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Multiparameter optimization of magnetite solid-phase microextraction for preconcentration of diclofenac and determination by UV–Vis Spectrophotometry

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Abstract

In this work, a clean and simple magnetic solid-phase microextraction based on L-arginine modified magnetic dialdehyde starch nanocomposite was developed for the preconcentration and determination of diclofenac in biological samples by UV–Vis Spectrophotometry. A Plackett–Burman experimental design was used to evaluate the influence of effective parameters. Significant parameters were further optimized by Central Composite Design. Sample volume, pH and salting effect had a main effect on extraction of diclofenac by the proposed method. Under the optimized conditions, the detection limit (3 \({S}_{b}\), n = 7) was found to be 0.039 µg ml−1. The calibration curve showed dynamic linear 0.05–10 µg ml−1 with correlation coefficients (R2) of 0.987. The enrichment factor was found to be 148. The proposed method showed good results for preconcentration and determination of diclofenac in serum and pharmaceutical samples.

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References

  1. M.R. Rezaei Kahkha, M. Kaykhaii, M.S. Afarani, Z. Sepehri, Anal. Methods. 8, 5978 (2016)

  2. Q. Fu, Q. Ye, J. Zhang,J. Richards, D. Borchardt, J. Gan, Environ. Pollut. (Barking, Essex : 1987) 222, 383 (2017)

  3. B. Lachmann, M. Kratzel, C.R. Noe, Sci. Pharm. 80, 311 (2012)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  4. Z. Es’haghi, E. Esmaeili-Shahri, J. Chromatogr. B Anal. Technol. Biomed. Life Sci. 973, 142 (2014)

    Article  CAS  Google Scholar 

  5. M. Ghorbani, M. Chamsaz, G.H. Rounaghi, Anal. Bioanal. Chem. 408, 4274 (2016)

    Google Scholar 

  6. N. C. Honakeri, S. J. Malode, R. M. Kulkarni, N. P. Shetti, Sensors International 1, 100002 (2020)

  7. M. Ferreira, S. Güney, I. Kuźniarska-Biernacka, O.S G.P. Soares, J.L. Figueiredo, M.F.R. Pereira, I.C. Neves, A.M. Fonseca, P. Parpot, New J. Chem, 45, 12622 (2021)

  8. A. MaciÃ, F. Borrull, M. Calull, C. Aguilar, J. Chromatogr. A. 1117, 234 (2006)

    Article  PubMed  Google Scholar 

  9. F.A. Aly, S.A. Al-Tamimi, A.A. Alwarthan, Anal. Chim. Acta 416, 87 (2000)

    Article  CAS  Google Scholar 

  10. T. Perez-Ruiz, C. Martinez-Lozano, A. Sanz, E. Bravo, J. Chromatogr. B Biomed. Appl. 708, 249 (1998)

    Article  CAS  Google Scholar 

  11. G. Andraws, S. Trefi, Heliyon. 6, e04613 (2020)

  12. A.O. Santini, H.R. Pezza, L. Pezza, Sensors Actuators B Chem. 128, 117 (2007)

    Article  CAS  Google Scholar 

  13. C.A.S. Silva, R.L.S. Silva, A.T. Figueiredo, V.N. Alves, J. Braz. Chem. Soc. 31, 109 (2020)

    CAS  Google Scholar 

  14. S. Heydari, Z. Shirmohammadi Aliakbarkhani, M. Hosseinpour Zaryabi, Int. J. Nanosci. Nanotechnol. 16, 153 (2020)

  15. N. Manousi, E.A. Deliyanni, E. Rosenberg, G.A. Zachariadis, RSC Adv. 11, 19492 (2021)

    Article  CAS  Google Scholar 

  16. M. C. L. do Nascimento, F. N. Ferreira, A. P. Benevides, D.C. da Silva, V. Cesar, A. S. Luna, J.S. de Gois, J. Anal. At. Spectrom. 36, 900 (2021)

  17. S. Heydari, Iran. J. Sci. Technol. Trans. Sci. 45, 1311 (2021)

    Article  Google Scholar 

  18. I.S. Barreto, S.I.E. Andrade, F.A.S. Cunha, M.B. Lima, M.C.U. Araujo, L.F. Almeida, Talanta 178, 384 (2018)

    Article  CAS  PubMed  Google Scholar 

  19. B. Debrus, P. Lebrun, J. Mbinze Kindenge, F. Lecomte, A. Ceccato, G. Caliaro, J. Mavar Tayey Mbay, B. Boulanger, R.D. Marini, E. Rozet, P. Hubert, J. Chromatogr. A. 1218, 5205 (2011)

