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Omniphobic, ice-repellent, anti-bacterial, slippery liquid-infused porous surface (SLIPS) using sprayable chitin nanofiber coating

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Abstract

Here, we introduce a novel slippery lubricant-infused porous surface (SLIPS) based on chitin nanofibers (ChNF) coating. The ChNF porous coating layers are simply formed using a common spray-coating method, into which a perfluoropolyether (PFPE) oil is infused as the lubricant. The ChNF-based SLIPS is optically transparent and exhibits an excellent omniphobic liquid repellency towards both high-/low-surface-tension fluids. In addition, taking advantage of the simple material-processing combination, we also demonstrate a large-scale fabrication of the ChNF-based SLIPS on a non-flat surface and test common real-life complex fluids (e.g., Ketchup) to verify its practical applicability. In addition, the ChNF-based SLIPS possess an outstanding ice-phobicity with a low ice adhesion strength as well as excellent anti-bacterial property.

Graphical abstract

A multi-functional SLIPS (slippery liquid-infused porous surface) based on a spray-coatable chitin nanofiber (ChNF) coating as the porous surface is introduced. The ChNF-based SLIPS shows excellent omniphobic liquid repellency against both high-/low-surface-tension liquids with a low sliding angle (SA) of less than 5 degree. In addition, the ChNF-based SLIPS also shows an anti-bacterial property and a low ice adhesion strength verifying its ice-phobicity.

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References

  1. K. Liu, X. Yao, L. Jiang, Chem. Soc. Rev. 39, 3240 (2010)

    Article  CAS  PubMed  Google Scholar 

  2. A. Marmur, Langmuir 20, 3517 (2004)

    Article  CAS  PubMed  Google Scholar 

  3. N.A. Patankar, Langmuir 20, 8209 (2004)

    Article  CAS  PubMed  Google Scholar 

  4. S.S. Latthe, R.S. Sutar, V.S. Kodag, A. Bhosale, A.M. Kumar, K.K. Sadasivuni, R. Xing, S. Liu, Prog. Org. Coat. 128, 52 (2019)

    Article  CAS  Google Scholar 

  5. M. Ma, R.M. Hill, Current Opinion Colloid Interface Sci. 11, 193 (2006)

    Article  CAS  Google Scholar 

  6. R. Poetes, K. Holtzmann, K. Franze, U. Steiner, Phys. Rev. Lett. 105, 166104 (2010)

    Article  PubMed  Google Scholar 

  7. T.P. Nhung Nguyen, P. Brunet, Y. Coffinier, R. Boukherroub, Langmuir 26, 18369 (2010)

    Article  Google Scholar 

  8. P. Lv, Y. Xue, Y. Shi, H. Lin, H. Duan, Phys. Rev. Lett. 112, 196101 (2014)

    Article  PubMed  Google Scholar 

  9. D. Murakami, H. Jinnai, A. Takahara, Langmuir 30, 2061 (2014)

    Article  CAS  PubMed  Google Scholar 

  10. T.-S. Wong, S.H. Kang, S.K. Tang, E.J. Smythe, B.D. Hatton, A. Grinthal, J. Aizenberg, Nature 477, 443 (2011)

    Article  CAS  PubMed  Google Scholar 

  11. J.D. Smith, R. Dhiman, S. Anand, E. Reza-Garduno, R.E. Cohen, G.H. McKinley, K.K. Varanasi, Soft Matter 9, 1772 (2013)

    Article  CAS  Google Scholar 

  12. S. Barthwal, B. Lee, S.-H. Lim, Appl. Surf. Sci. 496, 143677 (2019)

    Article  Google Scholar 

  13. K. Manabe, T. Matsubayashi, M. Tenjimbayashi, T. Moriya, Y. Tsuge, K.-H. Kyung, S. Shiratori, ACS Nano 10, 9387 (2016)

    Article  CAS  PubMed  Google Scholar 

  14. V.T.T. Thuy, L.T. Hao, H. Jeon, J.M. Koo, J. Park, E.S. Lee, S.Y. Hwang, S. Choi, J. Park, D.X. Oh, Green Chem. 23, 2658 (2021)

