Abstract
Herein, the transparent omniphobic coating on glass slides was fabricated by using three different colloidal dispersions as sacrificial templates for a silica sol to make nano-scale surface roughness. These surface structures were further functionalized with a long chain fluorinated silane. These coatings showed a stable repellency to both water and low-surface tension liquids with the maximum contact angle of 156° to water and of about 130° to corn and paraffin oils. The prepared glass slides presented very high transparency with a light transmittance of about 92–98%. The coated surfaces were stable up to 400 °C and represented a good resistance under corrosive conditions by immersing 24 h in aqueous solutions of H2SO4 (pH 2) and KOH (pH 14).
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L. Xu, J. He, Fabrication of highly transparent superhydrophobic coatings from hollow silica nanoparticles. Langmuir 28, 7512–7518 (2012)
T. Rezayi, M.H. Entezari, Achieving to a superhydrophobic glass with high transparency by a simple sol–gel-dip-coating method. Surf. Coat. Technol. 276, 557–564 (2015)
T. Rezayi, M.H. Entezari, Wettability properties vary with different morphologies of ZnO nanoparticles deposited on glass and modified by stearic acid. New J. Chem. 40, 2582–2591 (2016)
D. Wang, Q. Sun, M.J. Hokkanen, C. Zhang, F.-Y. Lin, Q. Liu, S.-P. Zhu, T. Zhou, Q. Chang, B. He, Design of robust superhydrophobic surfaces. Nature 582, 55–59 (2020)
F. Chen, J. Du, S. Huang, Fabrication of repairable anti-corrosive superhydrophobic surfaces with micro-nano structures by ultrasonic cavitation. Appl. Surf. Sci. 541, 148605 (2021)
N. Vogel, R.A. Belisle, B. Hatton, T.-S. Wong, J. Aizenberg, Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers. Nat. Commun. 4, 1–10 (2013)
Y. Si, Z. Guo, Superhydrophobic nanocoatings: from materials to fabrications and to applications. Nanoscale 7, 5922–5946 (2015)
M. Boban, K. Golovin, B. Tobelmann, O. Gupte, J.M. Mabry, A. Tuteja, Smooth, all-solid, low-hysteresis, omniphobic surfaces with enhanced mechanical durability. ACS Appl. Mater. Interfaces. 10, 11406–11413 (2018)
A. Jamsaz, E. K. Goharshadi, A. Barras, M. Ifires, S. Szunerits, R. Boukherroub, Magnetically driven superhydrophobic/superoleophilic graphene-based polyurethane sponge for highly efficient oil/water separation and demulsification. Sep. Purif. Technol. 274, 118931 (2021)
P. Mandal, J. Ivvala, H.S. Arora, S.K. Ghosh, H.S. Grewal, Bioinspired micro/nano structured aluminum with multifaceted applications. Colloids Surf. B Biointerfaces. 211, 112311 (2022)
T.-S. Wong, S.H. Kang, S.K.Y. Tang, E.J. Smythe, B.D. Hatton, A. Grinthal, J. Aizenberg, Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity. Nature 477, 443–447 (2011)
R. Hensel, C. Neinhuis, C. Werner, The springtail cuticle as a blueprint for omniphobic surfaces. Chem. Soc. Rev. 45, 323–341 (2016)
E. Arzt, H. Quan, R.M. McMeeking, R. Hensel, Functional surface microstructures inspired by nature—from adhesion and wetting principles to sustainable new devices. Prog. Mater. Sci. 120, 100823 (2021)
D.C. Leslie, A. Waterhouse, J.B. Berthet, T.M. Valentin, A.L. Watters, A. Jain, P. Kim, B.D. Hatton, A. Nedder, K. Donovan, A bioinspired omniphobic surface coating on medical devices prevents thrombosis and biofouling. Nat. Biotechnol. 32, 1134–1140 (2014)
M. Villegas, Y. Zhang, N. Abu Jarad, L. Soleymani, T.F. Didar, Liquid-infused surfaces: a review of theory, design, and applications. ACS Nano 13, 8517–8536 (2019)
A.K. Kota, G. Kwon, A. Tuteja, The design and applications of superomniphobic surfaces. NPG Asia Mater. 6, e109–e109 (2014)
Y. Lu, G. He, C.J. Carmalt, I.P. Parkin, Synthesis and characterization of omniphobic surfaces with thermal, mechanical and chemical stability. RSC Adv. 6, 106491–106499 (2016)
S.M. Imani, L. Ladouceur, T. Marshall, R. Maclachlan, L. Soleymani, T.F. Didar, Antimicrobial nanomaterials and coatings: current mechanisms and future perspectives to control the spread of viruses including SARS-CoV-2. ACS Nano 14, 12341–12369 (2020)
D. Zhang, L. Li, Y. Wu, B. Zhu, H. Song, One-step method for fabrication of bioinspired hierarchical superhydrophobic surface with robust stability. Appl. Surf. Sci. 473, 493–499 (2019)
Z. Altangerel, B. Purev-Ochir, A. Ganzorig, T. Tsagaantsooj, G. Lkhamsuren, A. Choisuren, G. Chimed, Superhydrophobic modification and characterization of cashmere fiber surfaces by wet coating techniques of silica nanoparticles. Surf. Interfaces. 19, 100533 (2020)
