Abstract
Nanocrystalline and amorphous Mg2Ni-type Mg20−x Y x Ni10 (x = 0, 1, 2, 3 and 4) electrode alloys were fabricated using mechanical milling. The effects of the Y content and milling time on the microstructures and electrochemical performances of the alloys were investigated in detail. X-ray diffraction and transmission electron microscopy analyses revealed that the substitution of Y for Mg yields an obvious change in the phase composition and micro morphology of the alloys. When the Y content x ≤ 1, the substitution of Y for Mg does not change the major phase Mg2Ni, but with a further increase in the Y content, the major phase of the alloys transforms into the YMgNi4 + YMg3 phase. A nanocrystalline and amorphous structure can be obtained by mechanical milling, and the amorphisation degree of the alloy visibly increases with increased milling time. Electrochemical measurements indicate that the discharge capacity of the alloys first increases and then decreases with increasing Y content and milling time. The substitution of Y for Mg dramatically ameliorates the cycle stability of the as-milled alloys, and the mechanical milling more or less impairs the cycle stability of the alloys. Furthermore, the high rate discharge ability, electrochemical impedance spectrum, Tafel polarisation curves and potential step measurements indicate that the electrochemical kinetic properties of the as-milled alloys first increase and then decrease with increasing Y content and milling time.
Similar content being viewed by others
References
T. Nejat, S. Şahin, Energy Convers. Manag. 49, 1820 (2008)
H. Wang, A.K. Prasad, S.G. Advani, Int. J. Hydrog. Energy 37, 290 (2012)
H.G. Huang, R. Li, T.W. Liu, L. Chen, D.L. Luo, Acta Metall. Sin. (Engl. Lett.) 23, 446 (2010)
L.Z. Ouyang, Z.J. Cao, H. Wang, J.W. Liu, D.L. Sun, Q.A. Zhang, M. Zhu, J. Alloys Compd. 586, 113 (2014)
A. Ebrahimi-Purkani, S.F. Kashani-Bozorg, J. Alloys Compd. 456, 211 (2008)
L. Schlapbach, A. Züttel, Nature 414, 353 (2001)
L.Z. Ouyang, Z.J. Cao, H. Wang, J.W. Liu, D.L. Sun, Q.A. Zhang, M. Zhu, Int. J. Hydrog. Energy 38, 8881 (2013)
M.Y. Song, Y.J. Kwak, H.S. Shin, S.H. Lee, B.G. Kim, Int. J. Hydrog. Energy 38, 1910 (2013)
M. Anik, I. Akay, S. Topcu, Int. J. Hydrog. Energy 34, 5449 (2009)
L.Z. Ouyang, Z.J. Cao, L.L. Li, H. Wang, J.W. Liu, D. Min, Y.W. Chen, F.M. Xiao, R.H. Tang, M. Zhu, Int. J. Hydrog. Energy 39, 12765 (2014)
Y.H. Jia, S.M. Han, W. Zhang, X. Zhao, P.F. Sun, Y.Q. Liu, H. Shi, J.S. Wang, Int. J. Hydrog. Energy 38, 2352 (2013)
R. Ohara, C.H. Lan, C.S. Hwang, J. Alloys Compd. 580, S368 (2013)
Y. Wang, S.Z. Qiao, X. Wang, Int. J. Hydrog. Energy 33, 1023 (2008)
L. Hima Kumar, B. Viswanathan, S. Srinivasa Murthy, J. Alloys Compd. 461, 72 (2008)
