Abstract
Nanostructured duplex stainless steel (DSS) was prepared using mechanical alloying (MA) and spark plasma sintering (SPS). The ball milling was performed under nitrogen atmosphere. X-ray diffraction (XRD) and scanning electron microscope (SEM) were used to identify the phases and carry out morphological investigations, respectively. XRD spectra revealed that ferrite phase formation dominated during the initial stages and austenite phase emerged after several hours of ball milling. Lattice parameter calculations showed a decrease in lattice parameter up to 5 h and later increased at 10 h of milling. A decrease in crystallite size was observed up to 10 h of milling. SPS was performed in vacuum at an optimized temp. of 1000 °C for a fixed holding time of 10 min, heating rate of 100 °C/min, cooling rate of 200 °C/min and under an applied pressure of 50 MPa. The electrochemical performance of DSS alloys was examined using potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS). The results showed that alloy Fe-18Cr-3Mn-1Mo-1Si-0, 22N-5Ni (wt.%), has the highest corrosion resistance among the designed alloys.
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References
Karahan, T.; Emre, H.E.; Tümer, M.; Kacar, R.: Strengthening of AISI 2205 duplex stainless steel by strain ageing. Mater. Des. 1(55), 250–256 (2014)
Dobrzanski, L.A.; Brytan, Z.; Actis Grande, M.; Rosso, M.: Properties of duplex stainless steels made by powder metallurgy. Arch. Mater. Sci. Eng. 28, 217–223 (2007)
Wang, Y.Q.; Yang, B.; Han, J.; Dong, F.; Wang, Y.L.: Localized corrosion of thermally aged cast duplex stainless steel for primary coolant pipes of nuclear power plant. Procedia Eng. 36, 88–95 (2012)
Herenu, S.; Alvarez-Armas, I.; Armas, A.F.: The influence of dynamic strain ageing on the low cycle fatigue of duplex stainless steel. Scr. Mater. 45, 739–745 (2001)
Miyamoto, H.; Mirnaki, T.; Hashimoto, S.: Super plastic deformation of microspecimens of duplex stainless steel. Mater. Sci. Eng. A 319, 779–783 (2001)
Schofield, M.J.; Bradsha, R.; Cottis, R.A.: Stress corrosion cracking of duplex stainless steel weldments in sour conditions. Mater. Perform. 35, 65–70 (2009)
Mahale, R.S.; Shamanth, V.; Sharath, P.C.; Shashanka, R.; Hemanth, K.: A review on spark plasma sintering of duplex stainless steels. Mater. Today Proceed. 1(45), 138–144 (2021)
He, H.; Liu, Z.; Xie, Y.; Zhang, L.; Yi, X.; Ao, Fu.; Zhao, W.: A stochastic study of the effect of the phase ratio on the corrosion resistance of duplex stainless steel. Mater. Lett. 360, 136003 (2024)
Kurzydłowski, K.J.: Microstructural refinement and properties of metals processed by severe plastic deformation. Bull. Pol. Acad. Sci. Tech. Sci. 52, 275 (2004)
Gleiter, H.: Nanocrystalline Materials. Prog. Mater. Sci. 33, 223–315 (1989)
Gupta, R.K.; Birbilis, N.: The influence of nanocrystalline structure and processing route on corrosion of stainless steel: A review. Corr. Sci. 92, 1–15 (2015)
Gupta, R.K.; Raman, R.K.S.; Koch, C.C.; Murty, B.S.: Effect of nanocrystalline structure on the corrosion of a Fe20Cr alloy. Int. J. Electrochem. Sci. 8, 6791–6806 (2013)
Dobrzanski, L.A.; Brytan, Z.; Actis Grande, M.; Rosso, M.: Corrosion behavior of vacuum sintered duplex stainless steels. J. Mater. Process. Technol. 191, 161–164 (2007)
Suryanarayana, C.; Ivanov, E.: Advances in Powder Metallurgy: 3. Elsevier Science, Mechanochemical Synthesis of Nanocrystalline Metal Powders (2013)
