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Spectral-induced polarization characterization of rocks from the Handuk iron mine, South Korea

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Abstract

Spectral-induced polarization (SIP) using the electrochemical reaction at the interface between mineral particle and groundwater is a powerful tool for the exploration of minerals. However, SIP responses of rocks have not been fully characterized because it is influenced by various petrological properties. In this study, the relationship between SIP responses and the petrological features of representative rocks from skarn deposits was analyzed. For the evaluation of the SIP responses, chargeability and relaxation time of time domain induced polarization (IP) were calculated by an equivalent circuit analysis. Among various circuit models used for the analysis, an existing circuit model was utilized for this study because it sufficiently describes the electrochemical reaction of water-saturated rocks and is more suitable for the analysis of heterogeneous rocks than the other models. The circuit model was found to be appropriate because the normalized root mean square error between the observed values and ones obtained through the model fittings reasonably low, ranging from 4.18 to 0.05 %. The chargeability values of the mineralized rocks were higher than those of the non-mineralized rocks (igneous and carbonates), and the relaxation time was related to the grain size of the magnetite. It was found that the SIP characteristics of the mineralized rocks are dependent on features of the ore minerals. In the non-mineralized rocks, there was little difference in the chargeability, whereas the variation in their relaxation time values was influenced by the feldspar content (sericitization) and the grain size of the calcite (recrystallization). The SIP characteristics of the non-mineralized rocks are considered to be dependent on the grade of the hydrothermal alteration.

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References

  • Abdel Aal GZ, Atekwana EA (2014) Spectral induced polarization (SIP) response of biodegraded oil in porous media. Geophys J Int 196:804–817. doi:10.1093/gji/ggt416

    Article  Google Scholar 

  • Abdel Aal GZ, Atekwana EA, Revil A (2014) Geophysical signatures of disseminated iron minerals: a proxy for understanding subsurface biophysicochemical processes. J Geophys Res: Biogeosci 119:2014JG002659. doi:10.1002/2014jg002659

    Google Scholar 

  • Barreto A, Dias CA (2014) Fluid salinity, clay content, and permeability of rocks determined through complex resistivity partition fraction decomposition. Geophysics 79:D333–D347. doi:10.1190/geo2013-0306.1

    Article  Google Scholar 

  • Bieniawski ZT, Bernede MJ (1979) Suggested methods for determining the uniaxial compressive strength and deformability of rock materials: part 1. Suggested method for determining deformability of rock materials in uniaxial compression. Int J Rock Mech Min Sci Geomech Abstr 16:138–140. doi:10.1016/0148-9062(79)91451-7

    Article  Google Scholar 

  • Bockris JOM, Devanathan MAV, Muller K (1963) On the structure of charged interfaces. Proc R Soc Lond Ser A Math Phys Sci 274:55–79. doi:10.1098/rspa.1963.0114

    Article  Google Scholar 

  • Castela AS, da Fonseca BS, Duarte RG, Neves R, Montemor MF (2014) Influence of unsupported concrete media in corrosion assessment for steel reinforcing concrete by electrochemical impedance spectroscopy. Electrochim Acta 124:52–60. doi:10.1016/j.electacta.2013.11.157

    Article  Google Scholar 

  • Choi DK, Kim DH, Sohn JW (2001) Ordovician trilobite faunas and depositional history of the Taebaeksan Basin, Korea: implications for palaeogeography. Alcheringa: Aust J Palaeontol 25:53–68. doi:10.1080/03115510108619213

    Article  Google Scholar 

  • Chough SK, Kwon ST, Ree JH, Choi DK (2000) Tectonic and sedimentary evolution of the Korean peninsula: a review and new view. Earth Sci Rev 52:175–235. doi:10.1016/S0012-8252(00)00029-5

    Article  Google Scholar 

  • Dias CA (1972) Analytical model for a polarizable medium at radio and lower frequencies. J Geophys Res 77:4945–4956. doi:10.1029/JB077i026p04945

    Article  Google Scholar 

  • Dias CA (2000) Developments in a model to describe low-frequency electrical polarization of rocks. Geophysics 65:437–451. doi:10.1190/1.1444738

    Article  Google Scholar 

  • Duarte RG, Castela AS, Neves R, Freire L, Montemor MF (2014) Corrosion behavior of stainless steel rebars embedded in concrete: an electrochemical impedance spectroscopy study. Electrochim Acta 124:218–224. doi:10.1016/j.electacta.2013.11.154

