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Development of Photochromic Authentication Patterns Using Self-Healable Sodium Alginate Hydrogel: Optical Strategy Toward Confidential Information Encryption

  • Research Article-Chemistry
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Abstract

Photochromic pattern with dual-mode fluorescence authentication was developed using a new self-healable nanocomposite hydrogel. A hybrid hydrogel of tricarboxy cellulose (TCC), sodium alginate (SA) and polyvinyl alcohol (PVA) was admixed with rare-earth doped aluminate (REA) nanoparticles (NPs) to produce inorganic–organic nanocomposite inks. The freezing and thawing procedures were used to prepare the TCC/SA/PVA composite hydrogel. TCC containing carboxylic substituents per anhydroglucose moiety was synthesized using one-pot oxidation technique, and PVA was dissolved in TCC aqueous solutions. To create transparent photochromic paper surface that changes color to green under UV illumination, a homogeneous film of REA@TCC/SA/PVA was imprinted directly onto paper surface. The luminous prints had a fluorescence peak at 519 nm once stimulated at 370 nm. The particles of the synthesized lanthanide-doped aluminate were measured to be between 9 and 33 nm in size using transmission electron microscope (TEM). X-ray powder diffraction was also employed to examine the structure of lanthanide-doped strontium aluminate. The morphological characteristics of stamped sheets were determined by a variety of analysis methods. The printed sheets displayed non-fatiguing reversible photochromism. The cytotoxicity of the prepared photoluminescent hydrogels was investigated. The mechanical performance of prints and hydrogel rheological properties were investigated. The prepared REA@TCC/SA/PVA hydrogel provides an efficient technique for a variety of authentications.

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Acknowledgements

The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work through Small group Research Project under grant number: RGP1/139/44

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  1. Department of Chemistry, Faculty of Science, King Khalid University, Abha, Saudi Arabia

    Aisha Hossan & Samar Y. Al nami

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  1. Aisha Hossan
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Correspondence to Aisha Hossan.

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Hossan, A., Al nami, S.Y. Development of Photochromic Authentication Patterns Using Self-Healable Sodium Alginate Hydrogel: Optical Strategy Toward Confidential Information Encryption. Arab J Sci Eng 49, 787–800 (2024). https://doi.org/10.1007/s13369-023-08488-z

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  • DOI: https://doi.org/10.1007/s13369-023-08488-z

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