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Influence of aluminum surface pre-treatments on the bonding mechanisms and mechanical performance of metal-composite single-lap joints

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Abstract

The use of frictional heat for joining thermoplastic-based materials to metals has grown in importance in recent years. Friction spot joining is a relatively new joining technology suitable to join metal-polymer and composite overlap structures. In this work, the influence of various aluminum surface pre-treatments on the bonding mechanisms and mechanical performance of single-lap shear and cross-tensile joints was studied. Mechanical, chemical, and electrochemical pre-treatments were applied to the aluminum surface prior to the joining process. All surface pre-treatments increased the joint strength to some extent, compared with specimens without surface pre-treatments. Some of the treatments (chemical and electrochemical) led to the formation of strong chemical bonding between the aluminum and composite. Phosphoric acid anodizing with additional primer layer showed the best performance in increasing the joint’s strength. The reason was the strong bond formation between the primer layer and the matrix of the composite during the joining cycle. Moreover, the morphology and chemical composition of the aluminum after surface pre-treatments were analyzed in detail to study the correlation between bonding mechanisms and the mechanical performance of the joints. Finally, fracture surface of the joints was analyzed optically and by SEM, demonstrating parts of the composite remained attached to the aluminum after failure.

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References

  1. Mallick PK (2010) Joining for lightweight vehicles. In: Mallick PK (ed) Materials, design and manufacturing for lightweight vehicles. Woodhead Publishing Ltd., Cambridge, pp 275–308

    Chapter  Google Scholar 

  2. Grujicica M, Sellappana V, Omara MA, Seyrb N, Obieglob A, Erdmannc M, Holzleitner J (2008) An overview of the polymer-to-metal direct-adhesion hybrid technologies for load-bearing automotive components. J Mater Process Technol 197(1–3):363–373

    Article  Google Scholar 

  3. Katayama S, Kawahito Y (2008) Laser direct joining of metal and plastic. Scr Mater 59:1247–1250

    Article  Google Scholar 

  4. Mitschang P, Velthuis R, Didi M (2013) Induction spot welding of metal/CFRPC hybrid joints. Adv Eng Mater. doi:10.1002/adem.201200273

  5. Amancio-Filho ST, Bueno C, dos Santos JF, Huber N, Hage E Jr (2011) On the feasibility of friction spot joining in magnesium/fiber-reinforced polymer composite hybrid structures. Mater Sci Eng A 528:3841–3848. doi:10.1016/j.msea.2011.01.085

    Article  Google Scholar 

  6. Amancio-Filho ST, dos Santos JF (2012) Method for joining metal and plastic workpieces. European Patent No. EP2329905B1

  7. Goushegir SM, dos Santos JF, Amancio-Filho ST (2014) Friction spot joining of aluminum AA2024/carbon-fiber reinforced poly(phenylene sulfide) composite single lap joints: microstructure and mechanical performance. Mater Des 54:196–206

    Article  Google Scholar 

  8. Esteves JV, Goushegir SM, dos Santos JF, Canto LB, Hage E Jr, Amancio-Filho ST (2014) Friction spot joining of aluminum AA6181-T4 and carbon fiber-reinforced poly(phenylene sulfide): effects of process parameters on the microstructure and mechanical strength. Mater Des 66(Part B):437–445. doi:10.1016/j.matdes.2014.06.070

    Google Scholar 

  9. Goushegir SM, dos Santos JF, Amancio-Filho ST (2015) Influence of process parameters on mechanical performance of AA2024/CF-PPS friction spot joints. Mater Des 83:431–442

    Article  Google Scholar 

  10. Goushegir SM, Scharnagl N, dos Santos JF, Amancio Filho ST (2015) XPS analysis of the interface between AA2024-T3/CF-PPS friction spot joints. Surf Interface Anal. doi:10.1002/sia.5816

  11. Goushegir SM, dos Santos JF, Amancio Filho ST (2016) Failure and fracture micro-mechanisms in metal-composite single lap joints produced by welding-based joining techniques. Compos Part A 81:121–128

    Article  Google Scholar 

  12. Baldan A (2004) Review adhesively-bonded joints and repairs in metallic alloys, polymers and composite materials: adhesives, adhesion theories and surface pretreatment. J Mater Sci 39:1–49

    Article  Google Scholar 

  13. Creton C (1997) Materials science of pressure-sensitive adhesives. In: Meijer HEH (ed) Materials science and technology, vol 18. Weinheim, Wiley-VCH Verlag, pp 707–741

    Google Scholar 

  14. Gutowski TG (1986) The mechanics of composite deformation during the manufacturing process. Paper presented at the First Conference of Composite Materials, Dayton

  15. Molitor P, Young T (2002) Adhesives bonding of a titanium alloy to a glass fibre reinforced composite material. Int J Adhes Adhes 22(2):101–107

