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Spectroscopic investigation by incorporation of charge compensator ions in CaBaSiO4: Dy3+ phosphors for solid-state lighting applications

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Abstract

In this research paper, we present a study on the preparation and spectroscopic properties of Dy3+-doped calcium barium ortho-silicate (CaBaSiO4) phosphor. The phosphors were synthesized using the solid-state reaction route. The obtained powders underwent characterization through X-ray diffraction (XRD) and Furrier transform infrared (FTIR), confirming phase purity and the presence of functional groups, respectively. Energy-dispersive X-ray (EDX) reveals the elemental composition of the material under examination. The spectroscopic properties of Dy3+ in CaBaSiO4 phosphor were investigated through emission and excitation spectra analysis. The emission spectra exhibit two peaks in the blue region at 482 nm and in the yellow region at 574 nm under UV excitation with a wavelength of 349 nm. Both emission peaks are attributed to the 4F9/2 → 6H15/2 and 4F9/2 → 6H13/2 characteristic transitions of the Dy3+ ion. The critical distance was calculated using the Blasse equation. Monovalent ions were added to the host as charge compensator ions to enhance the luminescence intensity. The CIE chromaticity coordinates were determined from the emission spectra, affirming that the CaBaSiO4 phosphor is a suitable candidate for solid-state lighting applications, particularly in w–LEDs.

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References

  1. L K Bharat, S H Lee and J S Yu Materials Research Bulletin 53 49 (2014)

    Article  Google Scholar 

  2. A H Mueller, M A Petruska, M Achermann, D J Werder, E A Akhadov, D D Koleske, M A Hoffbauer and V I Klimov Nano Lett. 510 39 (2005)

    Google Scholar 

  3. Y Wei, H Yang, Z Gao, G Xing, M S Molokeev and G Li RSC Commun (2020). https://doi.org/10.1039/D0CC03975F

    Article  Google Scholar 

  4. S Nakamura MRS Bull. 22 29 (1997)

    Article  Google Scholar 

  5. F Schubert and J K Kim Science 308 1274 (2005)

    Article  ADS  Google Scholar 

  6. S K Gupta, M Mohapatra, S Kaity, V Natarajan and S V Godbole J. Lumin. 132 1329 (2012)

    Article  Google Scholar 

  7. H Y Wu, Y H Hu, Y H Wang, F W Kang and Z F Mou Optics and Laser Technology 43 1104 (2011)

    Article  ADS  Google Scholar 

  8. Z Xia and J Zhuang Inorg. Chem. 51 7202 (2012)

    Article  Google Scholar 

  9. B Liu and L Kong J. Lumin. 122 121 (2007)

    Article  Google Scholar 

  10. Z Zhu, Z Sun and Z Guo J. Lumin. 207 430 (2019)

    Article  Google Scholar 

  11. S Sarina, B Nasir, A Tanaka and S Yoshiara J. Lumin. 207 22 (2019)

    Article  Google Scholar 

  12. C H Lu, S Som and P H Kuo J. All. and Comp. 790 1060 (2019)

    Article  Google Scholar 

  13. I P Sahu, D P Bisen, R K Tamrakar, K V R Murthy and M Mohapatra Journal of Science: Advanced Materials and Devices 2 69 (2017)

    Google Scholar 

  14. C H Hsu, R Jagannathan and C H Lu Mater. Sci. Eng. B 167 137 (2010)

    Article  Google Scholar 

  15. Y Fang, L Li, Y Chen and H Wang Luminescence 144 13 (2013)

    Article  ADS  Google Scholar 

  16. G R Banjare, D P Bisen, N Brahme, C Belodhiya, P Dewangan, E Chandrawansi and I P Sahu J. Therm. Anal. and Calorim. 139 1577 (2020). https://doi.org/10.1007/s10973-019-08520-1

    Article  Google Scholar 

  17. G R Banjare, D P Bisen, N Brahme and C Belodhiya Materials Science and Engineering: B 263 114882 (2021)

    Article  Google Scholar 

  18. H Irfan, K M Racik and S Anand Modern Electronic Materials 4 1 31 (2018). https://doi.org/10.3897/j.moem.4.1.33272

    Article  Google Scholar 

  19. M Bodke, U Gawai and A Patil B. Dole Matériaux & Techniques 106 602 (2018). https://doi.org/10.1051/mattech/2018055

    Article  ADS  Google Scholar 

  20. G K Williamson and W H Hall Acta Metal. 1 1 22 (1953)

    Article  Google Scholar 

  21. R D Shanon Acta Crystallogr. A 32 751 (1976)

    Article  ADS  Google Scholar 

  22. A Bigham, S A Hassanzadeh-Tabrizi and M Rafienia Ceramics International 42 17185 (2016)

    Article  Google Scholar 

  23. B Verma, R N Baghel, D P Bisen, N Brahme and A Khare Journal of Alloys and Compounds 805 663 (2019)

    Article  Google Scholar 

  24. M Peddaiah, P Ankoji and B H Rudramadevi Materials Today: Proceedings 46 184 (2021). https://doi.org/10.1016/j.matpr.2020.07.345