    Article  Google Scholar 

  • Florsch N, Llubes M, Téreygeol F, Ghorbani A, Roblet P (2011) Quantification of slag heap volumes and masses through the use of induced polarization: application to the Castel-Minier site. J Archaeol Sci 38:438–451. doi:10.1016/j.jas.2010.09.027

    Article  Google Scholar 

  • Gallas J, Taioli F, Malagutti Filho W (2011) Induced polarization, resistivity, and self-potential: a case history of contamination evaluation due to landfill leakage Environ. Earth Sci 63:251–261. doi:10.1007/s12665-010-0696-y

    Article  Google Scholar 

  • Gellert M et al (2014) LiNi0.5Mn1.5O4 thin-film cathodes on gold-coated stainless steel substrates: formation of interlayers and electrochemical properties. Electrochim Acta 133:146–152. doi:10.1016/j.electacta.2014.03.184

    Article  Google Scholar 

  • Jorcin J-B, Orazem ME, Pébère N, Tribollet B (2006) CPE analysis by local electrochemical impedance spectroscopy. Electrochimica Acta 51:1473–1479. doi:10.1016/j.electacta.2005.02.128

    Article  Google Scholar 

  • Keller GV, Frischknecht FC (1966) Electrical methods in geophysical prospecting. Pergamon Press, New York

    Google Scholar 

  • Koch K, Revil A, Holliger K (2012) Relating the permeability of quartz sands to their grain size and spectral induced polarization characteristics. Geophys J Int 190:230–242. doi:10.1111/j.1365-246X.2012.05510.x

    Article  Google Scholar 

  • Kwon YK, Chough SK, Choi DK, Lee DJ (2006) Sequence stratigraphy of the Taebaek Group (Cambrian–Ordovician), mideast Korea. Sed Geol 192:19–55. doi:10.1016/j.sedgeo.2006.03.024

    Article  Google Scholar 

  • Lee HS, Chough SK (2006) Lithostratigraphy and depositional environments of the Pyeongan Supergroup (Carboniferous–Permian) in the Taebaek area, mid-east Korea. J Asian Earth Sci 26:339–352. doi:10.1016/j.jseaes.2005.05.003

    Article  Google Scholar 

  • Lesmes DP, Morgan FD (2001) Dielectric spectroscopy of sedimentary rocks. J Geophys Res: Solid Earth 106:13329–13346. doi:10.1029/2000jb900402

    Article  Google Scholar 

  • Liu H, Sun Y (2010) Influential factors on spectral induced polarization of chrome-contaminated soil. In: 2010 4th international conference on bioinformatics and biomedical engineering (iCBBE), 18–20 June 2010, pp 1–4. doi:10.1109/icbbe.2010.5516778

  • Lopes IMF, Loureiro CRO, Junqueira RMR (2014) Corrosion monitoring of galvanized steel in soil extract solutions by electrochemical impedance spectroscopy. Materialwiss Werkstofftech 45:619–627. doi:10.1002/mawe.201400243

    Article  Google Scholar 

  • Macdonald JR, Johnson WB (2005) Fundamentals of impedance spectroscopy. In: Impedance spectroscopy. Wiley, pp 1–26. doi:10.1002/0471716243.ch1

  • Ni CS, Lu LY, Zeng CL, Niu Y (2014) Evaluation of corrosion resistance of aluminium coating with and without annealing against molten carbonate using electrochemical impedance spectroscopy. J Power Sources 261:162–169. doi:10.1016/j.jpowsour.2014.03.076

    Article  Google Scholar 

  • Niranjan U (2004) Simultaneous storage of medical images in the spatial and frequency domain: a comparative study. Biomed Eng Online 3:17

    Article  Google Scholar 

  • Ntarlagiannis D, Doherty R, Williams K (2010) Spectral induced polarization signatures of abiotic FeS precipitation. Geophysics 75:F127–F133. doi:10.1190/1.3467759

    Article  Google Scholar 

  • Park S-G, Kim J-H (2005) Geological survey by electrical resistivity prospecting in landslide area. Geosyst Eng 8:35–42. doi:10.1080/12269328.2005.10541234

    Article  Google Scholar 

  • Pelton W, Ward S, Hallof P, Sill W, Nelson P (1978) Mineral discrimination and removal of inductive coupling with multifrequency IP. Geophysics 43:588–609. doi:10.1190/1.1440839

    Article  Google Scholar 

  • Placencia-Gómez E, Slater L (2014) Electrochemical spectral induced polarization modeling of artificial sulfide-sand mixtures. Geophysics 79:EN91–EN106. doi:10.1190/geo2014-0034.1

