Abstract
The physicochemical sludge generated from treatment of effluents from marble processing facilities should be managed properly due to their adverse effects on the environment. These sludges can be evaluated as catalyst in pyrolysis since they consist of some inorganics such as CaCO3 and Al or Fe salts which come from marble structure and coagulation–flocculation treatment of the effluent, respectively. Therefore, in this study, an approach for sustainable resource recovery from agro-industrial wastes (olive pomace) was developed by offering a solution to the two different waste types via pyrolysis and by revealing economic value-added potential of the process. Olive pomace-marble sludge catalyst mixtures were pyrolyzed in a laboratory-scale fixed bed batch pyrolysis system by using four catalyst dosages (10, 20, 30 and 50%) and three pyrolysis temperatures (300, 500 and 700 °C) at 5 °C/min heating rate. Pyrolysis oils and gases were analyzed with GCMS-FID and FTIR for evaluating the potential of economically valuable organic compounds. Organic compounds having extensive usage areas, such as feedstock for surfactants production, emollient, flavoring and softening, and high economic value in the market, such as 1-Pentadecanol, 2-Pentadecanone and Octane, were identified especially in catalytic pyrolysis liquid products. For instance, the potential profit that can be obtained from the conversion of olive pomace to ‘2-pentadecanone’ compound found in catalytic pyrolysis oil produced in this study is around 2.46 × 1013 USD for 2021/22 years at ideal conditions. Consequently, the presented approach contributes to sustainable circular economy via converting wastes into economic value instead of conventional waste disposal methods.
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The datasets used and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
Abiko H (2015) The organic solvent extraction efficiency of activated carbon used in sampling tube products. 炭素 269:201–208
Al Bkoor Alrawashdeh K, Slopiecka K, Alshorman AA, Bartocci P, Fantozzi F (2017) Pyrolytic degradation of Olive Waste Residue (OWR) by TGA: thermal decomposition behavior and kinetic study. J Energy Power Eng 11(8):497–510
Christoforou EA, Fokaides PA, Banks SW, Nowakowski D, Bridgwater AV, Stefanidis S, Lappas AA (2018) Comparative study on catalytic and non-catalytic pyrolysis of olive mill solid wastes. Waste Biomass Valor 9(2):301–313
Dede OH, Dede C, Sakar S, Sazak M, Ozer H (2020) Investigation of treatment process and treatment sufficiency of marble mine wastewater: a case study in Turkey. Environ Dev Sustain 22:6505–6512
Demiral İ, Çemrek Kul Ş (2015) Kestane kabuğunun pirolizi ve elde edilen ürünlerin karakterizasyonu. Anadolu Univer J Sci Technol A—Appl Sci Eng 16(2):125–134 (in Turkish)
Dinc G (2018) Towards a sustainable waste management in olive mill through olive pomace pyrolysis. The Graudate School Of Natural and Applied Sciences of Selçuk University
Ding K, Zhong Z, Wang J, Zhang B, Fan L, Liu S, Ruan R (2018) Improving hydrocarbon yield from catalytic fast co-pyrolysis of hemicellulose and plastic in the dual-catalyst bed of CaO and HZSM-5. Biores Technol 261:86–92
Edeh I, Overton T, Bowra S (2021) Catalytic hydrothermal deoxygenation of fatty acids over palladium on activated carbon catalyst (Pd/C) for renewable diesel production. Biofuels 12(9):1075–1082
Ersoy B, Alptekin A, Sarıışık A, Gürcan S, Erkan ZE, Yıldız A (2005) Doğal taş İşleme tesis atıksularından bulanıklığın giderilmesinde farklı yöntemlerin ve farklı koagülantların etkisi. Madencilik ve Çevre Semp 117–125 (in Turkish)
Frankel EN (2012) Chapter 4—hydroperoxide decomposition. Lipid oxidation: Oily Press Lipid Library Series, 2nd edn., pp 67–98