  20. S. Ahmadi, M. T. Hamed Mosavian, S. Heydari, J. Iran. Chem. Soc. 15, 2605 (2018)

  21. M. Shamsipur, B. Hemmateenejad, N. Jalili Jahani, K. Maleki Majd, J. Photochem. Photobiol. 299, 210 (2015)

  22. E. Landagaray, C. Vaccher, S. Yous, E. Lipka, J. Pharm. Biomed. Anal. 120, 297 (2016)

    Article  CAS  PubMed  Google Scholar 

  23. S. Heydari, M. Hosseinpour Zaryabi, Anal. Bioanal. Chem. Res. 5, 373 (2018)

  24. B. Andri,A. Dispas,R. Djang'Eing'a Marini, P. Hubert, P. Sassiat, R. Al Bakain, D. Thiébaut, J. Vial, J. Chromatogr. A. 1491, 182 (2017)

  25. S. Heydari, L. Zare, S. Eshagh Ahmadi, J. Iran. Chem. Soc. (2021). https://doi.org/10.1007/s13738-021-02275-z

  26. H. A. Hosseini, S. Heydari, Z. Es’haghi, L. Zare, J. Iran. Chem. Soc. 17, 2397 (2020)

  27. Q.-F. Yin, B.-Z. Ju, S.-F. Zhang, X.-B. Wang, J.-Z. Yang, Carbohydr. Polym. 72, 326 (2008)

    Article  CAS  Google Scholar 

  28. W. Leyu, B. Jie, W. Lun, Z. Fang, L. Yadong, Chem. Eur. J. 12, 6341 (2006)

    Article  Google Scholar 

  29. X. Xin, Q. Wei, J. Yang, L. Yan, R. Feng, G. Chen, B. Du, H. Li, Chem. Eng. Sci. 184, 132 (2012)

    Article  CAS  Google Scholar 

  30. Y. Wang, Y. Zhang, C. Hou, Z. Qi, X. He, Y. Li, Chemosphere 141, 26 (2015)

    Article  CAS  PubMed  Google Scholar 

  31. R.Venkataraghavan, R.Thiruchelvi, D. Sharmila, Heliyon. 6, e05219 (2020)

  32. M.E. El-Sesy, S.S. Ibrahim, Water Sci. Technol. Water 83, 2931 (2021)

    Article  CAS  Google Scholar 

  33. L. Bahloul, F. Ismail, M.E-H. Samar, H. Meradi, Energy Procedia. 50, 1008 (2014)

  34. B. Yilmaz, U. Ciltas, J. Pharm. Anal. 5, 153 (2015)

    Article  CAS  PubMed  Google Scholar 

  35. U. Ciltas, B. Yilmaz, S. Kaban, B.K. Akcay, G. Nazik, Iran. J. Pharm. Sci. 14, 715 (2015)

    CAS  Google Scholar 

  36. M. sadaat, M. Qomi, S. emadzadeh, M. Gholghasemi, J. Appl. Chem. Res. 12, 16 (2018)

  37. S. Ershad, A. Razmara, K. Pourghazi, M. Amoli-Diva, Int. Eng. Technol. 10, 358 (2015)

    CAS  Google Scholar 

  38. L. Fernandez-Llano, M.C. Blanco-Lopez, M.J. Lobo-Castañón, A.J. Miranda-Ordieres, P. Tunon-Blanco, Electroanalysis 19, 1555 (2007)

    Article  CAS  Google Scholar 

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Acknowledgements

The support of this research by the Payame Noor University is greatly appreciated.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, 19395-4697, Tehran, Iran

    Hasan Ali Hosseini, Zarrin Es’haghi & Leili Zare

  2. Department of Chemistry, University of Torbat-e Jam, Torbat-e Jam, Iran

    Somayeh Heydari

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  1. Hasan Ali Hosseini
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  2. Somayeh Heydari
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  3. Zarrin Es’haghi
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  4. Leili Zare
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Correspondence to Hasan Ali Hosseini or Somayeh Heydari.

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Hosseini, H.A., Heydari, S., Es’haghi, Z. et al. Multiparameter optimization of magnetite solid-phase microextraction for preconcentration of diclofenac and determination by UV–Vis Spectrophotometry. J IRAN CHEM SOC 19, 1747–1754 (2022). https://doi.org/10.1007/s13738-021-02414-6

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