A. Teresiak, A. Gebert, M. Savyak, M. Uhlemann, C. Mickel, N. Mattern, J. Alloys Compd. 398, 156 (2005)
S. Ruggeri, L. Roué, J. Huot, R. Schulz, L. Aymard, J.M. Tarascon, J. Power Sources 112, 547 (2002)
Y.H. Zhang, C. Zhao, T. Yang, H.W. Shang, C. Xu, D.L. Zhao, J. Alloys Compd. 555, 131 (2013)
Y.H. Zhang, C. Li, Y. Cai, F. Hu, Z.C. Liu, S.H. Guo, J. Alloys Compd. 584, 81 (2014)
M. Mezbahul-Islam, M. Medraj, Calphad 33, 478 (2009)
H. Niua, D.O. Northwood, Int. J. Hydrog. Energy 27, 69 (2002)
X.Y. Zhao, Y. Ding, L.Q. Ma, L.Y. Wang, M. Yang, X.D. Shen, Int. J. Hydrog. Energy 33, 6727 (2008)
G. Zheng, B.N. Popov, R.E. White, J. Electrochem. Soc. 142, 2695 (1995)
N. Kuriyama, T. Sakai, H. Miyamura, I. Uehara, H. Ishikawa, T. Iwasaki, J. Alloys Compd. 202, 183 (1993)
W.H. Lai, C.Z. Yu, Battery Bimon. 26, 189 (1996)
E.A. Lass, Int. J. Hydrog. Energy 36, 10787 (2011)
L.Z. Ouyang, Z.J. Cao, L. Yao, H. Wang, J.W. Liu, M. Zhu, Int. J. Hydrog. Energy 39, 13616 (2014)
K. Tanaka, Y. Kanda, M. Furuhashi, K. Saito, K. Kuroda, H. Saka, J. Alloys Compd. 295, 521 (1999)
T. Spassov, L. Lyubenova, U. Köster, M.D. Baró, Mater. Sci. Eng., A 375–377, 794 (2004)
Y.H. Zhang, H.T. Wang, X.P. Dong, W.G. Bu, Z.M. Yuan, G.F. Zhang, Acta Metall. Sin. (Engl. Lett.) 27, 1088 (2014)
N. Cui, B. Luan, H.J. Zhao, H.K. Liu, S.X. Dou, J. Alloys Compd. 233, 236 (1996)
A. Züttel, F. Meli, L. Schtapbach, J. Alloys Compd. 200, 157 (1993)
L. Zaluski, A. Zaluska, J.O. Ström-Olsen, J. Alloys Compd. 253–254, 70 (1997)
C. Lenain, L. Aymard, L. Dupont, J. Tarascon, J. Alloys Compd. 292, 84 (1999)
H.P. Ren, Y.H. Zhang, B.W. Li, D.L. Zhao, S.H. Guo, X.L. Wang, Int. J. Hydrog. Energy 34, 1429 (2009)
M.V. Simičić, M. Zdujić, R. Dimitrijević, L. Nikolić-Bujanović, N.H. Popović, J. Power Sources 158, 730 (2006)
B.V. Ratnakumar, C. Witham, R.C. Bowman Jr, A. Hightower, B. Fultz, J. Electrochem. Soc. 143, 2578 (1996)
F. Feng, J. Han, M. Geng, D.O. Northwood, J. Electroanal. Chem. 487, 111 (2000)
N. Cui, J.L. Luo, Int. J. Hydrog. Energy 24, 37 (1999)
Y.H. Zhang, Z.C. Liu, B.W. Li, Z.H. Ma, S.H. Guo, X.L Wang. Electrochim. Acta 56, 427 (2010)
Acknowledgments
This work was financially supported by the National Natural Science Foundation of China (Nos. 51161015 and 51371094).
Author information
Authors and Affiliations
Corresponding author
Additional information
Available online at http://link.springer.com/journal/40195
Rights and permissions
About this article
Cite this article
Zhang, YH., Yuan, ZM., Yang, T. et al. Properties of Mechanically Milled Nanocrystalline and Amorphous Mg–Y–Ni Electrode Alloys for Ni–MH Batteries. Acta Metall. Sin. (Engl. Lett.) 28, 826–836 (2015). https://doi.org/10.1007/s40195-015-0266-0
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40195-015-0266-0