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Novel coated wire potentiometric sensor for selective determination of Mn(II) ions in various authentic samples

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Abstract

The current study described a novel covered platinum wire ion-selective electrode sensor that depends on Schiff base N-salicylidene-o-aminophenol that is synthesized as an ionophore for rapid and easy monitoring of Mn(II) in different real samples. Within the concentration range from 1.0 × 10−7 to 1.0 × 10−1 mol/L of Mn(II) ions, the trend of evaluation curve was straight in case of low concentration value 1 × 10−7 mol/L, and Nernstian slope was 30.17 ± 0.1 mVdecade−1 and suitable within the pH range from 3.0 to 8.0. The proposed sensor has been specified by a reasonable low time for response (5 s) with high stability for more than 75 days. Moreover, this sensor demonstrated a decent selectivity for Mn(II) ions among different metal ions. The impact of different plasticizers has been investigated. The selectivity coefficients assessed through separate solution method and match potential method showed significant selectivity for Mn(II). The proposed sensor was adequately utilized to evaluate and detect Mn(II) ions in various samples. Hypothetical calculations likewise affirm the complexation nature of Mn(II) ions with N-salicylidene-o-aminophenol.

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Abbreviations

CPtWISE:

Coated platinum wire ion-selective electrode

Mn(II):

Manganese (II)

MPM:

Match potential

SSM:

Separate solution method

PME:

PVC membrane electrodes

CWE:

Coated wire electrode

CPE:

Carbon paste electrode

SPE:

Screen-printed electrode

FET:

Field-effective transistor

ISE:

Ion-selective electrode

Mn(II)-CPtWISEs:

Manganese (II)-coated platinum wire ion-selective electrode

DBP:

Dibutylphthalate

DOP:

Dioctylphthalate

DOS:

Dioctylsebacate

TCP:

Tricresylphosphate

KTpClPB:

Potassium tetrakis(4-chlorophenyl)borate

o-NPOE:

o-Nitrophenyloctylether

THF:

Tetrahydrofuran

NaTPB:

Sodium tetraphenylborate

ICP-OES:

Inductively coupled plasma-optical emission spectrometry

KpotA, B:

The selectivity coefficient

EA:

Potentiometric response of the primary ion

EB:

Potentiometric response of the interfering ion

aA:

Ion activity of the primary ion

aB:

The ion activity of an interfering ion

S:

Nernstian slope

ZA:

Charge of the primary

ZB:

Charge of the interfering ions

ΔE:

Potential change

\(E_{{{\text{cell}}}}^{ \circ }\) :

The standard cell potentials

dE°/dt:

The isothermal temperature factor

% R:

Percentage recovery

% RSD:

The relative standard deviation

SD:

Standard deviation

EMF:

Electromotive force

–log [Mn (II)]:

Negative logarithm concentration of manganese(II) ion

LOD:

Limit of detection

DFT:

Density functional theory

HOMO:

Highest occupied molecular orbital

LUMO:

Lowest unoccupied molecular orbital

IUPAC:

International Union of Pure and Applied Chemistry

References

  1. R.F. Aglan, H.M. Saleh, G.G. Mohamed, Appl. Water Sci. 8, 141 (2018)

    Article  Google Scholar 

  2. R.F. Aglan, M.M. Hamed, H.M. Saleh, J. Anal. Sci. Technol. 10, 7 (2019)

    Article  Google Scholar 

  3. H.M. Saleh, H.H. Mahmoud, R.F. Aglan, T.A. Bayoumi, Environ. Eng. Manag. J. 18, 1327 (2019)

    Article  CAS  Google Scholar 

  4. H.M. Saleh, Nucl. Eng. Des. 242, 425 (2012)

    Article  CAS  Google Scholar 

  5. H.M. Saleh, H.R. Moussa, H.H. Mahmoud, F.A. El-Saied, M. Dawod, R.S.A. Wahed, Prog. Nucl. Energy 118, 103147 (2020)

    Article  CAS  Google Scholar 

  6. H.M. Saleh, T.A. Bayoumi, H.H. Mahmoud, R.F. Aglan, Nucl. Eng. Des. 315, 194 (2017)

    Article  CAS  Google Scholar 

  7. H.M. Saleh, R.F. Aglan, H.H. Mahmoud, Chem. Ecol. 35, 164 (2019)

    Article  CAS  Google Scholar 

  8. H.M. Saleh, H.R. Moussa, F.A. El-Saied, M. Dawoud, E.S.A. Nouh, R.S.A. Wahed, Prog. Nucl. Energy 125, 103393 (2020)

    Article  CAS  Google Scholar 

  9. H.M. Saleh, J. Nucl. Mater. 446, 124 (2014)

    Article  CAS  Google Scholar 

  10. T.A. Bayoumi, H.M. Saleh, Prog. Nucl. Energy 107, 83 (2018)

    Article  CAS  Google Scholar 

  11. H.M. Saleh, R.F. Aglan, H.H. Mahmoud, Prog. Nucl. Energy 219, 103178 (2020)

    Article  Google Scholar 

  12. H.M. Saleh, H.R. Moussa, F.A. El-Saied, M. Dawoud, T.A. Bayoumi, R.S.A. Wahed, Prog. Nucl. Energy 122, 103285 (2020)

    Article  CAS  Google Scholar 

  13. NRC, Drinking Water and Health,: Volume 3 (The National Academies Press, Washington, DC, 1980)

  14. X.G. Kondakis, N. Makris, M. Leotsinidis, M. Prinou, T. Papapetropoulos, Possible health effects of high manganese concentration in drinking water. Arch. Environ. Health Int. J. 44, 175 (1989)

