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Influence of Halide Ions on Anodic Oxidation of Ethanol on Palladium

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Abstract

Ethanol oxidation on polycrystalline palladium electrodes in alkaline media was studied in the presence of halide ions. Addition of halide ions decreased the ethanol oxidation peak current monotonically as a function of increasing halide concentration. The extent of poisoning was found to be in the order I− > Br− > Cl−. Thus, Cl− ions show appreciable inhibition of ethanol oxidation peak current at [Cl−] ~ 10−3 M, whereas Br− and I− inhibit ethanol oxidation even at [Br−] or [I−] ~ 10−6 M. The potential of the ethanol oxidation peak shifted positive with increasing halide ion concentration. The extent of the shift was found to be in the order I− > Br− > Cl−. This study is relevant due to the widespread use of palladium halide complexes in the production of Pd electrocatalysts for ethanol oxidation and other electrocatalytic reactions.

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Acknowledgments

This material is based upon work supported by the National Science Foundation under grant CHE-0957122.

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  1. Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ, 85287-1604, USA

    Ashok Kumar & Daniel A. Buttry

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Kumar, A., Buttry, D.A. Influence of Halide Ions on Anodic Oxidation of Ethanol on Palladium. Electrocatalysis 7, 201–206 (2016). https://doi.org/10.1007/s12678-015-0298-2

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