Abstract
The Terbium (III) complexes [Tb(III)-water, mixed-ligand complex Tb(III)-phenanthroline] with 2-methyl-5-phenyl-1-pentene-3,5-dione were synthesized. The polycomplex was obtained by free-radical polymerization. The results of above studies have shown that the configuration of the chelate unit is unchanged during the polymerization. As a result, the type of coordination was determined and the structure of coordination polyhedra was assumed. The luminescence spectra of obtained metallocomplexes and polymer were investigated and analyzed. The solubilization of terbium complex with phenanthroline, was shown to change luminescence intensity in this complex.
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Irina, S., Oleksandra, B., Olena, T. et al. Monomer and metallopolymer compounds of Tb(III) as precursors for OLEDs. Appl Nanosci 9, 787–793 (2019). https://doi.org/10.1007/s13204-018-0736-6
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DOI: https://doi.org/10.1007/s13204-018-0736-6