    Article  Google Scholar 

  16. Critchlow GW, Yendall KA, Bahrani D, Quinn A, Andrews F (2006) Strategies for the replacement of chromic acid anodising for the structural bonding of aluminium alloys. Int J Adhes Adhes 26:419–453

    Article  Google Scholar 

  17. Critchlow GW, Brewis DM (1996) Review of surface pretreatments for aluminium alloys. Int J Adhes Adhes 16:255–275

    Article  Google Scholar 

  18. Harris AF, Beevers A (1999) The effects of grit-blasting on surface properties for adhesion. Int J Adhes Adhes 19:445–452

    Article  Google Scholar 

  19. Kinloch AJ, Bishop HE, Smart NR (1982) Surface analysis and bonding of aluminium-magnesium alloys. J Adhes 14(2):105–118

    Article  Google Scholar 

  20. Asgharifar M, Mazar Atabaki M, Kovacevic R (2014) Characterization of the surface topography of arc-treated aluminum alloys by fractal geometry. Manufacturing Letters 2(2):26–29

    Article  Google Scholar 

  21. Chidambaram D, Clayton CR, Halada GP (2006) The role of hexafluorozirconate in the formation of chromate conversion coatings on aluminum alloys. Electrochim Acta 51:2862–2871

    Article  Google Scholar 

  22. Nordlien JH, Walmsley JC, Osterberg H, Nisancioglu K (2002) Formation of a zirconium-titanium based conversion layer on AA 6060 aluminium. Surf Coat Technol 153(1):72–78

    Article  Google Scholar 

  23. Fin N, Dodiuk H, Yaniv AE, Drori L (1987) Oxide treatments of Al 2024 for adhesive bonding-surface characterization. Appl Surf Sci 28:11–33

    Article  Google Scholar 

  24. Yu S, Zhang R, Tang Y, Ma Y, Du W (2013) Composition and performance of nanostructured zirconium titanium conversion coating on aluminum-magnesium alloys. J Nanomater. doi:10.1155/2013/594273

  25. Prolongo SG, del Rosario G, Urena A (2006) Comparative study on the adhesive properties of different epoxy resins. Int J Adhes Adhes 26:125–132

    Article  Google Scholar 

  26. Boutar Y, Naïmi S, Mezlini S, Ali MBS (2016) Effect of surface treatment on the shear strength of aluminium adhesive single-lap joints for automotive applications. Int J Adhes Adhes 67:38–43

    Article  Google Scholar 

  27. Balle F (2009) Ultraschallschweißen von Metall/C-Faser_Kunststoff (CFK) - Verbunden. PhD thesis, University of Kaiserslautern, Kaiserslautern

  28. Dursun T, Soutis C (2014) Recent developments in advanced aircraft aluminium alloys. Mater Des 56:862–871

    Article  Google Scholar 

  29. Wakeman MD, Manson JAE (2006) Cost analysis. In: Long AC (ed) Design and manufacture of textile composites. Woodhead Publishing Ltd., Cambridge

  30. Technical datasheet Corundum, WIWOX GmbH Surface Systems (2009)

  31. Alodine 4850 Sicherheitsdatenblatt gemäß Verordnung (EG) Nr. 1907/2006 (2014). Henkel Co

  32. ASTM D3163-01 (2008) Standard test method for determining strength of adhesively bonded rigid plastic lap-shear joints in shear by tension loading. ASTM International

  33. DIN EN ISO 14272 (2002) Specimen dimensions and procedure for cross tension testing resistance spot and embossed projection welds. DIN

  34. Pocius AV (2012) Adhesion and adhesives technology: an introduction, 3rd edn. Hanser, Munich

    Book  Google Scholar 

  35. Ebnesajjad S (ed) (2011) Handbook of adhesives and surface preparation: technology, applications and manufacturing, 1st edn. William Andrew, Oxford

  36. Hyland MM (2003) Surface chemistry of adhesion to aluminum. In: Totten GE, MacKenzie DS (eds) Handbook of aluminum: alloy production and materials manufacturing, vol 2. Marcel Dekker, New York City

    Google Scholar 

  37. Wenzel RN (1936) Resistance of solid surfaces to wetting by water. Ind Eng Chem 28(8):988–994

    Article  Google Scholar 

  38. Packham DE (1983) The adhesion of polymers to metals: the role of surface topography. In: Mittal KL (ed) Adhesion aspects of polymeric coatings. Plenum Press, New York, pp 19–44

    Chapter  Google Scholar 

  39. Lunder O, Walmsley JC, Mack P, Nisancioglu K (2005) Formation and characterisation of a chromate conversion coating on AA6060 aluminium. Corros Sci 47:1604–1624

    Article  Google Scholar 

  40. Venables JD (1984) Review adhesion and durability of metal-polymer bonds. J Mater Sci 19:2431–2453

    Article  Google Scholar 

  41. Le Coz F, Arurault L, Datas L (2010) Chemical analysis of a single basic cell of porous anodic aluminium oxide templates. Mater Charact 61:283–288

