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Iron and copper based catalysts containing anionic phenolate ligands for atom transfer radical polymerization

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Abstract

Iron and copper complexes with anionic phenolate-bis(pyridyl)amine ligands were synthesized and examined as catalysts for atom transfer radical polymerization (ATRP) of methyl (meth)acrylate and styrene. With copper complexes, polymers with narrow molecular weight distributions, M w /M n ~1.2, were prepared. The catalytic performance of copper catalysts was affected by nature of halogen species and by the steric and electronic effects. In iron-mediated ATRP procedures, the number-average molecular weights of the polymers increased with monomer conversion, however, the molecular weight distributions of the resulting polymers were relatively broad M w /M n ~1.7, due to slow deactivation processes.

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  1. Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania, 15213, USA

    Chiaki Nishiura, Valerie Williams & Krzysztof Matyjaszewski

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  1. Chiaki Nishiura
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  2. Valerie Williams
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Correspondence to Krzysztof Matyjaszewski.

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Acknowledgments: Support from NSF (CHE 1707490) is gratefully acknowledged.

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Nishiura, C., Williams, V. & Matyjaszewski, K. Iron and copper based catalysts containing anionic phenolate ligands for atom transfer radical polymerization. Macromol. Res. 25, 504–512 (2017). https://doi.org/10.1007/s13233-017-5118-5

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