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Influence of Surface Treatment of CaSO4 on the Drawability and Physical Properties of the PBAT/PLA/CaSO4 Composite Sheet

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An Erratum to this article was published on 08 October 2022

Abstract

This study investigated the effect of surface treatment of CaSO4 on the physical properties of the composite film manufactured using an inorganic additive CaSO4 and the biodegradable polymers, poly(butylene adipate-co-terephthalate) (PBAT) and poly(lactic acid) (PLA). Using a twin-screw extruder, the CaSO4 content of the PBAT/CaSO4 composite was prepared to be 1, 5, and 10 wt%, and the surface treatment of CaSO4 with stearic acid was studied for changes in mechanical properties and dispersibility of the composite. The surface-treated CaSO4 showed improved dispersion in the matrix polymer and improved strength and elongation compared to before surface treatment at all contents of the PBAT/CaSO4 composite. In addition, using a small amount of PLA, PBAT/PLA/CaSO4 composite sheets were prepared and biaxially stretched. The draw ratio of the PBAT/PLA/CaSO4 composite sheet was increased by CaSO4 surface treatment with stearic acid, and the mechanical properties of the stretched film were improved.

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References

  1. P. Rai, S. Mehrotra, S. Priya, E. Gnansounou, and S. K. Sharma, Bioresour. Technol., 124739 (2021).

    Google Scholar 

  2. F. Wu, M. Misra, and A. K. Mohanty, Prog. Polym. Sci., 101395 (2021).

    Google Scholar 

  3. R. Geyer, J. R. Jambeck, and K. L. Law, Sci. Adv., 3, e1700782 (2017).

    Article  PubMed  PubMed Central  Google Scholar 

  4. K. Hamad, M. Kaseem, and F. Deri, Polym. Degrad. Stab., 98, 2801 (2013).

    Article  CAS  Google Scholar 

  5. S. Lee, Y. Lee, and J. W. Lee, Macromol. Res., 15, 44 (2007).

    Article  CAS  Google Scholar 

  6. T. P. Haider, C. Völker, J. Kramm, K. Landfester, and F. R. Wurm, Angew. Chem. Int. Ed., 58, 50 (2019).

    Article  CAS  Google Scholar 

  7. S. Agarwal, Macromol. Chem. Phys., 221, 2000017 (2020).

    Article  CAS  Google Scholar 

  8. Y. Zhong, P. Godwin, Y. Jin, and H. Xiao, Adv. Ind. Eng. Polym. Res., 3, 27 (2020).

    Google Scholar 

  9. L. Manfra, V. Marengo, G. Libralato, M. Costantini, F. De Falco, and M. Cocca, J. Hazard. Mater., 416, 125763 (2021).

    Article  CAS  PubMed  Google Scholar 

  10. T. Zhang, W. Han, C. Zhang, and Y. Weng, Polym. Degrad. Stab., 183, 109455 (2021).

    Article  CAS  Google Scholar 

  11. Y. Yang, C. Zhang, and Y. Weng, Polym. Test., 102, 107334 (2021).

    Article  CAS  Google Scholar 

  12. M. Murariu and P. Dubois, Adv. Drug Delivery Rev., 107, 17 (2016).

    Article  CAS  Google Scholar 

  13. H.-Z. Li, S.-C. Chen, and Y.-Z. Wang, Ind. Eng. Chem. Res., 53, 17355 (2014).

    Article  CAS  Google Scholar 

  14. S.-Y. Gu, K. Zhang, J. Ren, and H. Zhan, Carbohydr. Polym., 74, 79 (2008).

    Article  CAS  Google Scholar 

  15. L. Jiang, B. Liu, and J. Zhang, Ind. Eng. Chem. Res., 48, 7594 (2009).

    Article  CAS  Google Scholar 

  16. D. B. Rocha, J. Souza de Carvalho, S. A. tde Oliveira, and D. dos Santos Rosa, J. Appl. Polym. Sci., 135, 46660 (2018).

    Article  Google Scholar 

  17. V. Titone, F. P. La Mantia, and M. C. Mistretta, Macromol. Mater. Eng., 305, 2000358 (2020).

    Article  CAS  Google Scholar 

  18. T. Zhang, C. Zhang, Y. Yang, F. Yang, M. Zhao, and Y. Weng, J. Appl. Polym. Sci., 50970 (2021).

    Google Scholar 

  19. I. Shainberg, M. Sumner, W. Miller, M. Farina, M. Pavan, and M. Fey, Adv. Soil Sci., 9, 1 (1989).

    Google Scholar 

  20. E. Caires, H. Joris, and S. Churka, Soil Use Manage., 27, 45 (2011).

    Article  Google Scholar 

  21. R. Prasad and Y. S. Shivay, Int. J. Bio-Resour. Stress Manage., 11, i (2020).

    CAS  Google Scholar 

  22. M. Rahmani, F. A. Ghasemi, and G. Payganeh, Mechanics Industry, 15, 63 (2014).

    Article  CAS  Google Scholar 

  23. Z. Cao, M. Daly, L. Clémence, L.M. Geever, I. Major, C.L. Higginbotham, and D. M. Devine, Appl. Surf. Sci., 378, 320 (2016).