    Article  Google Scholar 

  42. Solomon JS, Hanlin DE (1980) AES and SEM characterization of anodized aluminum alloy adherends for adhesive bonding application. Appl Surf Sci 4:307–323

    Article  Google Scholar 

  43. Treverton JA, Ball J, Johnson D, Vickerman JC, West RH (1990) SSIMS, XPS and microstructural studies of ac-phosphoric acid anodic films on aluminium. Surf Interface Anal 15:369–376

    Article  Google Scholar 

  44. Digby RP, Packham DE (1995) Pretreatment of aluminium: topography, surface chemistry and adhesive bond durability. Int J Adhes Adhes 15:61–71

    Article  Google Scholar 

  45. Hughes AE, MacRae CM, Wilson NC, Tropy A, Muster TH, Glenn AM (2010) Sheet AA2024-T3: a new investigation of microstructure and composition. Surf Interface Anal 42(4):334–338

    Article  Google Scholar 

  46. Gao M, Feng CR, Wei RP (1998) An analytical electron microscopy study of constituent particles in commercial 7075-T6 and 2024-T3 alloys. Metall Mater Trans A 29(4):1145–1151

    Article  Google Scholar 

  47. Boag A, Hughes AE, Wilson NC, Tropy A, MacRae CM, Glenn AM, Muster TH (2009) How complex is the microstructure of AA2024-T3? Corros Sci 51(8):1565–1568

    Article  Google Scholar 

  48. Prolongo SG, Urena A (2009) Effect of surface pre-treatment on the adhesive strength of epoxy–aluminium joints. Int J Adhes Adhes 29(1):23–31

    Article  Google Scholar 

  49. Johnsen BB, Lapique F, Bjorgum A, Walmsley J, Tanem BS, Luksepp T (2004) The effect of pre-bond moisture on epoxy-bonded sulphuric acid anodised aluminium. Int J Adhes Adhes 24:183–191

    Article  Google Scholar 

  50. Sheasby PG, Pinner R, Wernick S (eds) (2001) The surface treatment and finishing of aluminium and its alloys, volume 1. ASM International Materials Park, OH

    Google Scholar 

  51. Davis GD, Sun TS, Ahearn JS, Venables JD (1982) Application of surface behaviour diagrams to the study of hydration of phosphoric acid-anodized aluminium. J Mater Sci 17(6):1807–1818

    Article  Google Scholar 

  52. Baer DR, Clayton CR, Davis GD, Halada GP (eds) (2001) State-of-the-art application of surface and interface analysis methods to environmental material interactions. In Honor of James E. Castle's 65th year. The Electrochemical Society, New Jersey

    Google Scholar 

  53. Kinloch AJ (1987) Adhesion and adhesives: science and technology, First edn. Springer, Cambridge

    Book  Google Scholar 

  54. Bland DJ, Kinloch AJ, Watts JF (2013) The role of the surface pretreatment in the durability of aluminium-alloy structural adhesive joints: mechanisms of failure. J Adhes 89(5):369–397

    Article  Google Scholar 

  55. Rocher JP, Quenisset JM, Naslain R (1989) Wetting improvement of carbon or silicon carbide by aluminium alloys based on a K2ZrF6 surface treatment: application to composite material casting. J Mater Sci 24(8):2697–2703

    Article  Google Scholar 

  56. Schamm S, Fedou R, Rocher JP, Quenisset JM, Naslain R (1991) The K2ZrF6 wetting process: effect of surface chemistry on the ability of a SiC-fiber preform to be impregnated by aluminum. Metall Trans A 22(9):2133–2139

    Article  Google Scholar 

  57. Kinloch AJ, Little MSG, Watts JF (2000) The role of the interphase in the environmental failure of adhesive joints. Acta Mater 48:4543–4553

    Article  Google Scholar 

  58. van der Leeden MC, Frens G (2002) Surface properties of plastic materials in relation to their adhering performance. Adv Eng Mater 4(5):280–289

    Article  Google Scholar 

  59. Seidlitz H, Ulke-Winter L, Kroll L (2014) New joining technology for optimized metal/composite assemblies. J Eng. doi:10.1155/2014/958501

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Acknowledgements

This work was supported by Helmholtz Association (grant number VH-NG-626). The authors would also like to thank Mr. Fernando Fernandez and Mr. Marcos Miyazaki (Embraer Co., Brazil) for providing parts of the aluminum surface pre-treatments.

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Correspondence to S. T. Amancio-Filho.

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Recommended for publication by Commission III - Resistance Welding, Solid State Welding, and Allied Joining Process

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Goushegir, S.M., dos Santos, J.F. & Amancio-Filho, S.T. Influence of aluminum surface pre-treatments on the bonding mechanisms and mechanical performance of metal-composite single-lap joints. Weld World 61, 1099–1115 (2017). https://doi.org/10.1007/s40194-017-0509-y

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