Yang, Z.; Li, Y.; Zhigang, Xu.; Sun, Y.; Wang, P.; Cui, L.; Wang, T.: Characterization of σ-phase precipitation and effect on performance in duplex stainless steel S31803. Eng. Fail. Anal. 157, 107836 (2024)
Kurata, Y.; Futakawa, M.; Saito, S.: Comparison of the corrosion behavior of austenitic and ferritic/martensitic steels exposed to static liquid Pb–Bi at 450 and 550 °C. J. Nucl. Mater. 343, 333–340 (2005)
Ozturk, B.; Topcu, A.; Cora, O.N.: Influence of processing parameters on the porosity, thermal expansion, and oxidation behavior of consolidated Fe22Cr stainless steel powder. Powder Technol. 382, 199–207 (2021)
Ran, G.; Tu, W.; Dong, H.; Jiang, Y.; Li, J.; Liu, K.; Sun, Y.: Comparative statistical analysis of pitting in Two 2205 duplex stainless steel variants. NPJ Mater. Degrad. 8(1), 30 (2024)
Bautista, A.; Velasco, F.; Guzman, S.; De la Fuente, D.; Cayuela, F.; Morcillo, M.: Corrosion behavior of powder metallurgical stainless steels in urban and marine environments. Rev. Metal. 42, 175–184 (2006)
Velasco, F.; Bautista, A.: High-temperature oxidation and aqueous corrosion performance of ferritic, vacuum-sintered stainless steels prealloyed with Si. Corros. Sci. 51, 21–27 (2009)
Martin, F.; Garcia, C.; Blanco, Y.; Rodriguez-Mendez, M.L.: Influence of sinter-cooling rate on the mechanical properties of powder metallurgy austenitic, ferritic, and duplex stainless steels sintered in vacuum. Mater. Sci. Eng. A 642, 360–365 (2015)
Liu, X.; Ju, D.; Chen, L.: Effect of rare earth metals on passivation behavior of UNS S31803 duplex stainless steel in sulfuric acid solution. Constr. Build. Mater. 29(421), 135644 (2024)
Ahmed, J.; Toor, I.H.; Al-Aqeeli, N.: Effect of sintering temperature on the corrosion properties of nanostructured Fe-18Cr-2Si alloy prepared by SPS. Mater. Corros. 68, 361–367 (2017)
Pan, Y.; Sun, B.; Chen, H.; Liu, Z.; Dai, W.; Yang, X.; Yang, W.; Deng, Y.; Li, X.: Stress corrosion cracking behavior and mechanism of 2205 duplex stainless steel under applied polarization potentials. Corros. Sci. 1(231), 111978 (2024)
Bautista, A.; Moral, C.; Velasco, F.; Simal, C.; Guzmán, S.: Density-improved powder metallurgical ferritic stainless steels for high-temperature applications. J. Mater. Process. Technol. 189(1–3), 344–351 (2007)
Toor, I.-H.; Ahmed, J.; Hussein, M.A.; Al-Aqeeli, N.: Optimization of process parameters for spark plasma sintering of nano-structured ferritic Fe-18Cr-2Si alloy. Powder Technol. 299, 62–70 (2016)
Mariappan, R.; Kumaran, S.; Rao, T.S.: Effect of sintering atmosphere on structure and properties of austeno-ferritic stainless steels. Mater. Sci. Eng. A 517, 328–333 (2009)
Garcia, C.; Martin, F.; de Tiedra, P.; Cambronero, L.G.: Pitting corrosion behaviour of PM austenitic stainless steels sintered in nitrogen–hydrogen atmosphere. Corros. Sci. 49, 1718–1736 (2007)
Uzunsoy, D.: The characterisation of PM 304 stainless steel sintered in the presence of a copper based additive. Mater. Lett. 61, 10–15 (2007)
Kazior, J.; Nykiel, M.; Pieczonka, T.; Puscas, T.M.; Molinari, A.: Activated sintering of P/M duplex stainless steel powders. J. Mater. Process. Technol. 157–158, 712–717 (2004)
Nagesha, K.V.; Rajanish, M.; Shivappa, D.: A review on mechanical alloying. IJERA 3(3), 921–924 (2013)
Suryanarayanaa, C.; Ivanovb, E.; Boldyrevc, V.V.: The science and technology of mechanical alloying. Mater. Sci. Eng. A 304–306, 151–158 (2001)
