Abstract
Kraft pulping process is the foremost common pretreatment method utilized in pulp and paper businesses to break down the lignocellulosic linkages to urge cellulose and lignin separated. Due to higher degree of recuperation of the reagents utilized within the process of pulp production having higher cellulosic virtue, this technique rules over others since many decades. A factorial experiment may have star points and centre points added, offering three or five levels for each component. This is known as a central composite design, and it is utilised in response surface modelling. There are a few components to be considered in kraft pulping method which are temperature, retention time, % alkalinity, % sulfidity, and liquor to biomass stacking. The use of Na2S stands for a source of HS−, but too for an extra source of NaOH agreeing to the response included in this prepare. In spite of the fact that we have not taken those two components into thought, they can moreover be utilized in future inquire about. Thus, here, we utilized central composite plan to optimize our components. By taking temperature extend of 140–175 °C, time 20–80 min, and % alkalinity 10–20%, we have gotten diverse reactions of greatest bright absorbance wavelength and concentration information of black liquors.
Similar content being viewed by others
Data availability
No supplementary data.
References
Baruah J, Nath BK, Sharma R et al (2018) Recent trends in the pretreatment of lignocellulosic biomass for value-added products. Front Energy Res 6:1–19. https://doi.org/10.3389/fenrg.2018.00141
Korotkova E, Pranovich A, Wärnå J et al (2015) Lignin isolation from spruce wood with low concentration aqueous alkali at high temperature and pressure: influence of hot-water pre-extraction. Green Chem 17:5058–5068. https://doi.org/10.1039/c5gc01341k
Sannigrahi P, Ragauskas AJ (2013) Fundamentals of biomass pretreatment by fractionation. Aqueous Pretreat Plant Biomass Biol Chem Convers to Fuels Chem 201–222. https://doi.org/10.1002/9780470975831.ch10
Eugenia Eugenio M, Ibarra D, Martín-Sampedro R et al (2019) Alternative raw materials for pulp and paper production in the concept of a lignocellulosic biorefinery. Cellulose. https://doi.org/10.5772/intechopen.90041
Calvo-Flores FG (2020) Lignin: a renewable raw material. Encycl Renew Sustain Mater 102–118. https://doi.org/10.1016/b978-0-12-803581-8.11517-6
Watkins D, Nuruddin M, Hosur M et al (2015) Extraction and characterization of lignin from different biomass resources. J Mater Res Technol 4:26–32. https://doi.org/10.1016/j.jmrt.2014.10.009
Sun RC, Mark Lawther J, Banks WB (1997) Physico-chemical characterization of organosolv lignins from wheat straw. Cellul Chem Technol 31:199–212
Nitsos C, Rova U, Christakopoulos P (2018) Organosolv fractionation of softwood biomass for biofuel and biorefinery applications. Energies 11. https://doi.org/10.3390/en11010050
Ardina V, Irawan B, Prajitno DH, Roesyadi A (2018) Active alkali charge effect on kraft pulping process of acacia mangium and eucalyptus pellita. AIP Conf Proc 2014. https://doi.org/10.1063/1.5054440
Vicentim M, de Almeida Faria R, Ferraz A (2009) High-yield kraft pulping of Eucalyptus grandis Hill ex Maiden biotreated by Ceriporiopsis subvermispora under two different culture conditions. De Gruyter 63(4):408–413. https://doi.org/10.1515/HF.2009.067
Alén R (2019) Pulp and paper. Encycl Anal Sci 425–431. https://doi.org/10.1016/B978-0-12-409547-2.14014-4
Sixta H (2006) Handbook of pulp, vol 2. WILEY-VCH VERLAG
Maan P, Kadam A, Kumar A et al (2018) Process parameters optimization of Casuarina equisetifolia for enhanced production of bleachable grade kraft pulp through RSM. BioRes 13(4):8802–8813
Huang C, Chu Q, Xie Y et al (2015) Effect of kraft pulping pretreatment on the chemical composition, enzymatic digestibility, and sugar release of moso bamboo residues. BioResources 10:240–255. https://doi.org/10.15376/biores.10.1.240-255
Jablonský M, Kočiš J, Ház A, Šima J (2015) Characterization and comparison by UV spectroscopy of precipitated lignins and commercial lignosulfonates. Cellul Chem Technol 49:267–274
