Abstract
In the present paper, the corrosion behavior of Hf-rich Hf64Cu18Ni18 (at%) metallic glass (MG) was studied in acidic and alkaline media using electrochemical polarization experiments. Three different molar solutions of NaOH and HCl were used for the experiments. The results show that the glassy alloy possesses significantly high corrosion resistance in alkaline solution than acidic one. Pits are observed on the sample in acidic media, whereas alkaline sample does not show pitting. In both the solutions, primarily, HfO2 is formed on the surface as a corrosion product. The corroded surface is non-uniformly distributed on the ribbon and found to decrease with concentration of NaOH. The non-uniform distribution is attributed to inhomogeneity in the ribbon sample. In case of HCl solution, corroded surface increases with the increase in HCl concentration. Furthermore, an attempt has been made to understand the corrosion mechanism of this MG in view of phases formed during the experiment.
Similar content being viewed by others
References
Wang W H, Dong C, and Shek C H, Mater Sci Eng R 44 (2004) 45.
Suryanarayana C, Non-equilibrium processing of material, Oxford, U.K. Pergamon, (1999) p 318.
Greer A L, Cheng Y Q, and Ma E, Mat Sci Eng R 74 (2013) 71.
Yavari A R, Lewandowski J J, and Eckert J, MRS Bull 32 (2007) 635.
Suryanarayana C,and Inoue A, Bulk Metallic glasses, CRC Press, Boca Raton, FL, (2001) p 481.
Zander D, Heisterkamp B, and Gallino I, J. Alloys Compd 434-435 (2007) 234.
Gostin P F, Gebert A, and Schultz L, Corros Sci 52 (2010) 273–281.
Wang Z M, Zhang J, Chang X C, Hou W L, and Wang J Q, Corros Sci 52 (2010) 1342.
Gebert A, Gostin P F, and Schultz L, Corros Sci 52 (2010) 1711.
Lu H B, Li Y, and Wang F H, Corros Sci 48 (2006) 2106.
Kawashima A, Ohmura K, Yokoyama Y, and Inoue A, Corros Sci 53 (2011) 2778.
Si J J, Chen X H, Cai Y H, Wu Y D, Wang T, and Hui X H, Corros Sci 107 (2016) 123.
Cai A H, Xiong X, Liu Y, An W K, Zhou G J, Luo Y, and Li T L, Mater Chem Phys 134 (2012) 938.
Lin H M, Wu J K, Wang C C, and Lee P Y, Mater Lett 62 (2008) 2995.
Babilas R, Bajorek A, Simka W, and Babilas D, Electrochim Acta 209 (2016) 632.
Gebert A, Haehnel V, Park E S, Kim D H, and Schultz L, Electrochim Acta 53 (2008) 3403
Chlewicka M, Cieslak G, and Mizera J, Mater Corros 70 (2019) 2073.
Huang C H, Lai J J, Huang J C, Lin C H, and Jang J S C, Mater Sci Eng C 62 (2016) 368.
Li G, Huang L, Dong Y G, He G W, Qi L, Jing Q, Ma M Z, and Liu R P, Sci China Phys Mech Astron 53 (2010) 435.
Chattoraj I, Baunack S, Stoica M, and Gebert A, Mater Corros 55 (2004) 36.
Li C, Wang L, and Inoue A, Mater Lett 51 (2001) 203.
Louzguine D V, Ko M S, Ranganathan S, and Inoue A, J. Nanosci. and Nanotech 1 (2001) 185.
Zhang T, Inoue A, and Masumoto T, Mater Sci Engg A 182 (1994) 1423.
Cui Y Y, Bai X, Luo S Y, Wang Q, Li J H, and Liu B X, J. Alloys Compd 552 (2013) 55.
Khond A, Babu D A, Smaran S, Deshmukh A, Majumdar B, Bhatt J, and Srivastav A K, J Non-Cryst Solids 500 (2018) 191.
Corrosion, ASM Metals Handbook, Volume 13, 1980 p 16.
Manning P E, Corrosion 36 (1980) 468.
Barbosa M A, Garrido A, Campilho A, and Sutherland I, Corros Sci 32 (1991) 179.
Gebert A, Subba Rao R V, Wolff U, Baunack S, Eckert J, and Schultz L, Mater Sci Eng A 375-377 (2004) 280.
Lekatou A, Marinou A, Patsalas P, and Karakassides M A, J Alloys Compd 483 (2009) 514.
Wang Y B, Zheng Y F, Wei S C, and Li M, J Biomed Mater Res 96 (2011) 34.
Elkin V V, Marshakov A I, Rybkina A A, and Maleeva M A, Russ J Electrochem 47 (2011) 136.
Scully J R, Gebert A, and Payer J H, J Mater Res 22 (2007) 302.
Gebert A, Kuehn U, Baunack S, Mattern N, and Schultz L, Mater Sci Eng A 415 (2006) 242.
Green B A, Meyer H M, Benson R S, Yokoyama Y, Liaw P K, and Liu C T, Corros Sci 50 (2008) 1825.
Mandal S, Sivakumar B, Singhbabu Y N, Bandyopadhyay N R, Chattopadhyay P P, and Kailath A J, J Mater Eng Perform 1059 (2019) 1.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Khond, A., Arya, S.B., Majumdar, B. et al. Corrosion Studies of Hf64Cu18Ni18 Metallic Glass in Acidic and Alkaline Media. Trans Indian Inst Met 74, 949–956 (2021). https://doi.org/10.1007/s12666-021-02201-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12666-021-02201-0