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Organostannoxanes Containing Peripheral Thiomethyl Groups

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Abstract

The reaction of 4-thiomethylbenzoic acid with [n-BuSn(O)OH]n in a 6:6 stoichiometric ratio results in the formation of a hexameric organostannoxane drum. (1) On treatment of 1 with HAuCl4 a ring opening reaction occurs to afford a hexatin ladder. (2) The synthesis and structural characterization of these compounds are discussed.

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Acknowledgments

Authors thank the Department of Science and Technology, India for financial support. RSN is thankful to CSIR, India for Senior Research Fellowship.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, Kanpur, 208 016, India

    Vadapalli Chandrasekhar & Ramakirushnan Suriya Narayanan

  2. School of Chemical Sciences, National Institute of Science Education and Research, Jatni, Khurda, 752 050, India

    Vadapalli Chandrasekhar & Ramakirushnan Suriya Narayanan

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  1. Vadapalli Chandrasekhar
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  2. Ramakirushnan Suriya Narayanan
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Correspondence to Vadapalli Chandrasekhar.

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Chandrasekhar, V., Suriya Narayanan, R. Organostannoxanes Containing Peripheral Thiomethyl Groups. Proc. Natl. Acad. Sci., India, Sect. A Phys. Sci. 86, 627–632 (2016). https://doi.org/10.1007/s40010-016-0290-0

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