Abstract
Liquefied petroleum gas (LPG) is used as fuel for cooking, heating, and transportation globally. This gas is highly inflammable, poisonous, explosive, and hazardous, and it creates several health issues when inhaled. Thus, its leakage detection is of the utmost importance. There are several sensors used for LPG detection, but they have a high operating temperature; therefore, developing sensors that work at normal temperatures has always been a challenge. This paper describes the synthesis of bismuth (Bi)-doped Praseodymium orthoferrite (PrFeO3) nanomaterials by the sol–gel self-combustion technique and their application in LPG detection. The synthesized nanomaterials were characterized using powder X-ray diffraction (PXRD), field emission scanning electron microscope (FESEM), Brunauer–Emmett–Teller (BET), ultraviolet–visible spectroscopy (UV–Vis), and Fourier transform infrared spectroscopy (FTIR). PXRD reveals that the synthesized nanomaterial has an orthorhombic structure with the Pbnm space group, and the crystallite size (D) changes from 30 to 41 nm. FESEM was used for the analysis of surface morphology. BET analysis reveals the mesoporous nature of synthesized nanomaterials with a 16.331 to 37.645 m2g−1 specific surface area. UV–Vis spectroscopy affirms the optical energy band gap lying between 2.27 and 1.95 eV. The FTIR study represents the existence of different functional groups and their lattice vibration. Synthesized nanomaterials were explored as an LPG detector working at room temperature for the first time. Different sensing parameters have been evaluated. The gas sensing studies reveal that the response and recovery times are 15.3 and 22.4 s for 0.5 vol% of LPG, and the sensor shows high selectivity towards LPG. This study reveals that the designed sensor is capable of working at room temperature, and the synthesized nanomaterials are promising for LPG sensing.
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References
Ahirrao RB, Pawar VN, Bagul SD (2021) CuO-modified SrTiO3 thick film resisters for LPG sensing. Mazedan Chem Res J 2:4–9
Aishwarya K, Nirmala R, Navamathavan R (2021) Recent advancements in liquefied petroleum gas sensors: a topical review. Sens Int 2:100091. https://doi.org/10.1016/j.sintl.2021.100091
Anju AA, Aghamkar P, Lal B (2017) Structural and multiferroic properties of barium substituted bismuth ferrite nanocrystallites prepared by sol-gel method. J Magn Magn Mater 426:800–805. https://doi.org/10.1016/j.jmmm.2016.09.103
Bonilla JTG, Bonilla HG, Rodríguez-Betancourtt VM, Bonilla AG, Zamora AC, Alonso OB, Ortega JAR (2021) A gas sensor for application as a propane leak detector. J Sens 2021:8871166. https://doi.org/10.1155/2021/8871166
Chavali MS, Nikolova MP (2019) Metal oxide nanoparticles and their applications in nanotechnology. S N Appl Sci 1:607. https://doi.org/10.1007/s42452-019-0592-3
Chen Y, Wang D, Qin H, Zhang H, Zhang Z, Zhou G, Gao C, Hu J (2019) CO2 sensing properties and mechanism of PrFeO3 and NdFeO3 thick film sensor. J Rare Earths 37:80–87. https://doi.org/10.1016/j.jre.2018.06.007
Cui X, Zhang Z, Yang J, Ren Z, Zhou H, Shi C, Meng F, Feng J, Zhao S (2023a) Chemical mechanical polishing for potassium dihydrogen phosphate using four kinds of green developed slurries. J Manuf Process 101:1158–1166. https://doi.org/10.1016/j.jmapro.2023.06.065
Cui X, Zhang Z, Yu S, Chen X, Shi C, Zhou H, Meng F, Yu J, Wen W (2023b) Unprecedented atomic surface of silicon induced by environmentally friendly chemical mechanical polishing. Nanoscale 15(21):9304–9314. https://doi.org/10.1039/D3NR01149F
