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Soil geochemistry as a tool for the origin investigation and environmental evaluation of urban parks in Mashhad city, NE of Iran

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Abstract

The total concentration of major oxides and trace elements, sequential extraction of heavy metals, and Pb isotope signatures of park soils were investigated in Mashhad, the largest city in northeastern Iran. The geochemical characteristics of park soils show two different trends: high silica soils (HSS) and low silica soils (LSS). The elements such as Mg, Fe, As, Co, Cr, Cu, Mn, Ni, Pb, Sn, and Zn were concentrated in LSS, while HSS samples were enriched of Si, Ga, Li, Nb, Ta, Th, U, Y, Z, and rare-earth elements (REE). The REE composition and chondrite—normalized patterns of LSS [low ∑REE (20–68 mg kg−1) and low LaN/YbN (1.9–7.4)]—are compatible with ultramafic-derived soils. The HSS samples display distinct REE composition with high ∑REE (102–336 mg kg−1) and LaN/YbN (13–51) which would be originated from granitoid, metamorphic, and sedimentary derived soils. The available percentage of heavy metals in the park soils is much higher than natural samples. The Pb characteristics of park soils are distinct from natural soils. These samples are less radiogenic than natural soils with lower 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, 206Pb/207Pb, and higher 208Pb/206Pb ratios. The calculated contributions of possible sources in Mashhad park soils release 6.6 and 93.4% for natural and anthropogenic (industrial and leaded petrol) sources, respectively. The central parks exhibit the highest pollution of heavy metals in Mashhad indicating high traffic intensity in this area. The concentration of potentially toxic elements in the surface soils of Mashhad parks is lower than the national maximum permissible concentration, but many of them such as Cd, Cu, Mo, Pb, Sn, Se, and Zn are highly enriched relative to non-urban soils.

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(modified from Taheri and Ghaemi 1994)

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References

  • Alavi M (1979) The virani ophiolite complex and surrounding rocks. Geol Rundsch 68:334–341

    Article  Google Scholar 

  • Alavi M (1991) Sedimentary and structural characteristics of the Paleo-Tethys remnants in northeastern Iran. Geol Soc Am Bull 1038:983–992

    Article  Google Scholar 

  • Alekseenko V, Alekseenko A (2014) The abundances of chemical elements in urban soils. J Geochem Explor 147:245–249

    Article  Google Scholar 

  • Alexander EB (2004) Serpentine soil redness, differences among peridotite and serpentinite materials, Klamath Mountains, California. Int Geol Rev 46:754–764

    Article  Google Scholar 

  • Andersson M, Ottesen RT, Langedal M (2010) Geochemistry of urban surface soils—monitoring in Trondheim, Norway. Geoderma 156:112–118

    Article  Google Scholar 

  • Argyraki A, Kelepertzis E (2014) Urban soil geochemistry in Athens, Greece: the importance of local geology in controlling the distribution of potentially harmful trace elements. Sci Total Environ 482–483:366–377

    Article  Google Scholar 

  • Bourliva A, Papadopoulou L, Aidona E, Giouri K (2017) Magnetic signature, geochemistry, and oral bioaccessibility of technogenic metals in contaminated industrial soils from Sindos Industrial Area, Northern Greece. Environ Sci Pollut Res 24:17041–17055

    Article  Google Scholar 

  • Buat-Menard P, Chesselet R (1979) Variable influence of the atmospheric flux on the trace metal chemistry of oceanic suspended matter. Earth Planet Sci Lett 42:398–411

    Article  Google Scholar 

  • CCME (Canadian Council of Ministers of the Environment) (2007) Canadian soil quality guidelines for the protection of environmental and human health: summary tables. Canadian environmental quality guidelines. http://ceqg-rcqe.ccme.ca/download/en/342/

  • EPMC (Environmental Pollution Control of Mashhad) (2017) 2016 air quality report of Mashhad (in Persian)

  • Ferri R, Donna F, Smith DR, Guazzetti S, Zacco A, Rizzo L, Bontempi E, Zimmerman NJ, Lucchini RG (2012) Heavy metals in soil and salad in the proximity of historical ferroalloy emission. J Environ Prot 3:374–385

    Article  Google Scholar 

  • Frostick A, Bollhöfer A, Parry D, Munksgaard N, Evans K (2008) Radioactive and radiogenic isotopes in sediments from Cooper Creek, Western Arnhem land. J Environ Radioact 99:468–482

