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Influence of mesoporous carbon and silica structures as support on catalytic behavior of CMK-3 and MCM-41 modified Cu(II)-acetohydrazide in multicomponent organic reactions

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Abstract

Cu(II)-acetohydrazide functionalized CMK-3 and MCM-41 mesoporous materials prepared by a simple, efficient and less expensive protocol. These catalysts are carefully characterized by SEM, XRD, TGA, FT-IR, EDX, ICP‐OES and BET techniques. The obtained nanostructured compounds were also used as a green, efficient, heterogeneous and reusable catalytic systems for the synthesis of 2-amino-4-H-pyran and 2,4,5-trisubstituted imidazole derivatives. Also the results and behavior of the two catalysts were comparable in some cases. The synthesized nanocatalysts could be easily recovered from the reaction mixture and reused many times without significant loss of their catalytic activities.

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Acknowledgements

The authors acknowledge Ilam University, Ilam, Iran, and Bu Ali Sina University, Hamedan, Iran, for financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, P. O. Box: 69315516, Ilam, Iran

    Raziyeh Ghafouri-Nejad & Shabnam Rashidi

  2. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, P. O. Box: 6517838683, Hamedan, Iran

    Maryam Hajjami

Authors
  1. Raziyeh Ghafouri-Nejad
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  2. Shabnam Rashidi
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  3. Maryam Hajjami
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Corresponding author

Correspondence to Maryam Hajjami.

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Ghafouri-Nejad, R., Rashidi, S. & Hajjami, M. Influence of mesoporous carbon and silica structures as support on catalytic behavior of CMK-3 and MCM-41 modified Cu(II)-acetohydrazide in multicomponent organic reactions. J IRAN CHEM SOC 19, 2505–2517 (2022). https://doi.org/10.1007/s13738-021-02473-9

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