Munir, Z.A.; Anselmi-Tamburini, U.; Ohyanagi, M.: The effect of electric field and pressure on the synthesis and consolidation of materials: a review of the spark plasma sintering method. J. Mater. Sci. 41, 763–777 (2006)
Garcia, C.; Martin, F.; Blanco, Y.; de Tiedra, M.P.; Aparicio, M.L.: Corrosion behaviour of duplex stainless steels sintered in nitrogen. Corros. Sci. 51, 76–86 (2009)
Garcia, C.; Martin, F.; Blanco, Y.; Tiedra, M.P.; Aparicio, M.L.: Influence of sintering under nitrogen atmosphere on microstructures of powder metallurgy duplex stainless steels. Metall. Mater. Trans. A 40, 292–301 (2009)
Dobrzanski, L.A.; Brytan, Z.; Grande, M.A.; Rosso, M.; Pallavicini, E.J.: Properties of vacuum sintered duplex stainless steels. J. Mater. Process. Technol. 162–163, 286–292 (2005)
Toor, I.H.: Effect of sintering holding time on the corrosion properties of nano-structured Fe-18Cr-2Si alloy prepared by SPS. Int. J. Electrochem. Sci. 11, 2897–2908 (2016)
Zhang, H.W.; Gopalan, R.; Mukai, T.; Hono, K.: Fabrication of bulk nanocrystalline Fe-C alloy by spark plasma sintering of mechanically milled powder. Scr. Mater. 53, 863–868 (2005)
Liu, Z.F.; Zhang, Z.H.; Lu, J.F.; Korznikov, A.V.; Korznikova, E.; Wang, F.C.: Effect of sintering temperature on microstructures and mechanical properties of spark plasma sintered nanocrystalline aluminum. Mater. Des. 64, 625–630 (2014)
Shashanka, R.; Chaira, D.: Development of nano-structured duplex and ferritic stainless steels by pulverisette planetary milling followed by pressureless sintering. Mater Charact 99, 220–229 (2015)
Yadav, R.; Vinay, G.; Kant, R.: Mechanical, metallurgical and corrosion analysis of forced cooling assisted laser bending of duplex-2205. Opt. Laser Technol. 175, 110804 (2024)
Toor, I.-H.; Ahmed, J.; Hussein, M.A.; Patel, F.; Al-Aqeeli, N.: Phase evolution studies during mechanical alloying of Fe(82–x)-Cr18-Six (x = 0, 1, 2, 3) alloy. J. Alloys Compd. 683, 463–469 (2016)
Patil, U.; Hong, S.J.; Suryanarayana, C.: An unusual phase transformation during mechanical alloying of an Fe-based bulk metallic glass composition. J. Alloys Compd. 389, 121–126 (2005)
Movahedi, B.; Enayati, M.H.; Wong, C.C.: Study on nanocrystallization and amorphization in Fe-Cr-Mo-B-P-Si-C system during mechanical alloying. Mater. Sci. Eng. B 172, 50–54 (2010)
Mote, V.; Purushotham, Y.; Dole, B.: Williamson-Hall analysis in estimation of lattice strain in nanometer-sized ZnO particles. J. Theor. Appl. Phys. 6(6), 1–8 (2012)
Yousefi, M.; Sharafi, S.: The effect of simultaneous addition of Si and Co on microstructure and magnetic properties of nanostructured iron prepared by mechanical alloying. Mater. Des. 37, 325–333 (2012)
Tehrani, F.; Abbasi, M.H.; Golozar, M.A.; Panjepour, M.: The effect of particle size of iron powder on α to γ transformation in the nanostructured high nitrogen Fe-Cr-Mn-Mo stainless steel produced by mechanical alloying. Mater. Sci. Eng. A 528(12), 3961–3966 (2011)
Shashanka, R.; Chaira, D.: Optimization of milling parameters for the synthesis of nano-structured duplex and ferritic stainless steel powders by high energy planetary milling. Powder Technol. 278, 35–45 (2015)
Isern, N.L.; Luque, H.L.; Jimenez, I.L.; Biezma, M.V.: Identification of sigma and chi phases in duplex stainless steels. Mater Charact 112, 41–46 (2016)
Lim, Y.S.; Kim, J.S.; Ahn, S.J.; Kwon, H.S.; Katada, Y.: The influences of microstructure and nitrogen alloying on pitting corrosion of type 316L and 20 wt.% Mn-substituted type 316L stainless steels. Corros. Sci. 43(1), 53–68 (2001)