    Article  Google Scholar 

  • Placencia-Gómez E, Parviainen A, Slater L, Leveinen J (2015) Spectral induced polarization (SIP) response of mine tailings. J Contam Hydrol 173:8–24. doi:10.1016/j.jconhyd.2014.12.002

    Article  Google Scholar 

  • Raijmakers LHJ, Danilov DL, van Lammeren JPM, Lammers MJG, Notten PHL (2014) Sensorless battery temperature measurements based on electrochemical impedance spectroscopy. J Power Sources 247:539–544. doi:10.1016/j.jpowsour.2013.09.005

    Article  Google Scholar 

  • Randles JEB (1947) Kinetics of rapid electrode reactions. Discuss Faraday Soc 1:11–19. doi:10.1039/df9470100011

    Article  Google Scholar 

  • Revil A (2012) Spectral induced polarization of shaly sands: influence of the electrical double layer. Water Resour Res 48:W02517. doi:10.1029/2011wr011260

    Article  Google Scholar 

  • Revil A, Florsch N (2010) Determination of permeability from spectral induced polarization in granular media. Geophys J Int 181:1480–1498. doi:10.1111/j.1365-246X.2010.04573.x

    Google Scholar 

  • Revil A, Florsch N, Camerlynck C (2014) Spectral induced polarization porosimetry. Geophys J Int 198:1016–1033. doi:10.1093/gji/ggu180

    Article  Google Scholar 

  • Ryu I-C, Doh S-J, Choi S-G (2002) Carbonate breccias in the lower-middle Ordovician Maggol Limestone (Taebacksan Basin, South Korea): implications for regional tectonism. Facies 46:35–56. doi:10.1007/bf02668072

    Article  Google Scholar 

  • Schwartz N, Shalem T, Furman A (2014) The effect of organic acid on the spectral-induced polarization response of soil. Geophys J Int 197:269–276. doi:10.1093/gji/ggt529

    Article  Google Scholar 

  • Seigel H, Nabighian M, Parasnis D, Vozoff K (2007) The early history of the induced polarization method. Lead Edge 26:312–321. doi:10.1190/1.2715054

    Article  Google Scholar 

  • Shin SW, Park S, Shin DB (2015) Development of a new equivalent circuit model for spectral induced polarization data analysis of ore samples. Environ Earth Sci 74:5711–5716 doi:10.1007/s12665-015-4588-z

    Article  Google Scholar 

  • Slater L, Lesmes D (2002) IP interpretation in environmental investigations. Geophysics 67:77–88. doi:10.1190/1.1451353

    Article  Google Scholar 

  • Slater L, Ntarlagiannis D, Wishart D (2006) On the relationship between induced polarization and surface area in metal-sand and clay-sand mixtures. Geophysics 71:A1–A5. doi:10.1190/1.2187707

    Article  Google Scholar 

  • Slater L, Ntarlagiannis D, Personna YR, Hubbard S (2007) Pore-scale spectral induced polarization signatures associated with FeS biomineral transformations. Geophys Res Lett 34:L21404. doi:10.1029/2007gl031840

    Article  Google Scholar 

  • Telford WM, Telford WM, Geldart LP, Sheriff RE (1990) Applied geophysics. Cambridge University Press, Cambridge

    Book  Google Scholar 

  • Titov K, Tarasov A, Ilyin Y, Seleznev N, Boyd A (2010) Relationships between induced polarization relaxation time and hydraulic properties of sandstone. Geophys J Int 180:1095–1106. doi:10.1111/j.1365-246X.2009.04465.x

    Article  Google Scholar 

  • Yang DY, Utsugi Y, Mariko T (1993) Fluid inclusion study on magnesian Fe skarn-type deposit of the Shinyemi mine. Republic of Korea Shigen-Chishitsu 43:11–22. doi:10.11456/shigenchishitsu1992.43.11

    Google Scholar 

  • Zonge K, Wynn J (1975) Recent advances and applications in complex resistivity measurements. Geophysics 40:851–864. doi:10.1190/1.1440572

    Article  Google Scholar 

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Acknowledgments

This research was supported by the Basic Research Project of the Korea Institute of Geoscience and Mineral Resources (KIGAM) funded by the Ministry of Science, ICT and Future Planning and Resources of the Korea Institute of Energy Technology and Planning (KETEP) grant funded by the Korea Government Ministry of Trade, Industry and Energy (MOTIE) (20142510101750).

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Shin, S.W., Park, S. & Shin, D.B. Spectral-induced polarization characterization of rocks from the Handuk iron mine, South Korea. Environ Earth Sci 75, 827 (2016). https://doi.org/10.1007/s12665-016-5618-1

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