    Article  CAS  Google Scholar 

  15. P. Kim, T.-S. Wong, J. Alvarenga, M.J. Kreder, W.E. Adorno-Martinez, J. Aizenberg, ACS Nano 6, 6569 (2012)

    Article  CAS  PubMed  Google Scholar 

  16. N. Vogel, R.A. Belisle, B. Hatton, T.-S. Wong, J. Aizenberg, Nat. Commun. 4, 2176 (2013)

    Article  Google Scholar 

  17. J. Li, E. Ueda, D. Paulssen, P.A. Levkin, Adv. Func. Mater. 29, 1802317 (2019)

    Article  Google Scholar 

  18. C. Howell, A. Grinthal, S. Sunny, M. Aizenberg, J. Aizenberg, Adv. Mater. 30, 1802724 (2018)

    Article  Google Scholar 

  19. S. Sunny, N. Vogel, C. Howell, T.L. Vu, J. Aizenberg, Adv. Func. Mater. 24, 6658 (2014)

    Article  CAS  Google Scholar 

  20. X. Huang, J.D. Chrisman, N.S. Zacharia, ACS Macro Lett. 2, 826 (2013)

    Article  CAS  PubMed  Google Scholar 

  21. J. Yin, M.L. Mei, Q. Li, R. Xia, Z. Zhang, C.H. Chu, Sci. Rep. 6, 1 (2016)

    Article  Google Scholar 

  22. P. Zhang, H. Chen, L. Zhang, D. Zhang, Appl. Surf. Sci. 385, 249 (2016)

    Article  CAS  Google Scholar 

  23. A.B. Tesler, P. Kim, S. Kolle, C. Howell, O. Ahanotu, J. Aizenberg, Nat. Commun. 6, 1 (2015)

    Article  Google Scholar 

  24. W. Ma, Y. Higaki, H. Otsuka, A. Takahara, Chem. Commun. 49, 597 (2013)

    Article  CAS  Google Scholar 

  25. I. Okada, S. Shiratori, ACS Appl. Mater. Interfaces 6, 1502 (2014)

    Article  CAS  PubMed  Google Scholar 

  26. J. Li, T. Kleintschek, A. Rieder, Y. Cheng, T. Baumbach, U. Obst, T. Schwartz, P.A. Levkin, ACS Appl. Mater. Interfaces 5, 6704 (2013)

    Article  CAS  PubMed  Google Scholar 

  27. T. Mahmut, H. Memon, F. Xu, I. Ahmed, X. Hou, Colloids Surf. A: Physicochem. Eng. Asp. 585, 124177 (2020)

    Article  Google Scholar 

  28. H. Agarwal, L.D.J. Quinn, S.C. Walter, T.J. Polaske, D.H. Chang, S.P. Palecek, H.E. Blackwell, D.M. Lynn, ACS Appl. Mater. Interfaces (2022)

  29. S. Anand, A.T. Paxson, R. Dhiman, J.D. Smith, K.K. Varanasi, ACS Nano 6, 10122 (2012)

    Article  CAS  PubMed  Google Scholar 

  30. J. Yong, J. Huo, Q. Yang, F. Chen, Y. Fang, X. Wu, L. Liu, X. Lu, J. Zhang, X. Hou, Adv. Mater. Interfaces 5, 1701479 (2018)

