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Substituted group-directed magnesium(II) coordination compounds based on the derivatives of tetrazole-2-acetic acid

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Abstract

The different substituted group will have a substantial effect on the crystal structures of the resulting compounds. Tetrazole–carboxylate ligands are outstanding blocks for construction of novel coordination architectures. Three derivative ligands of tetrazole-2-acetic acid, H3-pytza, H4-pytza and H3tzpha, where H3-pytza = 5-(3-pyridyl)tetrazole-2-acetic acid, H4-pytza = 5-(4-pyridyl)tetrazole-2-acetic acid and H3tzpha = 1,3,5-tris(tetrazol-5-yl)benzene-N2,N2′,N2″-triacetic acid, have been chosen to be reacted with Mg(NO3)2·6H2O, resulting in the formation of three new compounds, [Mg(H2O)6](3-pytza)2·2H2O (1), [Mg(4-pytza)2(H2O)4] (2) and [Mg3(tzpha)2(H2O)12]·10H2O (3). These compounds were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The X-ray diffraction reveals that compounds 1 and 2 are mononuclear structures, while compound 3 shows a one-dimensional chain. The structures of these compounds are controlled by not only the different 5-substituted group of the tetrazole-2-acetic acid, but also the complementary hydrogen bonds. Furthermore, the luminescence studies show that compounds 1–3 show stronger emission than the corresponding ligands.

Graphical Abstract

Three Mg(II) coordination compounds 5-substituted group derivative of tetrazole-2-acetic acid (H3-pytza, H4-pytza and H3tzpha) show different luminescence properties.

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References

  1. G. Aromi, L.A. Barrios, O. Roubeau, P. Gamez, Coord. Chem. Rev. 255, 485–546 (2011)

    Article  CAS  Google Scholar 

  2. M. Wriedt, A.A. Yakovenko, G.J. Halder, A.V. Prosvirin, K.R. MDunbar, H.C. Zhou, J. Am. Chem. Soc. 135, 4040–4050 (2013)

    Article  CAS  Google Scholar 

  3. M. Wriedt, J.P. Sculley, A.A. Yakovenko, Y.G. Ma, G.J. Halder, P.B. Balbuena, H.C. Zhou, Angew. Chem. Int. Ed. 51, 9804–9808 (2012)

    Article  CAS  Google Scholar 

  4. D.Y. Chen, J.H. Zou, W.X. Li, B. Xu, Q.Y. Li, G.W. Yang, J. Wang, Y.M. Ding, Y. Zhang, X.F. Shen, Inorg. Chem. Commun. 40, 35–38 (2014)

    Article  Google Scholar 

  5. H.Y. Yang, L.K. Li, J. Wu, H.W. Hou, B. Xiao, Y.T. Fan, Chem. Eur. J. 15, 4049–4056 (2009)

    Article  CAS  Google Scholar 

  6. M.F. Wu, Z.F. Liu, S.H. Wang, J. Chen, G. Xu, F.K. Zheng, G.C. Guo, J.S. Huang, CrystEngComm 13, 6386 (2011)

    Article  CAS  Google Scholar 

  7. Q. Ye, Y.M. Song, W.X.G.K. Chen, D.W. Fu, P.W.H. Chan, J.S. Zhu, S.D. Huang, R.G. Xiong, J. Am. Chem. Soc. 128, 6554–6555 (2006)

    Article  CAS  Google Scholar 

  8. D.W. Fu, J.Z. Ge, J. Dai, H.Y. Ye, Z.R. Qu, Inorg. Chem. Commun. 12, 994–997 (2009)

    Article  CAS  Google Scholar 

  9. J.H. Zou, D.Y. Chen, G.W. Yang, Q.Y. Li, J. Yang, L. Shen, RSC Adv. 5, 27887–27890 (2015)

    Article  CAS  Google Scholar 

  10. Q.Y. Li, H. Tian, X.Y. Li, J.H. Zou, G.D. Mei, L.J. Qiu, B. Wei, G.W. Yang, RSC Adv. 5, 43741–43749 (2015)

    Article  CAS  Google Scholar 

  11. J.H. Zou, D.L. Zhu, F.F. Li, F.S. Li, H. Wu, Q.Y. Li, G.W. Yang, P. Zhang, Y.X. Miao, J. Xie, Z. Anorg, Allg. Chem. 640(11), 2226–2231 (2014)