    Article  CAS  Google Scholar 

  15. K. Daly, A. Fenelon, Appl. Spectrosc. 72, 1661 (2018)

    Article  CAS  Google Scholar 

  16. M.R. Ganjali, F. Faridbod, N. Davarkhah, S.J. Shahtaheri, P. Norouzi, Int. J. Environ. Res. 9, 333 (2015)

    CAS  Google Scholar 

  17. A. Abbaspour, A. Izadyar, Anal. Bioanal. Chem. 386, 1559 (2006)

    Article  CAS  Google Scholar 

  18. A. Abbaspour, A. Izadyar, H. Sharghi, Anal. Chim. Acta 525, 91 (2004)

    Article  CAS  Google Scholar 

  19. N. Hajizadeh, Int. J. New Chem. 6, 198 (2019)

    CAS  Google Scholar 

  20. L. Lvova, C.G. Gonçalves, C. Di Natale, A. Legin, D. Kirsanov, R. Paolesse, Talanta 179, 430 (2018)

    Article  CAS  Google Scholar 

  21. M. Apostu, N. Bibire, G. Tantaru, M. Vieriu, A.D. Panainte, L. Agoroaei, Rev. Chim. 66, 657 (2015)

    CAS  Google Scholar 

  22. K. Brodowska, E. Łodyga-Chruścińska, Chemik 68, 129 (2014)

    CAS  Google Scholar 

  23. A.A.A. Aziz, A.N.M. Salem, M.A. Sayed, M.M. Aboaly, J. Mol. Struct. 1010, 130 (2012)

    Article  Google Scholar 

  24. H.A.M. Arida, R.F. Aglan, S.A. El-Reefy, Anal. Lett. 37, 21 (2004)

    Article  CAS  Google Scholar 

  25. M.V. Zoriy, A. Rashad, C. Pickhardt, H.T. Mohsen, H. Forstel, A.I. Helal, N.F. Zahran, J.S. Becker, At. Spectrosc. 24, 195 (2003)

    CAS  Google Scholar 

  26. X.-G. Li, H. Feng, M.-R. Huang, G.-L. Gu, M.G. Moloney, Anal. Chem. 84, 134 (2012)

    Article  CAS  Google Scholar 

  27. E.Y.Z. Frag, R.F. Aglan, H.A. Mohamed, Arab. J. Chem. 12, 388 (2019)

    Article  CAS  Google Scholar 

  28. T.A. Ali, G.G. Mohamed, R.F. Aglan, M.A. Mourad, Russ. J. Electrochem. 54, 201 (2018)

    Article  CAS  Google Scholar 

  29. M. Ghanei-motlagh, M. Fayazi, M. A. Taher 199, 133 (2014)

    CAS  Google Scholar 

  30. Y.S. Kim, J.J. Lee, S.Y. Lee, T.G. Jo, C. Kim, RSC Adv. 6, 61505 (2016)

    Article  CAS  Google Scholar 

  31. S. Kumar, S.K. Mittal, N. Kaur, R. Kaur, RSC Adv. 7, 16474 (2017)

    Article  CAS  Google Scholar 

  32. M. Aghaie, M. Giahi, M. Zawari, Bull. Korean Chem. Soc 31, 2981 (2010)

    Article  Google Scholar 

  33. V.K. Gupta, R. Jain, M.K. Pal, Int. J. Electrochem. Sci. 5, 1164 (2010)

    CAS  Google Scholar 

  34. V.K. Gupta, A.K. Jain, G. Maheshwari, Talanta 72, 49 (2007)

    Article  CAS  Google Scholar 

  35. M.H. Mashhadizadeh, E.P. Taheri, I. Sheikhshoaie, Talanta 72, 1088 (2007)

    Article  CAS  Google Scholar 

  36. J. Motonaka, H. Nishioka, S. Ikeda, N. Tanaka, Bull. Chem. Soc. Jpn. 59, 39 (1986)

    Article  CAS  Google Scholar 

  37. I. Sheikhshoaie, T. Shamspur, S.Y. Ebrahimipur, Arab. J. Chem. 5, 201 (2012)

    Article  CAS  Google Scholar 

  38. A.K. Singh, P. Saxena, A. Panwar, Sens. Actuators B Chem. 110, 377 (2005)

    Article  CAS  Google Scholar 

  39. A.K. Singh, K.R. Bandi, A. Upadhyay, A.K. Jain, Mater. Sci. Eng. C 33, 626 (2013)

    Article  CAS  Google Scholar 

  40. M.R.J. Sarvestani, R. Ahmadi, Anal. Bioanal. Chem. Res. 5, 273 (2018)

    CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Analytical Chemistry, Hot Labs Center, Atomic Energy Authority, Cairo, Egypt

    Refaat F. Aglan

  2. Radioisotope Department, Nuclear Research Center, Egyptian Atomic Energy Authority (EAEA), Dokki, Giza, 12311, Egypt

    Hazem H. Mahmoud & Hosam M. Saleh

  3. Central Laboratory for Elemental and Isotopic Analysis and Department of Accelerators and Ion Sources, Nuclear Research Center, Atomic Energy Authority, Cairo, Egypt

    Ahmed M. Rashad

Authors
  1. Refaat F. Aglan
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  2. Hazem H. Mahmoud
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  3. Ahmed M. Rashad
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  4. Hosam M. Saleh
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Correspondence to Hosam M. Saleh.

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Aglan, R.F., Mahmoud, H.H., Rashad, A.M. et al. Novel coated wire potentiometric sensor for selective determination of Mn(II) ions in various authentic samples. J IRAN CHEM SOC 18, 1567–1579 (2021). https://doi.org/10.1007/s13738-020-02135-2

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  • DOI: https://doi.org/10.1007/s13738-020-02135-2

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