazquez, A. Borisevich, R. Mishra, K.M. Floresa, Intermetallics 95, 110 (2018)

    CAS  Google Scholar 

  53. C. Zhang, B. Huang, P.Q. Dai, Chin. Surf. Eng. 29, 32 (2016)

    CAS  Google Scholar 

  54. C. Zhang, B.Q. Wu, Q.T. Wang, D.N. Chen, P.Q. Dai, Rare Met. Mater. Eng. 46, 2639 (2017)

    Google Scholar 

  55. C. Zhang, B. Huang, P.Q. Dai, Met. Heat Treat. 41, 82 (2016)

    CAS  Google Scholar 

  56. H. Zhang, W.F. Wu, Y.Z. He, M.X. Li, S. Guo, Appl. Surf. Sci. 363, 543 (2016)

    CAS  Google Scholar 

  57. G.J. Chen, C. Zhang, Q.H. Tang, P.Q. Dai, Rare Met. Mater. Eng. 44, 1418 (2015)

    CAS  Google Scholar 

  58. Y.X. Guo, X.J. Shang, Q.B. Liu, Surf. Coat. Technol. 344, 353 (2018)

    CAS  Google Scholar 

  59. Y. Shon, S.S. Joshi, S. Katakam, R.S. Rajamure, N.B. Dahotre, Mater. Lett. 142, 122 (2015)

    CAS  Google Scholar 

  60. B. Zheng, Y. Jiang, W. Hu, Appl. Laser 36, 18 (2016)

    Google Scholar 

  61. G.H. Meng, X. Lin, H. Xie, C. Wang, S.Q. Wang, X. Ding, J. Alloys Compd. 672, 660 (2016)

    CAS  Google Scholar 

  62. S. Zhang, C.L. Wu, J.Z. Yi, C.H. Zhang, Surf. Coat. Technol. 262, 64 (2015)

    CAS  Google Scholar 

  63. S. Zhang, C.L. Wu, J.Z. Yi, C. Wang, C.H. Zhang, M. Guan, J.Z. Tan, Chin. J. Lasers 41, 97 (2014)

    Google Scholar 

  64. I. Kunce, M. Polanski, J. Bystrzycki, Int. J. Hydrogen Energy. 39, 9904 (2014)

    CAS  Google Scholar 

  65. F. Zhou, Q.B. Liu, B. Zheng, Chin. J. Lasers 43, 58 (2016)

    Google Scholar 

  66. B. Huang, C. Zhang, H. Cheng, Q.H. Tang, H.C. Rao, P.Q. Dai, Chin. Surf. Eng. 27, 82 (2014)

    CAS  Google Scholar 

  67. Z.F. Huang, C. Zhang, Q.H. Tang, P.Q. Dai, B. Wu, Surf. Technol. 42, 9 (2013)

    CAS  Google Scholar 

  68. Z. Chong, G. Chen, P. Dai, Heat Treat. Met. 40, 146 (2015)

    Google Scholar 

  69. R. Ferro, A. Saccone, Physical Metallurgy (North Holland, Amsterdam, 1996)

  70. Z.J. Wang, Y.H. Huang, C.T. Liu, J.J. Li, J.C. Wang, Intermetallics 109, 139 (2019)

    CAS  Google Scholar 

  71. M. Calvo-Dahlborg, S.G.R. Brown, J. Alloys Compd. 724, 353 (2017)

    CAS  Google Scholar 

  72. S.Z. Li, H.R. Zhang, D.B. Dai, G.T. Ding, X. Wei, Y.K. Guo, J. Alloys Compd. 782, 110 (2019)

    CAS  Google Scholar 

  73. M.G. Poletti, L. Battezzati, Acta Mater. 75, 297 (2014)

    CAS  Google Scholar 

  74. X. Gu, Phys. Exp. Colloids 3, 66 (2006)

    Google Scholar 

  75. J.W. Gooch, Relative Standard Deviation (Encyclopedic Dictionary of Polymers, West Yorkshire, 2011).

    Google Scholar 

  76. H. Zho, L.R. Long, Adv. Psychol. Sci. 12, 942 (2004)

    Google Scholar 

  77. T. Egami, Y. Waseda, J. Non-Cryst, Solids 64, 113 (1984)

    CAS  Google Scholar 

  78. L. Vitos, I.A. Abrikosov, B. Johansson, Phys. Rev. Lett. 87, 1 (2001)

    Google Scholar 

  79. T. Uesugi, K. Higashi, Comput. Mater. Sci. 67, 1 (2013)

    CAS  Google Scholar 

  80. A. Takeuchi, A. Inoue, Mater. Sci. Eng. 304, 446 (2001)

    Google Scholar 

  81. A. Takeuchi, A. Inoue, Mater. Trans. 41, 1372 (2000)

    CAS  Google Scholar 

  82. M.M. Ren, B.S. Li, H.Z. Fu, Trans. Nonferrous Met. Soc. China 23, 991 (2013)

    CAS  Google Scholar 

Download references

Acknowledgement

This work was financially supported by the National Natural Science Foundation of China (No. 51627802).

Author information

Authors and Affiliations

  1. Shanghai Key Lab of Advanced High-Temperature Materials and Precision Forming, Shanghai Jiao Tong University, Shanghai, 200240, China

    Yongfei Juan, Jiao Zhang, Yongbing Dai, Qing Dong & Yanfeng Han

Authors
  1. Yongfei Juan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jiao Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yongbing Dai
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Qing Dong
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yanfeng Han
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jiao Zhang.

Additional information

Available online at http://link.springer.com/journal/40195.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Juan, Y., Zhang, J., Dai, Y. et al. Designing Rules of Laser-Clad High-Entropy Alloy Coatings with Simple Solid Solution Phases. Acta Metall. Sin. (Engl. Lett.) 33, 1064–1076 (2020). https://doi.org/10.1007/s40195-020-01040-0

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40195-020-01040-0

Keywords

Search

Navigation