    Article  Google Scholar 

  • Galušková I, Mihaljevič M, Borůvka L, Drábek O, Frühauf M, Němeček K (2014) Lead isotope composition and risk elements distribution in urban soils of historically different cities Ostrava and Prague, the Czech Republic. J Geochem Explor 147:215–221

    Article  Google Scholar 

  • Giusti L (2013) The chemistry and parent material of urban soils in Bristol (UK): implications for contaminated land assessment. Environ Geochem Health 35:53–67

    Article  Google Scholar 

  • Gu YG, Gao YP, Lin Q (2016) Contamination, bioaccessibility and human health risk of heavy metals in exposed-lawn soils from 28 urban parks in southern China’s largest city, Guangzhou. Appl Geochem 67:52–58

    Article  Google Scholar 

  • Hansmann W, Köppel V (2000) Lead-isotopes as tracers of pollutants in soils. Chem Geol 171:123–144

    Article  Google Scholar 

  • Hooda PS (2010) Trace elements in soils. Wiley, New York

    Book  Google Scholar 

  • Horvath A, Szita R, Bidlo A, Gribovszki Z (2016) Changes in soil and sediment properties due the impact of the urban environment. Environ Earth Sci 75:1211. https://doi.org/10.1007/s12665-016-6012-8

    Article  Google Scholar 

  • IDM (Iranian Department of Science) (2013) The standards of soil quality and guidelines (in Persian)

  • Jin L, Ma L, Dere A, White T, Mathur R, Brantley SL (2017) REE mobility and fractionation during shale weathering along a climate gradient. Chem Geol 466:352–379

    Article  Google Scholar 

  • Karimi A, Haghnia GH, Safari T, Hadadian H (2017) Lithogenic and anthropogenic pollution assessment of Ni, Zn and Pb in surface soils of Mashhad plain, northeastern Iran. Catena 157:151–162

    Article  Google Scholar 

  • Kelepertzis E, Argyraki A (2015) Geochemical associations for evaluating the availability of potentially harmful elements in urban soils: lessons learnt from Athens, Greece. Appl Geochem 512–513:94–102

    Google Scholar 

  • Komárek M, Ettler V, Chrastny V, Mihaljevic M (2008) Lead isotopes in environmental sciences: a review. Environ Int 34:562–577

    Article  Google Scholar 

  • Li H, Yu S, Li G, Deng H, Luo X (2011) Contamination and source differentiation of Pb in park soils along an urban–rural gradient in Shanghai. Environ Pollut 159:3536–3344

    Article  Google Scholar 

  • Liu Z, Pan S, Sun Z, Ma F, Chen L, Wang Y, Wang S (2015) Heavy metal spatial variability and historical changes in the Yangtze River estuary and North Jiangsu tidal flat. Mar Pollut Bull 98:115–129

    Article  Google Scholar 

  • Loska K, Wiechuya D (2003) Application of principle component analysis for the estimation of source of heavy metal contamination in surface sediments from the Rybnik Reservoir. Chemosphere 51:723–733

    Article  Google Scholar 

  • Mazhari SA, Sharifiyan Attar R (2015) Rare earth elements in surface soils of the Davarzan area, NE of Iran. Geod Reg 5:25–33

    Google Scholar 

  • Mazhari SA, Mazloumi Bajestani AR, Sharifiyan Attar R (2013) Geochemical investigation of Davarzan surface soils, west of Sabzevar, NE Iran. Iran J Earth Sci 5:43–53

    Google Scholar 

  • Mazhari SA, Sharifiyan Attar R, Haghighi F (2017) Heavy metals concentration and availability of different soils in Sabzevar area, NE of Iran. J Afr Earth Sci 134:106–112

    Article  Google Scholar 

  • Mirnejad H, Lalonde AE, Obeid M, Hassanzadeh J (2013) Geochemistry and petrogenesis of Mashhad granitoids: an insight into the geodynamic history of the Paleo-Tethys in northeast of Iran. Lithos 170–171:105–116

    Article  Google Scholar 

  • Monna F, Aiuppa A, Varrica D, Dongarra G (1999) Pb isotope composition in lichens and aerosols from eastern Sicily: insights into the regional impact of volcanoes on the environment. Environ Sci Technol 33:2517–2523

    Article  Google Scholar 

  • Morel JL, Charzyn´ski P, Shaw RK, Zhang G (2015) The seventh SUITMA conference held in Toruń, Poland. J Soils Sediments 15:1657–1658

