Abstract
The blends of two crosslinked polystyrene-b-polyisoprene (PS-b-PI) copolymers with homopolystyrene were investigated for their dynamic mechanical properties. Elastomeric block copolymer nanofibers utilized as filler were prepared by employing the phase separation property of a polystyrene-b-polyisoprene copolymer, which was then exposed to a crosslinking agent (S2Cl2) for cold vulcanization. The crosslinking density and morphology of nanofillers resulted in three elastomeric block copolymer nanofillers: fully cross-linked nanofiber (FCF), fully crosslinked multi-junctioned nanofiber (FCM), and partially crosslinked multi-junctioned sample (PCM). Uncrosslinked PS-PI block copolymer (UBC) was also studied as a comparison. Crosslinking density was calculated by measuring the change in intensity of the double bond peaks using FTIR spectroscopy. Thermo-mechanical properties and morphology of the blends were characterized by dynamic mechanical analysis (DMA) and scanning electron microscope (SEM). DMA results show that modulus increases with increasing filler loading in the terminal region for both PS/FCM and PS/FCF systems and the increasing rate is related to crosslinking density.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. Cadek, J. N. Coleman, V. Barron, K. Hedicke, and W. J. Blau, Appl. Phys. Lett., 81, 5123 (2002).
J. N. Coleman, U. Khan, and Y. K. Gun'ko, Adv. Mater., 18, 689 (2006).
P. C. LeBaron, Z. Wang, and T. J. Pinnavaia, Appl. Clay Sci., 15, 11 (1999).
F. Croce, G. B. Appetecchi, L. Persi, and B. Scrosati, Nature, 394, 456 (1998).
R. Gangopadhyay and A. De, Chem. Mater., 12, 608 (2000).
L. L. Beecroft and C. K. Ober, Chem. Mater., 9, 1302 (1997).
Y. S. Thio, A. S. Argon, R. E. Cohen, and M. Weinberg, Polymer, 43, 3661 (2002).
J. X. Wu, Y. S. Thio, and F. S. Bates, J. Polym. Sci., Part B: Polym. Phys., 43, 1950 (2005).
A. J. Crosby and J. Y. Lee, Polym. Rev., 47, 217 (2007).
G. H. Chen, D. J. Wu, W. G. Weng, and W. L. Yan, J. Appl. Polym. Sci., 82, 2506 (2001).
S. Kumar, M. A. Alam, and J. Y. Murthy, Appl. Phys. Lett., 90 (2007).
J. Li, S. Guo, Y. Zhai, and E. Wang, Electrochem. Commun., 11, 1085 (2009).
A. R. Abramson, W. C. Kim, S. T. Huxtable, H. Q. Yan, Y. Y. Wu, A. Majumdar, C. L. Tien, and P. D. Yang, J. Microelectromech. Syst., 13, 505 (2004).
R. Asaletha, M. G. Kumaran, and S. Thomas, Eur. Polym. J., 35, 253 (1999).
S. George, K. Ramamurthy, J. S. Anand, G. Groeninckx, K. T. Varughese, and S. Thomas, Polymer, 40, 4325 (1999).
J. Glazer, Nature, 167, 404 (1951).
G. J. Liu, X. H. Yan, and S. Duncan, Macromolecules, 35, 9788 (2002).
G. J. Liu, Z. Li, and X. H. Yan, Polymer, 44, 7721 (2003).
A. P. Chatterjee and D. A. Prokhorova, J. Appl. Phys., 101 (2007).
R. A. Pearson and A. F. Yee, J. Mater. Sci., 24, 2571 (1989).
K. J. Ishizu and A. Onen, J. Polym. Sci., Part A: Polym. Chem., 27, 3721 (1989).
T. Hashimoto, H. Tanaka, and H. Hasegawa, Macromolecules, 23, 4378 (1990).
J. D. Ferry, Viscoleastic Properties of Polymers, Wiley, New York, 1980.
D. G. H. Ballard, G. D. Wignall, and J. Schelten, Eur. Polym. J., 9, 965 (1973).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ma, S., Thio, Y. Dynamic mechanical properties of elastomeric nanoparticle composites. Macromol. Res. 24, 915–923 (2016). https://doi.org/10.1007/s13233-016-4121-6
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13233-016-4121-6