    Article  Google Scholar 

  31. S.-H. Jeong, J.-K. Kim, Y.-W. Lim, H.-B. Hwang, H.-Y. Kwon, B.-S. Bae, J. Jin, APL Mater. 6, 016102 (2018)

    Article  Google Scholar 

  32. S. Ifuku, M. Nogi, K. Abe, M. Yoshioka, M. Morimoto, H. Saimoto, H. Yano, Biomacromol 10, 1584 (2009)

    Article  CAS  Google Scholar 

  33. H. Hwang, S. Jang, J. Jin, Carbohyd. Polym. 281, 119051 (2022)

    Article  CAS  Google Scholar 

  34. J. Jin, D. Lee, H.G. Im, Y.C. Han, E.G. Jeong, M. Rolandi, K.C. Choi, B.S. Bae, Adv. Mater. 34, 5169 (2016)

    Article  Google Scholar 

  35. M. Rinaudo, Prog. Polym. Sci. 31, 603 (2006)

    Article  CAS  Google Scholar 

  36. J. Jin, V. Reese, R. Coler, D. Carter, M. Rolandi, Adv. Healthcare Mater. 3, 349 (2014)

    Article  CAS  Google Scholar 

  37. M.S. Hong, G.M. Choi, J. Kim, J. Jang, B. Choi, J.K. Kim, S. Jeong, S. Leem, H.Y. Kwon, H.B. Hwang, H.G. Im, J.-U. Park, B.-S. Bae, J. Jin, Adv. Func. Mater. 28, 1705480 (2018)

    Article  Google Scholar 

  38. K. Manabe, S. Nishizawa, K.-H. Kyung, S. Shiratori, ACS Appl. Mater. Interfaces 6, 13985 (2014)

    Article  CAS  PubMed  Google Scholar 

  39. T. Kondo, R. Kose, H. Naito, W. Kasai, Carbohyd. Polym. 112, 284 (2014)

    Article  CAS  Google Scholar 

  40. R. Maboudian, W.R. Ashurst, C. Carraro, Sens. Actuators A: Phys. 82, 219 (2000)

    Article  CAS  Google Scholar 

  41. L. Li, B. Li, J. Dong, J. Zhang, J. Mater. Chem. A 4, 13677 (2016)

    Article  CAS  Google Scholar 

  42. D. Quéré, Rep. Prog. Phys. 68, 2495 (2005)

    Article  Google Scholar 

  43. J. Bravo, L. Zhai, Z. Wu, R.E. Cohen, M.F. Rubner, Langmuir 23, 7293 (2007)

    Article  CAS  PubMed  Google Scholar 

  44. M. Miwa, A. Nakajima, A. Fujishima, K. Hashimoto, T. Watanabe, Langmuir 16, 5754 (2000)

    Article  CAS  Google Scholar 

  45. M.J. Kreder, J. Alvarenga, P. Kim, J. Aizenberg, Nat. Rev. Mater. 1, 1 (2016)

    Article  Google Scholar 

  46. Y. Wang, J. Xue, Q. Wang, Q. Chen, J. Ding, ACS Appl. Mater. Interfaces 5, 3370 (2013)

    Article  CAS  PubMed  Google Scholar 

  47. M.A. Sarshar, D. Song, C. Swarctz, J. Lee, C.-H. Choi, Langmuir 34, 13821 (2018)

    Article  CAS  PubMed  Google Scholar 

  48. C. Wang, W. Zhang, A. Siva, D. Tiea, K. Wynne, Langmuir 30, 540 (2014)

    Article  CAS  PubMed  Google Scholar 

  49. X. Yin, Y. Zhang, D. Wang, Z. Liu, Y. Liu, X. Pei, B. Yu, F. Zhou, Adv. Func. Mater. 25, 4237 (2015)

    Article  CAS  Google Scholar 

  50. Q. Liu, Y. Yang, M. Huang, Y. Zhou, Y. Liu, X. Liang, Appl. Surf. Sci. 346, 68 (2015)

    Article  CAS  Google Scholar 

  51. J.S. Association (2000)

  52. A.K. Epstein, T.-S. Wong, R.A. Belisle, E.M. Boggs, J. Aizenberg, Proc. Natl. Acad. Sci. 109, 13182 (2012)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

Download references

Acknowledgements

This research is supported by National R&D Program through the National Research Foundation of Korea (NRF) grant funded by Ministry of Science and ICT (2022R1A2B5B0100139411, 2022M3H4A1A03076577).

Funding

This study was funded by National Research Foundation of Korea, 2022R1A2B5B0100139411, Jungho Jin, 2022M3H4A1A03076577, Jungho Jin.

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Kwon, HY., Jin, J. Omniphobic, ice-repellent, anti-bacterial, slippery liquid-infused porous surface (SLIPS) using sprayable chitin nanofiber coating. Macromol. Res. 31, 65–74 (2023). https://doi.org/10.1007/s13233-022-00107-4

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