A. Tuteja, W. Choi, M. Ma, J.M. Mabry, S.A. Mazzella, G.C. Rutledge, G.H. McKinley, R.E. Cohen, Designing superoleophobic surfaces. Science (80-.) 318, 1618–1622 (2007)
Y. Zhang, B. Dong, S. Wang, L. Zhao, L. Wan, E. Wang, Mechanically robust, thermally stable, highly transparent superhydrophobic coating with low-temperature sol–gel process. RSC Adv. 7, 47357–47365 (2017)
X. Zhang, B. Ding, Y. Bian, D. Jiang, I.P. Parkin, Synthesis of superhydrophobic surfaces with Wenzel and Cassie-Baxter state: experimental evidence and theoretical insight. Nanotechnology 29, 485601 (2018)
D. Goswami, S.K. Medda, G. De, Superhydrophobic films on glass surface derived from trimethylsilanized silica gel nanoparticles. ACS Appl. Mater. Interfaces. 3, 3440–3447 (2011)
X. Deng, L. Mammen, H.-J. Butt, D. Vollmer, Candle soot as a template for a transparent robust superamphiphobic coating. Science (80-.) 335, 67–70 (2012)
I. Jerman, M. Koželj, B. Orel, The effect of polyhedral oligomeric silsesquioxane dispersant and low surface energy additives on spectrally selective paint coatings with self-cleaning properties. Sol. Energy Mater. Sol. Cells. 94, 232–245 (2010)
P. Kim, T.-S. Wong, J. Alvarenga, M.J. Kreder, W.E. Adorno-Martinez, J. Aizenberg, Liquid-infused nanostructured surfaces with extreme anti-ice and anti-frost performance. ACS Nano 6, 6569–6577 (2012)
H.-J. Choi, S. Choo, J.-H. Shin, K.-I. Kim, H. Lee, Fabrication of superhydrophobic and oleophobic surfaces with overhang structure by reverse nanoimprint lithography. J. Phys. Chem. C. 117, 24354–24359 (2013)
S. Utech, K. Bley, J. Aizenberg, N. Vogel, Tailoring re-entrant geometry in inverse colloidal monolayers to control surface wettability. J. Mater. Chem. A. 4, 6853–6859 (2016)
J. Choi, W. Jo, S.Y. Lee, Y.S. Jung, S.-H. Kim, H.-T. Kim, Flexible and robust superomniphobic surfaces created by localized photofluidization of azopolymer pillars. ACS Nano 11, 7821–7828 (2017)
Z. Zhang, H. Wang, Y. Liang, X. Li, L. Ren, Z. Cui, C. Luo, One-step fabrication of robust superhydrophobic and superoleophilic surfaces with self-cleaning and oil/water separation function. Sci. Rep. 8, 1–12 (2018)
J.A. Kharraz, M.U. Farid, N.K. Khanzada, B.J. Deka, H.A. Arafat, A.K. An, Macro-corrugated and nano-patterned hierarchically structured superomniphobic membrane for treatment of low surface tension oily wastewater by membrane distillation. Water Res. 174, 115600 (2020)
Y. Wu, S. Zhou, B. You, L. Wu, Bioinspired design of three-dimensional ordered tribrachia-post arrays with re-entrant geometry for omniphobic and slippery surfaces. ACS Nano 11, 8265–8272 (2017)
J. Liu, Y. Sun, X. Zhou, X. Li, M. Kappl, W. Steffen, H. Butt, One-step synthesis of a durable and liquid-repellent poly (dimethylsiloxane) coating. Adv. Mater. 33, 2100237 (2021)
P. Zhu, T. Kong, X. Tang, L. Wang, Well-defined porous membranes for robust omniphobic surfaces via microfluidic emulsion templating. Nat. Commun. 8, 1–10 (2017)
A. Tuteja, W. Choi, J.M. Mabry, G.H. McKinley, R.E. Cohen, Robust omniphobic surfaces. Proc. Natl. Acad. Sci. 105, 18200–18205 (2008)
Y. Sun, Z. Guo, Recent advances of bioinspired functional materials with specific wettability: from nature and beyond nature. Nanoscale Horizons. 4, 52–76 (2019)
T.A.S. Mahmut, H. Memon, F. Xu, I. Ahmed, X. Hou, Electrospun nanofibre membrane based transparent slippery liquid-infused porous surfaces with icephobic properties. Colloids Surf. A Physicochem. Eng. Asp. 585, 124177 (2020)
P. Tian, Z. Guo, Bioinspired silica-based superhydrophobic materials. Appl. Surf. Sci. 426, 1–18 (2017)
S. Yu, Z. Guo, W. Liu, Biomimetic transparent and superhydrophobic coatings: from nature and beyond nature. Chem. Commun. 51, 1775–1794 (2015)
N. Wang, D. Xiong, Comparison of micro-/nano-hierarchical and nano-scale roughness of silica membranes in terms of wetting behavior and transparency. Colloids Surf. A Physicochem. Eng. Asp. 446, 8–14 (2014)
K.R. Phillips, G.T. England, S. Sunny, E. Shirman, T. Shirman, N. Vogel, J. Aizenberg, A colloidoscope of colloid-based porous materials and their uses. Chem. Soc. Rev. 45, 281–322 (2016)
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The authors express their gratitude to the Ferdowsi University of Mashhad for support of this project (Grant No. 3/38438).
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Mahvelati-Shamsabadi, T., Goharshadi, E.K., Zohuri, G. et al. Transparent and robust omniphobic surface using colloidal polymer layers. J IRAN CHEM SOC 19, 4589–4599 (2022). https://doi.org/10.1007/s13738-022-02623-7
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DOI: https://doi.org/10.1007/s13738-022-02623-7