Eklund, G.S.: Initiation of pitting at sulfide inclusions in stainless steel. J. Electrochem. Soc. 121, 467 (1974)
Park, K.J.; Kwon, H.: Manganese effects on repassivation kinetics and SCC susceptibility of high Mn–N austenitic stainless steel alloys. J. Electrochem. Soc. 154(9), C494 (2007)
Lee, J.S.; Kim, S.T.; Lee, I.S.; Kim, G.T.; Kim, J.S.; Park, Y.S.: Effect of copper addition on the active corrosion behavior of hyper duplex stainless steels in sulfuric acid. Mater. Trans. 53, 1048–1055 (2012)
Banas, J.; Mazurkiewicz, A.: The effect of copper on passivity and corrosion behaviour of ferritic and ferritic-austenitic stainless steels. Mater. Sci. Eng. A 277, 183–191 (2000)
Sourisseau, T.; Chauveau, E.; Baroux, B.: Mechanism of copper action on pitting phenomena observed on stainless steels in chloride media. Corr. Sci. 47, 1097–1117 (2005)
Oguzie, E.E.; Li, J.; Liu, Y.; Chen, D.; Li, Y.; Yang, K.; Wang, F.: The effect of Cu addition on the electrochemical corrosion and passivation behavior of stainless steels. Electrochim. Acta 55(17), 5028–5035 (2010)
Oh, K.; Ahn, S.; Kwon, H.: Effects of Cu on the passive film stability of Fe–20Cr–xCu (x= 0, 2, 4 wt.%) alloys in H2SO4 solution. Electrochim. Acta 15(88), 170–176 (2013)
Oh, K.; Toor, I.H.; Ahn, S.; Kwon, H.S.: Influence of Cu on the passivation behavior in sulfuric acid solution. Corrosion 69(6), 560–567 (2013)
Toor, I.H.; Ejaz, M.; Kwon, H.S.: Mott-Schottky analysis of passive films on Cu containing Fe-20Cr-xCu (x = 0, 4) alloys. Corros. Eng. Sci. Technol. 49, 390–395 (2014)
Pardo, A.; Merino, M.C.; Carboneras, M.; Coy, M.E.; Arrabal, R.: Pitting corrosion behaviour of austenitic stainless steels with Cu and Sn additions. Corros. Sci. 49, 510–525 (2007)
Kim, J.J.; Young, Y.M.: Study on the passive film of type 316 stainless steel. Int. J. Electrochem. Sci. 8, 11847–11859 (2013)
Shen, K.; Jiang, W.; Chong Sun, Yu.; Wan, W.Z.; Sun, J.: Insight into microstructure, microhardness and corrosion performance of 2205 duplex stainless steel: Effect of plastic pre-strain. Corros. Sci. 210, 110847 (2023)
Li, R.; Bin-guo, Fu.; Dong, T.-S.; Li, G.-l; Li, J.-K.; Zhao, X.-b; Liu, J.-H.: Effect of annealing treatment on microstructure, mechanical property and anti-corrosion behavior of X2CrNi12 ferritic stainless steel. J. Mater. Res. Technol. 18, 448–460 (2022)
Lopez, D.A.; Duran, A.; Cere, S.M.: Electrochemical characterization of AISI 316L stainless steel in contact with simulated body fluid under infection conditions. J. Mater. Sci. Mater. Med. 19, 2137–2144 (2008)
UreNaa, J.; Tsipasa, S.; Pinto, A.M.; Toptan, F.; Gordo, E.; Jimenez-Morales, A.: Corrosion and tribo corrosion behaviour of β-type Ti-Nb and Ti-Mo surfaces designed by diffusion treatments for biomedical applications. Corros. Sci. 140, 51–60 (2018)
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The authors would like to acknowledge the support provided by King Fahd University of petroleum & Minerals (KFUPM), Saudi Arabia, in conducting this research.
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Toor, IuH. Synthesis and Corrosion Performance Evaluation of Nanostructured Duplex Stainless Steel Alloys Prepared by MA and SPS. Arab J Sci Eng (2024). https://doi.org/10.1007/s13369-024-09091-6
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DOI: https://doi.org/10.1007/s13369-024-09091-6