Abstract
Al, Ga and B silicate hierarchical zeolites of structural types MOR, BEA, MFI and MTW with morphology of nanorods, nanolayers or nanoparticles, due to the presence of optimal strength of Brønsted acid centers are active and highly selective catalysts for indanol dehydration in mild conditions (yield of the target product up to 99%). Ga and B silicate hierarchical zeolites with low and medium acidity show moderate yields in Beckman rearrangement of oximes. Hierarchical aluminosilicate zeolites of structural types MOR, BEA and MFI of different morphology show high activity in the process of n-hexane cracking, which allows us to consider them as promising catalysts for this reaction. Formation of the basic centers in zeolite composites with different nature and structure allows obtaining effective catalysts for the cycloaddition reactions under carbon dioxide pressure.
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The authors declare that the data supporting the findings of this study are available within the paper. Should any raw data files be needed in another format they are available from the corresponding author upon reasonable request.
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Acknowledgements
The authors gratefully acknowledge the financial support of the National Research Foundation of Ukraine to the project “New effective zeolite catalysts for environmentally friendly processes of the conversion of renewable raw materials into valuable organic compounds” (project number 2020.02/0335).
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Shvets, O.V., Kurmach, M.M., Yaremov, P.S. et al. Zeolite nanocomposites with variable acid and basic properties: effective catalysts for fine chemical synthesis and industrial reaction. Appl Nanosci 13, 7545–7553 (2023). https://doi.org/10.1007/s13204-023-02955-7
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DOI: https://doi.org/10.1007/s13204-023-02955-7