    Google Scholar 

  • Muller G (1969) Index of geo-accumulation in sediments of the Rhine river. Geojournal 2:108–118

    Google Scholar 

  • Nabavi MH (1976) Introduction to geology of Iran. Geological Survey of Iran Press, Tehran (in Persian)

    Google Scholar 

  • Rauret G, Lopez-Sanchez JF, Sahuquillo A, Barahona E, Lachica M, Ure AM, Davidson CM, Gomez A, Luck D, Bacon J, Yli-Halla M, Muntaub H, Quevauvilleri P (2000) Application of a modified BCR sequential extraction (three-step) procedure for the determination of extractable trace metal contents in a sewage sludge amended soil reference material (CRM 483) complemented by a three-year stability study of acetic acid and EDTA extractablemetal content. J Environ Monit 2:228–233

    Article  Google Scholar 

  • Reid MK, Spencer KL (2009) Use of principal components analysis (PCA) on estuarine sediment datasets: the effect of data pre-treatment. Environ Pollut 157:2275–2281

    Article  Google Scholar 

  • Rodríguez L, Ruiz E, Alonso-Azcárate J, Rincón J (2009) Heavy metal distribution and chemical speciation in tailings and soils around a Pb–Zn mine in Spain. J Environ Manage 90:1106–1116

    Article  Google Scholar 

  • Rodríguez-Seijo A, Arenas-Lago D, Andrade ML, Vega FA (2015) Identifying sources of Pb pollution in urban soils by means of MC-ICP-MS and TOF-SIMS. Environ Sci Pollut Res 22:7859–7872

    Article  Google Scholar 

  • Rollinson HR (1993) Using geochemical data: evaluation, presentation, interpretation. Longman Scientific & Technical, London

    Google Scholar 

  • Schilling J, Reimann C, Roberts D (2014) REE potential of the Nordkinn Peninsula, North Norway: a comparison of soil and bedrock composition. Appl Geochem 41:95–106

    Article  Google Scholar 

  • Sun SS, McDonough WF (1989) Chemical and isotopic systematics of the oceanic basalts: implications for mantle composition and processes. In: Saunders AD, Norry MJ (eds) Magmatism in the Oceanic Basalts. Geol Soc London, London, pp 313–345

    Google Scholar 

  • Taheri J, Ghaemi F (1994) The 1:100000 quadrangle geological map of Mashhad. Geological Survey of Iran, Tehran

    Google Scholar 

  • Taylor SR (1964) Abundance of chemical elements in the continental crust: a new table. Geochim Cosmochim Acta 28:1273–1285

    Article  Google Scholar 

  • Ure AM, Davidson CM (1995) Chemical speciation in the environment. Blackie, Glasgow

    Google Scholar 

  • Yang Z, Lu W, Long Y, Bao X, Yang Q (2011) Assessment of heavy metals contamination in urban topsoil from Changchun City, China. J Geochem Explor 108:27–38

    Article  Google Scholar 

  • Yang J, Meng XZ, Duan YP, Liu LZ, Chen L, Cheng H (2014) Spatial distributions and sources of heavy metals in sediment from public park in Shanghai, the Yangtze River Delta. Appl Geochem 44:54–60

    Article  Google Scholar 

Download references

Funding

Some analytical cost of this project was supported by Payame Noor University. The authors gratefully acknowledge the comments of the anonymous reviewers that helped improve the original manuscript.

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Authors and Affiliations

  1. Department of Geology, Payame Noor University, Tehran, 19395-4697, Iran

    Seyed Ali Mazhari, Ali Reza Mazloumi Bajestani & Fereshteh Hatefi

  2. Faculty of Geography and Environmental Science, Hakim Sabzevari University, Sabzevar, Iran

    Kazem Aliabadi

  3. Cellular and Molecular Research Center, Sabzevar University of Medical Sciences, Sabzevar, Iran

    Faezeh Haghighi

Authors
  1. Seyed Ali Mazhari
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  2. Ali Reza Mazloumi Bajestani
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  3. Fereshteh Hatefi
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  4. Kazem Aliabadi
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  5. Faezeh Haghighi
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Correspondence to Seyed Ali Mazhari.

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Mazhari, S.A., Bajestani, A.R.M., Hatefi, F. et al. Soil geochemistry as a tool for the origin investigation and environmental evaluation of urban parks in Mashhad city, NE of Iran. Environ Earth Sci 77, 492 (2018). https://doi.org/10.1007/s12665-018-7684-z

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