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Polyphenols in fruit and vegetable peel extract: procedure of selective extraction and method of analysis

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Abstract

The processed fruit and vegetable (F&V) include frozen, canned, and dried F&V. The peel weighs 10–15% of the total weight of the fruit. F&V are stripped before handling, which is practiced either by steam or abrasion, in turn, generating 5-kg water per kg of F&V peeled. The F&V peels are rich source of polyphenols like 4 hydroxy benzoic acid (4-HB). This study is the first attempt for the selective recovery of a representative polyphenol 4-HB using molecular imprinting technique from real F&V peel extract. Acrylamide functionalized chitosan was imprinted with 4-HB and cross-linked with epichlorohydrin to get molecularly imprinted adsorbent (AGCT-4HBIP; adsorption capacity 40 mg g−1), which effectively recovered 90.95% of 4-HB from the potato peel aqueous extract (PPAE). Fast and reliable HPLC method was developed and validated for 4-HB in PPAE with limit of quantization (LOQ) 0.5337μg mL−1. The developed method could effectively recover 4-HB from PPAE.

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Acknowledgements

PSD thanks Dr. Deepali Rahangdale and Ranjita Das for explanatory help.

Funding

The authors thank DST for financial support (Project Grant DST/ TDT/ TDP-02/ 2017) for directing the work.

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Authors and Affiliations

  1. Department of Chemical Engineering, Visvesvaraya National Institute of Technology, South Ambazari Road, Nagpur, 440010, India

    Praful S. Dadhe & Sachin A. Mandavgane

  2. Department of Chemistry, Visvesvaraya National Institute of Technology, South Ambazari Road, Nagpur, 440 010, India

    Anupama Kumar

Authors
  1. Praful S. Dadhe
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  2. Sachin A. Mandavgane
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  3. Anupama Kumar
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Contributions

Praful S. Dadhe: investigation, methodology, writing—original draft preparation

Dr. Sachin A. Mandavgane: supervision, editing manuscript, and funding

Anupama Kumar: supervision, conceptualization, and editing manuscript

Corresponding authors

Correspondence to Sachin A. Mandavgane or Anupama Kumar.

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The authors declare no competing interests

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Highlights

Molecular imprinting for resource recovery of value-added product

Selective recovery of 4-hydroxy benzoic acid from potato peel aqueous extract

HPLC method development and its validation

Selective separation of a moiety from dilute solution of 100 ppm

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Dadhe, P.S., Mandavgane, S.A. & Kumar, A. Polyphenols in fruit and vegetable peel extract: procedure of selective extraction and method of analysis. Biomass Conv. Bioref. 13, 3797–3807 (2023). https://doi.org/10.1007/s13399-021-01420-1

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  • DOI: https://doi.org/10.1007/s13399-021-01420-1

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