    Article  CAS  Google Scholar 

  24. H. Huang, M. Tian, J. Yang, H. Li, W. Liang, L. Zhang, and X. Li, J. Appl. Polym. Sci., 107, 3325 (2008).

    Article  CAS  Google Scholar 

  25. T. Y. Chan and S. T. Lin, J. Am. Ceram. Soc., 78, 2746 (1995).

    Article  CAS  Google Scholar 

  26. M. Xu, G. Pan, Y. Cao, Y. Guo, H. Chen, Y. Wang, and Y. Wu, Surf. Interface Anal., 52, 626 (2020).

    Article  CAS  Google Scholar 

  27. X. Shi, R. Rosa, and A. Lazzeri, Langmuir, 26, 8474 (2010).

    Article  CAS  PubMed  Google Scholar 

  28. W. Liu, Z. Xie, X. Yang, Y. Wu, C. Jia, T. Bo, and L. Wang, J. Am. Ceram. Soc., 94, 1327 (2011).

    Article  CAS  Google Scholar 

  29. R.-Y. Wu and W.-C. J. Wei, J. Eur. Ceram. Soc., 20, 67 (2000).

    Article  CAS  Google Scholar 

  30. C. Liu, Q. Zhao, Y. Wang, P. Shi, and M. Jiang, Appl. Surf. Sci., 360, 263 (2016).

    Article  CAS  Google Scholar 

  31. Y. Liu, Planet. Space Sci., 163, 35 (2018).

    Article  CAS  Google Scholar 

  32. M. Al Dabbas, M. Y. Eisa, and W. H. Kadhim, Iraqi J. Sci., 55, 1916 (2014).

    Google Scholar 

  33. G. Anbalagan, S. Mukundakumari, K. S. Murugesan, and S. Gunasekaran, Vib. Spectrosc, 50, 226 (2009).

    Article  CAS  Google Scholar 

  34. B. Salvadori, V. Errico, M. Mauro, E. Melnik, and L. Dei, Spectrosc. Lett., 36, 501 (2003).

    Article  CAS  Google Scholar 

  35. H. A. Moghadam and A. Mirzaei, J. Build. Eng., 28, 101075 (2020).

    Article  Google Scholar 

  36. P. K. Mandal and T. K. Mandal, Cem. Concr. Res., 32, 313 (2002).

    Article  CAS  Google Scholar 

  37. H. Böke, S. Akkurt, S. Özdemir, E. Göktürk, and E. N. C. Saltik, Mater. Lett., 58, 723 (2004).

    Article  Google Scholar 

  38. S. Polat and P. Sayan, Indian Chem. Eng., 63, 363 (2021).

    Article  CAS  Google Scholar 

  39. Y. Xi, Y. Qi, Z. Mao, Z. Yang, and J. Zhang, Constr. Build. Mater., 266, 120916 (2021).

    Article  CAS  Google Scholar 

  40. Y.-X. Zeng, X.-W. Zhong, Z.-Q. Liu, S. Chen, and N. Li, J. Nanomater., 2013 (2013).

  41. G. Deshmukh, S. Pathak, D. Peshwe, and J. Ekhe, Bull. Mater. Sci., 33, 277 (2010).

    Article  CAS  Google Scholar 

  42. M. S. Huda, L. T. Drzal, A. K. Mohanty, and M. Misra, Compos. Sci. Technol., 68, 424 (2008).

    Article  CAS  Google Scholar 

  43. S. Karamipour, H. Ebadi-Dehaghani, D. Ashouri, and S. Mousavian, Polym. Test., 30, 110 (2011).

    Article  CAS  Google Scholar 

  44. R. Sahraeian, M. Esfandeh, and S. Hashemi, Polym. Polym. Compos., 21, 243 (2013).

    CAS  Google Scholar 

  45. R. Al-Itry, K. Lamnawar, and A. Maazouz, Polym. Degrad. Stab., 97, 1898 (2012).

    Article  CAS  Google Scholar 

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Author notes

  1. These authors contributed equally to this work as co-first authors.

Authors and Affiliations

  1. Department of Polymer Science and Engineering, Graduate School, Alan G. MacDiarmid Energy Research Institute Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju, 61186, Korea

    Young Jun Kong, Je Sung Youm & Yang Il Huh

  2. Space-Aeronautics & Advanced Non-Material Center, Jeonnam Technopark, 1448-345, Goheungman-ro, Goheug-eup, Goheung-gun, Jeonnam, 59532, Korea

    Tae Woong Kong

  3. Korea Institute of Industrial Technology, 6 Cheomdangwagiro 208gil, Buk-gu, Gwangju, 61012, Korea

    Jeong Cheol Kim

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  1. Young Jun Kong
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  2. Je Sung Youm
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  3. Tae Woong Kong
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  4. Yang Il Huh
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Correspondence to Jeong Cheol Kim.

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Supporting information

Information is available regarding the experimental results of SEM images of the CaSO4 particles, differential scanning calorimetry (DSC) thermograms, tensile stress and strain curves, and chemical structures of PBAT and SA. The materials are available via the Internet at http://www.springer.com/13233.

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Acknowledgment: This work was supported and funded by the Ministry of Trade, Industry and Energy (MOTIE, Korea) (No. 20003970).

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Kong, Y.J., Youm, J.S., Kong, T.W. et al. Influence of Surface Treatment of CaSO4 on the Drawability and Physical Properties of the PBAT/PLA/CaSO4 Composite Sheet. Macromol. Res. 30, 615–622 (2022). https://doi.org/10.1007/s13233-022-0072-2

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  • DOI: https://doi.org/10.1007/s13233-022-0072-2

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