Ghouma I, Jeguirim M, Guizani C, Ouederni A, Limousy L (2017) Pyrolysis of olive pomace: degradation kinetics, gaseous analysis and char characterization. Waste Biomass Valor 8:1689–1697
Hani FFB, Hailat MM (2016) Production of bio-oil from pyrolysis of olive biomass with/without catalyst. Adv Chem Eng Sci 6(04):488
Kumagai S, Hasegawa I, Grause G, Kameda T, Yoshioka T (2015) Thermal decomposition of individual and mixed plastics in the presence of CaO or Ca (OH)2. J Anal Appl Pyrol 113:584–590
López A, De Marco I, Caballero BM, Laresgoiti MF, Adrados A, Torres A (2011) Pyrolysis of municipal plastic wastes II: influence of raw material composition under catalytic conditions. Waste Manage 31(9–10):1973–1983
Lyu G, Wu S, Zhang H (2015) Estimation and comparison of bio-oil components from different pyrolysis conditions. Front Energy Res 3:28
Miskolczi N, Czégény Z (2016) Thermo-catalytic pyrolysis of waste plastics from end of life vehicle. MATEC Web Confer 49:05002
Ministry of Industry and Technology (2021) Mersin İli Pirina Tesisi Ön Fizibilite Raporu. https://www.yatirimadestek.gov.tr/pdf/assets/upload/fizibiliteler/mersin-ili-pirina-tesisi-on-fizibilite-raporu-2021.pdf (in Turkish)
Muhammad C, Onwudili JA, Williams PT (2015) Catalytic pyrolysis of waste plastic from electrical and electronic equipment. J Anal Appl Pyrol 113:332–339
National Center for Biotechnology Information (2021) PubChem compound summary for CID 8174, 1-Decanol. https://pubchem.ncbi.nlm.nih.gov/compound/1-Decanol. Accessed 4 Oct 2021
Onen V, Ozgan A, Goktepeli G, Kalem M, Ahmetli G, Yel E (2023) Marble processing effluent treatment sludge in waste PET pyrolysis as catalyst-I: pyrolysis product yields and the char characteristics. Int J Environ Sci Technol 20(4):3965–3986
Panchasara H, Ashwath N (2021) Effects of pyrolysis bio-oils on fuel atomisation—a review. Energies 14(4):794
Schmidt R, Griesbaum K, Behr A, Biedenkapp D, Voges HW, Garbe D, Paetz C, Collin G, Mayer D, Höke H (2014) Hydrocarbons. Ullmann’s Encycloped Ind Chem
Şensöz S, Demiral I, Gerçel HF (2006) Olive bagasse (Olea europea L.) pyrolysis. Biores Technol 97:429–436
Shang Q, Xiao J, Liu X, Ling Y, Liu W, Cui G, Tang B (2022) Isobaric vapor–liquid equilibria and distillation process design for separating ketones in biomass pyrolysis oil. J Chem Thermodyn 164:106622
Shen D, Liu G, Zhao J, Xue J, Guan S, Xiao R (2015) Thermo-chemical conversion of lignin to aromatic compounds: effect of lignin source and reaction temperature. J Anal Appl Pyrol 112:56–65
Siyumbwa SN, Ekeuku SO, Amini F, Emerald NM, Sharma D, Okechukwu PN (2019) Wound healing and antibacterial activities of 2-Pentadecanone in streptozotocin-induced Type 2 diabetic rats. Pharmacogn Mag 15(62):71
Soeder DJ (2021) Fossil fuels and climate change. In: Fracking and the environment. Springer, Cham, pp 155–185. https://doi.org/10.1007/978-3-030-59121-2_9
TEPGE (2022) Ürün Raporu-zeytinyağı ve sofralık zeytin, T.R. Ministry of Agriculture and Forestry. https://arastirma.tarimorman.gov.tr/tepge/Belgeler/PDF%20%C3%9Cr%C3%BCn%20Raporlar%C4%B1/2022%20%C3%9Cr%C3%BCn%20Raporlar%C4%B1/Zeytinya%C4%9F%C4%B1%20%20Sofral%C4%B1k%20Zeytin%20%C3%9Cr%C3%BCn%20Raporu%202022-371%20TEPGE.pdf (in Turkish)
TUBITAK (2015) Zeytin Sektörü Atiklarinin Yönetimi Projesi 5148602, TUBITAK MAM, Kocaeli-Gebze. https://webdosya.csb.gov.tr/db/destek/icerikler/zeyt-n_sektoru_at-klar-n-n_yonet-m-_projes--20191127122437.pdf (in Turkish)
URL 1. Chemical Book (2022) Alpha-Pinene. https://www.chemicalbook.com/SupplierPriceList_EN.aspx?cbn=CB8209087&page=1#price. Accessed 30 Sep 2022
URL 2. National Center for Biotechnology Information (2022) PubChem Compound Summary for CID 12397, 1-Pentadecanol. Retrieved September 30, 2022 from https://pubchem.ncbi.nlm.nih.gov/compound/1-Pentadecanol.