Tian Z, Zong L, Niu R, et al (2015) Recovery and characterization of lignin from alkaline straw pulping black liquor: as feedstock for bio-oil research. J Appl Polym Sci 132. https://doi.org/10.1002/APP.42057
Agrawal PK (2014) Natural product communications: Editorial. Nat Prod Commun 9(8)
Biswas B, Pandey N, Bisht Y et al (2017) Pyrolysis of agricultural biomass residues: comparative study of corn cob, wheat straw, rice straw and rice husk. Bioresour Technol 237:57–63. https://doi.org/10.1016/j.biortech.2017.02.046
Danish M, Naqvi M, Farooq U, Naqvi S (2015) Characterization of South Asian agricultural residues for potential utilization in future ‘energy mix.’ Energy Procedia 75:2974–2980. https://doi.org/10.1016/j.egypro.2015.07.604
Cuiping L, Chuangzhi W, Yanyongjie HH (2004) Chemical elemental characteristics of biomass fuels in China. Biomass Bioenerg 27:119–130. https://doi.org/10.1016/j.biombioe.2004.01.002
Wang X, Yang Z, Liu X et al (2020) The composition characteristics of different crop straw types and their multivariate analysis and comparison. Waste Manag 110:87–97. https://doi.org/10.1016/j.wasman.2020.05.018
Ma Y, Li H, Yang H et al (2021) Effects of solid acid and base catalysts on pyrolysis of rice straw and wheat straw biomass for hydrocarbon production. J Energy Inst. https://doi.org/10.1016/j.joei.2021.08.010
Kumar M, Upadhyay SN, Mishra PK (2019) A comparative study of thermochemical characteristics of lignocellulosic biomasses. Bioresour Technol Reports 8:100186. https://doi.org/10.1016/j.biteb.2019.100186
Oriez V, Peydecastaing J, Pontalier PY (2020) Lignocellulosic biomass mild alkaline fractionation and resulting extract purification processes: conditions, yields, and purities. Clean Technol 2:91–115. https://doi.org/10.3390/cleantechnol2010007
GharehBagh FS, Ray S, Seth R (2021) Optimizing lignin extraction from kraft black liquor using protic ionic liquids. Biomass Bioenergy 154:106249. https://doi.org/10.1016/j.biombioe.2021.106249
Pérez E, Abad-Fernández N, Lourençon T et al (2022) Base-catalysed depolymerization of lignins in supercritical water: influence of lignin nature and valorisation of pulping and biorefinery by-products. Biomass Bioenergy 163:106536. https://doi.org/10.1016/j.biombioe.2022.106536
Liu T, Wang P, Tian J et al (2022) Enzymatic saccharification promotion for bioenergy poplar under green liquor pretreatment by fully sulfonated polystyrene: effect of molecular weight. Bioresour Technol 363:127904. https://doi.org/10.1016/j.biortech.2022.127904
Zhang L, Zhang Z, Chen K, Wu Y (2021) Promoting catalytic hydrogenolysis degradation of black liquor crude lignin by extended soda-oxygen cooking. Ind Crops Prod 170:113788. https://doi.org/10.1016/j.indcrop.2021.113788
Skulcova AB, Jablonsky M (2017) UV/Vis spectrometry as a quantification tool for lignin solubilized in deep eutectic solvents. https://doi.org/10.15376/biores.12.3.6713-6722
Sameni J, Krigstin S, Sain M (2017) Solubility of lignin and acetylated lignin in organic solvents. BioResources 12:1548–1565. https://doi.org/10.15376/biores.12.1.1548-1565
Sadeghifar H, Ragauskas A (2020) Lignin as a UV Light blocker-a review. Polymers (Basel) 12:1–10. https://doi.org/10.3390/POLYM12051134
Ghalibaf M, Alén R, Hita I et al (2022) Valorization potential of technical lignins from Norway spruce (Picea abies) via pyrolysis. J Anal Appl Pyrolysis 165:105549. https://doi.org/10.1016/j.jaap.2022.105549
Pauline AL, Joseph K (2021) Hydrothermal carbonization of crude oil sludge –characterization of hydrochar and hydrothermal liquor. Process Saf Environ Prot 154:89–96. https://doi.org/10.1016/j.psep.2021.08.014
Hansen B, Kusch P, Schulze M, Kamm B (2016) Qualitative and quantitative analysis of lignin produced from beech wood by different conditions of the Organosolv process. J Polym Environ 24:85–97. https://doi.org/10.1007/s10924-015-0746-3