Dhawale DS, Lokhande CD (2011) Chemical route to synthesis of mesoporous ZnO thin films and their liquefied petroleum gas sensor performance. J Alloy Compd 509:10092–10097. https://doi.org/10.1016/j.jallcom.2011.08.046
Freeman E, Kumar S, Thomas SR, Pickering H, Fermin DJ, Eslava S (2020) PrFeO3 photocathodes prepared through spray pyrolysis. ChemElectroChem 7:1365–1372. https://doi.org/10.1002/celc.201902005
Gao F, Chen XY, Yin KB, Dong S, Ren ZF, Yuan F, Yu T, Zou ZG, Liu JM (2007) Visible-light photocatalytic properties of weak magnetic BiFeO3 nanoparticles. Adv Mater 19(19):2889–2892. https://doi.org/10.1002/adma.200602377
Haridas D, Sreenivas K, Gupta V (2008) Improved response characteristics of SnO2 thin film loaded with nanoscale catalysts for LPG detection. Sens Actuators B Chem 133:270–275. https://doi.org/10.1016/j.snb.2008.02.030
Janbutrach Y, Hunpratub S, Swatsitang E (2014) Ferromagnetism and optical properties of La1−xAlxFeO3 nanopowders. Nanoscale Res Lett 9:498. https://doi.org/10.1186/1556-276X-9-498
Jena B, Pradhan SK, Jha R, Goel S, Sharma R (2023) LPG gas leakage detection system using IoT. Mater Today Proc 74:795–800. https://doi.org/10.1016/j.matpr.2022.11.172
Jumaa NK, Abdulkhaleq YM, Nadhim MA, Abbas TA (2022) IoT based gas leakage detection and alarming system using Blynk platforms. Iraqi J Electr Electron Eng 18:64–70. https://doi.org/10.37917/ijeee.18.1.8
Li L, Zhang M, Tian P, Gu W, Wang X (2014) Synergistic photocatalytic activity of LnFeO3 (Ln=Pr, Y) perovskites under visible-light illumination. Ceram Int 40:13813–13817. https://doi.org/10.1016/j.ceramint.2014.05.097
Li Y, Zhang Z, Yang J, Ren Z, Zhao S (2023) A novel green waterless and oilless chemical mechanical polishing for soft-brittle, temperature-sensitive and deliquescent potassium dihydrogen phosphate. Surfa Interfaces 40:103117. https://doi.org/10.1016/j.surfin.2023.103117
Liao L, Zhang Z, Meng F, Liu D, Wu B, Li Y, Xie W (2021) A novel slurry for chemical mechanical polishing of single crystal diamond. Appl Surf Sci 564:150431. https://doi.org/10.1016/j.apsusc.2021.150431
Liu L, Zhang Z, Shi C, Zhou H, Liu D, Li Y, Xu G, Feng J, Meng F (2023a) Atomic surface of fused silica and polishing mechanism interpreted by molecular dynamics and density unctional theory. Mater Today Sustain 23:100457. https://doi.org/10.1016/j.mtsust.2023.100457
Liu J, Zhang Z, Shi C, Ren Z, Feng J, Zhou H, Liu Z, Meng F, Zhao S (2023b) Novel green chemical mechanical polishing of fused silica through designing synergistic CeO2/h-BN abrasives with lubricity. Appl Surf Sci 637:157978. https://doi.org/10.1016/j.apsusc.2023.157978
Naik MC, Bamane SR, Pakhare KS, Potdar SS (2022) Novel synthesis of perovskite GdxAl1–XO3 semiconductor by combustion route for selective LPG sensing. Bull Mater Sci 45(3):123. https://doi.org/10.1007/s12034-022-02716-2
Patil LA, Suryawanshi DN, Pathan IG, Patil DG (2014) Effect of firing temperature on gas sensing properties of nanocrystalline perovskite BaTiO3 thin films prepared by spray pyrolysis techniques. Sens Actuators B Chem 195:643–650. https://doi.org/10.1016/j.snb.2013.12.048
Prasad BV, Rao GN, Chen JW, Babu DS (2012) Colossal dielectric constant in PrFeO3 semiconductor ceramics. Solid State Sci 14:225–228. https://doi.org/10.1016/j.solidstatesciences.2011.11.016
Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomie distances in halides and chaleogenides. Acta Crystallogr Sect a Cryst Phys Diffr Theor Gen Crystallogr 32:751–767. https://doi.org/10.1107/S0567739476001551
Shinde SR, Shinde VP (2022) Liquefied petroleum gas sensing performance of solochemically synthesized ZnO Nanorods: role of precursors and fractal analysis. Sens Actuators A 345:113800. https://doi.org/10.1016/j.sna.2022.113800
Singh S, Singh A, Yadav BC, Dwivedi PK (2013) Fabrication of nanobeads structured perovskite type neodymium iron oxide film: its structural, optical, electrical and LPG sensing investigations. Sens Actuators B Chem 177:730–739. https://doi.org/10.1016/j.snb.2012.11.096
Singh M, Yadav BC, Ranjan A, Kaur M, Gupta SK (2017a) Synthesis and characterization of perovskite barium titanate thin film and its application as LPG sensor. Sens Actuators B Chem 241:1170–1178. https://doi.org/10.1016/j.snb.2016.10.018
Singh M, Yadav BC, Ranjan A, Sonker RK, Kaur M (2017b) Detection of liquefied petroleum gas below lowest explosion limit (LEL) using nanostructured hexagonal strontium ferrite thin film. Sens Actuators B Chem 249:96–104. https://doi.org/10.1016/j.snb.2017.04.075
Singh A, Kumar K, Sikarwar S, Yadav BC (2022) Highly sensitive and selective LPG sensor working below lowest explosion limit (LEL) at room temperature using as-fabricated indium doped SnO2 thin film. Mater Chem Phys 287:126275. https://doi.org/10.1016/j.matchemphys.2022.126275
Tijare SN, Bakardjieva S, Subrt J, Joshi MV, Rayalu SS, Hishita S, Labhsetwar N (2014) Synthesis and visible light photocatalytic activity of nanocrystalline PrFeO3 perovskite for hydrogen generation in ethanol-water system. J Chem Sci 126:517–525. https://doi.org/10.1007/s12039-014-0596-x
Xu G, Zhang Z, Meng F, Liu L, Liu D, Shi C, Cui X, Wang J, Wen W (2023) Atomic-scale surface of fused silica induced by chemical mechanical polishing with controlled size spherical ceria abrasives. J Manuf Process 85:783–792. https://doi.org/10.1016/j.jmapro.2022.12.008
Yadav A, Yadav BC (2015) Experimental investigations on solid state LPG sensor using ZnFe2O4 nanocomposite prepared by Co-precipitation method. J Mater Sci Eng B 5(1112):435–445. https://doi.org/10.17265/2161-6221/2015.11-12.004
Yadav AK, Singh RK, Singh P (2016) Fabrication of lanthanum ferrite based liquefied petroleum gas sensor. Sens Actuators B Chem 229:25–30. https://doi.org/10.1016/j.snb.2016.01.066
Zakaria Z, Idroas M, Samsuri A, Adam AA (2017) Ultrasonic instrumentation system for liquefied petroleum gas level monitoring. J Nat Gas Sci Eng 45:428–435. https://doi.org/10.1016/j.jngse.2017.05.006
Zhang Z, Cui J, Zhang J, Liu D, Yu Z, Guo D (2019) Environment friendly chemical mechanical polishing of copper. Appl Surf Sci 467–468:5–11. https://doi.org/10.1016/j.apsusc.2018.10.133
Zhang Z, Liao L, Wang X, Xie W, Guo D (2020) Development of a novel chemical mechanical polishing slurry and its polishing mechanisms on a nickel alloy. Appl Surf Sci 506:144670. https://doi.org/10.1016/j.apsusc.2019.144670
Acknowledgements
Keval Bharati is thankful to the CSIR, U. G. C., New Delhi, India, for providing financial assistance in form of Senior Research Fellowship.
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Bharati, K., Tiwari, P.R., Singh, R.P. et al. Synthesis of bismuth-doped praseodymium ortho ferrite nanomaterials for LPG sensing. Appl Nanosci 14, 277–289 (2024). https://doi.org/10.1007/s13204-023-02976-2
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DOI: https://doi.org/10.1007/s13204-023-02976-2