URL 3. National Center for Biotechnology Information (2022). PubChem Compound Summary for CID 5364509, Methyl oleate. https://pubchem.ncbi.nlm.nih.gov/compound/Methyl-oleate. Accessed 30 Sep 2022
URL 4. National Center for Biotechnology Information (2022) PubChem Compound Summary for CID 8181, Methyl palmitate. https://pubchem.ncbi.nlm.nih.gov/compound/Methyl-palmitate. Accessed 1 Oct 2022
URL 5. Ministry of Environment, Urbanization and Climate Change (2023) Circular on the transition of olive oil production facilities to 2-phase production. https://www.csb.gov.tr/zeytinyagi-isletmelerinin-2-fazli-uretime-gecisi-genelgesi-yayimlandi-bakanlik-faaliyetleri-37394. Accessed 11 Dec 2023
URL 6. Merck (2023) 2-Pentadecanone Price. https://www.sigmaaldrich.com/TR/en/product/aldrich/w372404. Accessed 11 Dec 2023
URL 7. National Center for Biotechnology Information (2022) PubChem Compound Summary for CID 11610, 1-Heptene. https://pubchem.ncbi.nlm.nih.gov/compound/1-Heptene. Accessed 3 Oct 2022
URL 8. National Center for Biotechnology Information (2022) PubChem Compound Summary for CID 8125, 1-Octene. https://pubchem.ncbi.nlm.nih.gov/compound/1-Octene. Accessed 3 Oct 2022
URL 9. National Center for Biotechnology Information (2022) PubChem Compound Summary for CID 356, n-Octane. https://pubchem.ncbi.nlm.nih.gov/compound/n-Octane. Accessed 5 Oct 2022
URL 10. National Center for Biotechnology Information (2022) PubChem Compound Summary for CID 8900, Heptane. https://pubchem.ncbi.nlm.nih.gov/compound/Heptane. Accessed 1 Oct 2022
URL 11. CISION (2022) Global Toluene Market 2017–2022. Retrieved October 5, 2022 from https://www.prnewswire.com/news-releases/global-toluene-market-2017-2022---market-reached-a-value-of-us-21-billion-in-2016-and-is-expected-to-reach-28-billion-in-2022-300580058.html. Accessed 5 Oct 2022
Uzun BB, Pütün AE, Pütün E (2007) Composition of products obtained via fast pyrolysis of olive-oil residue: effect of pyrolysis temperature. J Anal Appl Pyrol 79(1–2):147–153
Wang P, Chen L, Shen Y (2021) Recycling spent ternary lithium-ion batteries for modification of dolomite used in catalytic biomass pyrolysis—a preliminary study by thermogravimetric and pyrolysis-gas chromatography/mass spectrometry analysis. Biores Technol 337:125476
Wang Z, Wang F, Cao J, Wang J (2010) Pyrolysis of pinewood in a slowly heating fixed-bed reactor: potassium carbonate versus calcium hydroxide as a catalyst. Fuel Process Technol 91(8):942–950
Xue Y (2017) Thermochemical conversion of organic and plastic waste materials through pyrolysis. Doctoral dissertation, Iowa State University, 156
Yılmaztürk, D. (2011). Andezit işleme atiksuyunun fizikokimyasal aritimı. Master of science thesis, Selçuk Üniversitesi Fen Bilimleri Enstitüsü (in Turkish)
Zadeh ZE, Abdulkhani A, Aboelazayem O, Saha B (2020) Recent insights into lignocellulosic biomass pyrolysis: a critical review on pretreatment, characterization, and products upgrading. Processes 8(7):799
Zhang Y, Duan S, Li J, Shao S, Wang W, Zhang S (2017) Life cycle assessment of industrial symbiosis in Songmudao chemical industrial park, Dalian, China. J Clean Prod 158:192–199
Zheng A, Zhao Z, Chang S, Huang Z, Wu H, Wang X, Li H (2014) Effect of crystal size of ZSM-5 on the aromatic yield and selectivity from catalytic fast pyrolysis of biomass. J Mol Catal a: Chem 383:23–30
Acknowledgements
This study was produced from a part of PhD thesis of Gamze GÖKTEPELİ. The authors gratefully acknowledge the Bilateral Joint Research Project between TUBITAK (Turkey) [CAYDAG-118Y475] and JSPS (Japan) [JPJSBP12019942]; the authors also acknowledge to Konya Technical University BAP (201101071) for financial supports.
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Project Administration and Funding Acquisition: Esra Yel. The authors declare that no funds, grants, or other support were received during the preparation of this manuscript.
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Original manuscript draft was prepared by Gamze Goktepeli. Experimental studies, material preparation, data collection and analyses were perfomed by Gamze Goktepeli and Afra Ozgan. Conceptualization, review and editing were made by Gamze Goktepeli, Vildan Onen, Gulnare Ahmetli, Merve Kalem and Esra Yel.
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Goktepeli, G., Ozgan, A., Onen, V. et al. Development of sustainable resource recovery approach from agro-industrial wastes by revealing the economic added value potential. Int. J. Environ. Sci. Technol. (2024). https://doi.org/10.1007/s13762-024-05520-z
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DOI: https://doi.org/10.1007/s13762-024-05520-z