Ajao O, Jeaidi J, Benali M, et al (2018) Quantification and variability analysis of lignin optical properties for colour-dependent industrial applications. Molecules 23. https://doi.org/10.3390/molecules23020377
Wen JL, Sun SL, Xue BL, Sun RC (2013) Recent advances in characterization of lignin polymer by solution-state nuclear magnetic resonance (NMR) methodology. Materials (Basel) 6:359–391. https://doi.org/10.3390/ma6010359
Hawkes GE, Smith CZ, Utley JHP et al (1993) A comparison of solution and solid state 13C NMR spectra of lignins and lignin model compounds. Holzforschung 47:302–312. https://doi.org/10.1515/hfsg.1993.47.4.302
Ralph J, Landucci L (2010) Chapter 5: NMR of lignins. In: Heitner C, Dimmel DR, Schmidt JA (eds) Lignin and lignans: Advances in chemistry. CRC Press (Taylor & Francis Group), Boca Raton FL, pp 137–243
Chen CL, Robert D (1988) Characterization of lignin by 1H and 13C NMR spectroscopy. Methods Enzymol 161:137–174. https://doi.org/10.1016/0076-6879(88)61017-2
Saboe PO, Tomashek EG, Monroe HR et al (2022) Recovery of low molecular weight compounds from alkaline pretreatment liquor via membrane separations††Electronic supplementary information (ESI) available. Green Chem 24:3152–3166. https://doi.org/10.1039/d2gc00075j
Cipriano DF, Chinelatto LS, Nascimento SA et al (2020) Potential and limitations of 13C CP/MAS NMR spectroscopy to determine the lignin content of lignocellulosic feedstock. Biomass Bioenergy 142:105792. https://doi.org/10.1016/j.biombioe.2020.105792
Suzuki S, Kurachi S, Wada N, Takahashi K (2021) Selective modification of aliphatic hydroxy groups in lignin using ionic liquid. Catalysts 11:1–17. https://doi.org/10.3390/catal11010120
Hynynen J, Riddell A, Achour A et al (2021) “Lignin and extractives first” conversion of lignocellulosic residual streams using UV light from LEDs. Green Chem 23:8251–8259. https://doi.org/10.1039/d1gc02543k
Gordobil O, Herrera R, Poohphajai F et al (2021) Impact of drying process on kraft lignin: lignin-water interaction mechanism study by 2D NIR correlation spectroscopy. J Market Res 12:159–169. https://doi.org/10.1016/j.jmrt.2021.02.080
Svenningsson L, Bengtsson J, Jedvert K et al (2021) Disassociated molecular orientation distributions of a composite cellulose–lignin carbon fiber precursor: a study by rotor synchronized NMR spectroscopy and X-ray scattering. Carbohydr Polym 254:117293. https://doi.org/10.1016/j.carbpol.2020.117293
Rana M, Nshizirungu T, Park J-H (2021) Synergistic effect of water-ethanol-formic acid for the depolymerization of industrial waste (black liquor) lignin to phenolic monomers. Biomass Bioenergy 153:106204. https://doi.org/10.1016/j.biombioe.2021.106204
Mei Q, Shen X, Liu H et al (2019) Selective utilization of methoxy groups in lignin for: N -methylation reaction of anilines. Chem Sci 10:1082–1088. https://doi.org/10.1039/c8sc03006e
Lu F, Wang C, Chen M et al (2021) A facile spectroscopic method for measuring lignin content in lignocellulosic biomass. Green Chem 23:5106–5112. https://doi.org/10.1039/d1gc01507a
Katahira R, Elder TJ, Beckham GT (2018) Chapter-1: A brief introduction to lignin structure. In: Beckham GT (ed) Lignin valorization: Emerging approaches, pp 1–20. https://doi.org/10.1039/9781788010351-00001
Author information
Authors and Affiliations
Contributions
Subhrajeet Dash—Investigation, Validation, Writing-original draft, Writing-review and editing.
Anjireddy Bhavanam—Conceptualization, Methodology, Writing-review and editing, Supervision, Project administration.
Poonam Gera—Visualization, Writing-review and editing, Supervision, Project administration.
Corresponding author
Ethics declarations
Ethical approval
Not applicable.
Competing interests
The authors declare no competing interests.
Additional information
Publisher's note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Dash, S., Bhavanam, A. & Gera, P. Parametric optimization of kraft pulping of wheat straw for extraction of lignin using response surface methodology. Biomass Conv. Bioref. (2023). https://doi.org/10.1007/s13399-023-04011-4
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s13399-023-04011-4