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Dimensionally stable and light-colored polyimide hybrid reinforced with layered silicate

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Abstract

Light-colored polyimide hybrids with a quaternary alkylammonium modified montmorillonite, Cloisite® 20A (C20A) were successfully synthesized via a solution intercalation method. The structural and morphological features of the PI/C20A hybrids were characterized by Fourier transform infrared (FTIR) spectroscopy, wide-angle X-ray diffraction (WAXD), field emission scanning electron microscopy (FE-SEM), and spherical aberration correction scanning transmission electron microscope (STEM). The dimensional stabilities were strongly dependent upon the chemical and morphological structures which were influenced by the Cloisite® 20A loading content. A critical Cloisite® 20A concentration was obtained for the evolution of both the structural and physical properties of the PI/C20A hybrids. The dynamic stress behaviors were investigated in situ by using the wafer bending method during thermal imidization of the softbaked PI/C20A hybrid precursor and thermally cured hybrid films using a thin film stress analyzer. The PI/C20A hybrid films exhibited stability at 510 °C, high glass transition and relatively low coefficient of thermal expansion, and an improved solvent resistance capacity.

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Authors and Affiliations

  1. Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 03722, Korea

    Ki-Ho Nam & Haksoo Han

  2. Carbon Composite Materials Research Center, Institute of Advanced Composites Materials, Korea Institute of Science and Technology, Eunha-ri san 101, Bondong-eup, Wanju-gun, Jeonbuk, 55324, Korea

    Ki-Ho Nam & Bon-Cheol Ku

  3. Department of Chemical Engineering, Kyung Hee University, 1 Seocheon-Dong, Giheung-gu, Yongin Gyeonggi, 17104, Korea

    Sejeong Kim & Sang-Hyon Paek

  4. Agency for Defense Development, Yuseong-gu, Daejeon, 34060, Korea

    Jungkun Song & Seungsu Baek

Authors
  1. Ki-Ho Nam
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  2. Sejeong Kim
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  3. Jungkun Song
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  4. Seungsu Baek
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  5. Sang-Hyon Paek
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  6. Bon-Cheol Ku
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  7. Haksoo Han
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Correspondence to Haksoo Han.

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Nam, KH., Kim, S., Song, J. et al. Dimensionally stable and light-colored polyimide hybrid reinforced with layered silicate. Macromol. Res. 24, 104–113 (2016). https://doi.org/10.1007/s13233-016-2021-9

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  • DOI: https://doi.org/10.1007/s13233-016-2021-9

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