    Article  CAS  Google Scholar 

  12. G.W. Yang, F.F. Zhang, Q. Wu, M.J. Cao, Y. Bai, Q.Y. Li, B. Wei, J.H. Zou, RSC Adv. 5, 84439–84445 (2015)

    Article  CAS  Google Scholar 

  13. L. Sun, L. Ma, J.B. Cai, L. Liang, H. Deng, CrystEngComm 14, 890 (2012)

    Article  CAS  Google Scholar 

  14. A. Rodrıguez-Dieguez, A. Salinas-Castillo, A. Sironi, CrystEngComm 12, 876–1879 (2010)

    Google Scholar 

  15. M.F. Wu, M.S. Wang, S.P. Guo, Cryst. Growth Des. 11, 2 (2011)

    Google Scholar 

  16. J. Chen, S.H. Wang, Z.F. Liu, M.F. Wu, Y. Xiao, F.K. Zheng, G.C. Guo, J.S. Huang, N. J. Chem. 38, 269–276 (2014)

    Article  CAS  Google Scholar 

  17. Y. Zhou, G.W. Yang, Q.Y. Li, K. Liu, G.Q. Gu, Y.S. Ma, R.X. Yuan, Inorg. Chim. Acta 362, 1723 (2009)

    Article  CAS  Google Scholar 

  18. J.H. Zou, H.J. Cui, B. Xu, D.L. Zhu, Q.Y. Li, G.W. Yang, Y.C. Hua, Inorg. Chim. Acta 423, 430–434 (2014)

    Article  CAS  Google Scholar 

  19. B.J. Wang, J.H. Zou, W.X. Li, Z. Wang, B. Xu, S. Li, Y.S. Zhai, D.L. Zhu, Q.Y. Li, G.W. Yang, J. Organomet. Chem. 749, 428–432 (2014)

    Article  CAS  Google Scholar 

  20. Q.Y. Li, G.W. Yang, L. Shen, M.H. He, W. Shen, K. Gu, J.N. Jin, Z. Anorg. Allg. Chem. 638, 826–831 (2012)

    Article  CAS  Google Scholar 

  21. J. Yang, Q.Y. Li, L. Shen, G.W. Yang, X.Y. Tang, C. Zhai, H.D. Ding, J.N. Jin, W. Shen, J Chem Crystallogr 41, 1483–1489 (2011)

    Article  CAS  Google Scholar 

  22. C.C. Auriga, Rigaku corporation (Tokyo, Japan, 2005)

    Google Scholar 

  23. G.M. Sheldrick, SHELXS-97, Program for Solution of Crystal Structures (University of Gottingen, Gottingen, 1997)

    Google Scholar 

  24. J.H. Zou, H. Tian, Z. Wang, F.S. Li, F.F. Zhang, L.Y. Zhao, P. Zhang, D.L. Zhu, G.W. Yang, Q.Y. Li, Z. Anorg, Allg. Chem. 640(12–13), 2566–2570 (2014)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors acknowledge financial support from the Natural Science Foundation of Jiangsu Province (Grant No. BK2012210), the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant No. 10KJB430001) and the Opening Fund of Jiangsu Key Laboratory of Advanced Functional Materials (Grant No. 12KFJJ010).

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Authors and Affiliations

  1. Jiangsu Key Laboratory of Advanced Functional Material, Department of Chemistry and Material Engineering, Changshu Institute of Technology, Changshu, 215500, Jiangsu, People’s Republic of China

    Jiao Wu, Yu Bai, Yi Ming Lu, Jing Wang, Qi Wu, Gao Wen Yang & Qiao Yun Li

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  1. Jiao Wu
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  2. Yu Bai
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  3. Yi Ming Lu
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  4. Jing Wang
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  5. Qi Wu
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Correspondence to Gao Wen Yang or Qiao Yun Li.

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Wu, J., Bai, Y., Lu, Y.M. et al. Substituted group-directed magnesium(II) coordination compounds based on the derivatives of tetrazole-2-acetic acid. J IRAN CHEM SOC 13, 2155–2162 (2016). https://doi.org/10.1007/s13738-016-0933-8

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  • DOI: https://doi.org/10.1007/s13738-016-0933-8

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