    Article  Google Scholar 

  25. M A Marzouk, F H ElBatal and A M Abdelghany Spectrochim. Acta Part A 114 658 (2013)

    Article  ADS  Google Scholar 

  26. I P Sahu and D P Bisen Displays 38 68 (2015)

    Article  Google Scholar 

  27. J C Lassègues, J Grondin and C Aupetit J. Phys. Chem. A 113 305 (2009)

    Article  Google Scholar 

  28. L Zhang, Z Lu, P Han and L Wang Q. Zhang J. nanomaterials 848274 1 (2012). https://doi.org/10.1155/2012/848274

    Article  Google Scholar 

  29. H J Wooa, S Gandhib, M Jayasimhadri, D S Shin and H S Lee K. Jang Sensors and Actuators B 241 1106 (2017)

    Article  Google Scholar 

  30. K Mondal J. Manam Journal of Molecular Structure 1125 503 (2016)

    Article  ADS  Google Scholar 

  31. G S Rama Raju, J Y Park, H C Jung, B K Moon, J H Jeong and J H Kim Curr. Appl. Phys. 9 92 (2009)

    Article  Google Scholar 

  32. L Reddy J. Fluorescence 33 2181 (2023)

    Article  Google Scholar 

  33. S K Gupta, M Kumar, V Natrajan and S V Godbole Optical Materials 35 2320 (2013)

    Article  ADS  Google Scholar 

  34. Z Xia and R S Liu J. Phys. Chem. C 116 15604 (2012)

    Article  Google Scholar 

  35. G Blasse Phys. Lett. A 28 444 (1968)

    Article  ADS  Google Scholar 

  36. L Mukhopadhyay, S Pattnaik and V K Rai RSC Adv. 13 21096 (2023)

    Article  ADS  Google Scholar 

  37. W Tang and Z Zhang J. Mater. Chem. C 3 5339 (2015)

    Article  Google Scholar 

  38. K Y Jung and H K Jung J. Lumin. 130 1970 (2010)

    Article  Google Scholar 

  39. T L Barry J. Electrochem. Soc. 115 1181 (1968)

    Article  ADS  Google Scholar 

  40. A M Pires and M R Davolos Chem. Mater. 13 1202 (2001)

    Article  Google Scholar 

  41. S Kumar and A K Ojha J. Alloys. Compd. 644 654 (2015)

    Article  Google Scholar 

  42. K V Dabre and S J Dhoble RSC Adv. 5 60409 (2015)

    Article  ADS  Google Scholar 

  43. J Wu, M Li, H Jia and M Wang J. Lumin. 214 116607 (2019)

    Article  Google Scholar 

  44. H Liu, Y Hao, H Wang, J Zhao and P Huang J. Lumin. 131 2422 (2011)

    Article  Google Scholar 

  45. R Venkatesh and N Dhananjaya Int. J. Nanotechnol 14 793 (2017)

    Article  Google Scholar 

  46. C Xueqin, W Tao, C Yonghu, Y Min and G Changxin J. Rare Earths 29 1029 (2011)

    Article  Google Scholar 

  47. Y N Li, D Zhao, L Y Shi, S J Dai, Y P Fan, B Z Liu and Q X Yao J. Lumin. 220 116976 (2020)

    Article  Google Scholar 

  48. M Fhoula J. Lumin. 210 1 (2019)

    Article  Google Scholar 

  49. S Tamboli and S J Dhoble Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 184 119 (2017)

    Article  ADS  Google Scholar 

  50. R Nagraj, V P Manjari, G T Rao, B Shailaja and R V Ravishankar Intern. J. Sci. Res. 6 11 311 (2015)

    Google Scholar 

  51. A K Vishwakarma, K Jha, M Jayasimhadri, B Sivaiah and B Gahtoria Dalton Trans. 44 17166 (2015)

    Article  Google Scholar 

  52. N Ohta, A.R.Robertson John Wiley & Sons, Ltd., England (2005)

Download references

Acknowledgements

The authors are very much grateful to UGC-DAE,CSR Indore for providing an XRD facility and also Dr Mukul Gupta, Scientist F, for his cooperation and for providing experimental data. We are also thankful to Dr. H.K. Narang, Assistant Professor, Department of Mechanical Engineering, and Dr Anil Manjhi, Assistant Professor, Department of Humanities, NIT, Raipur (C.G.), for their help and support.

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Authors and Affiliations

  1. Department of Physics, Government Engineering College, Raipur, Chhattisgarh, 492015, India

    Ganesh Ram Banjare

  2. School of Studies in Physics and Astrophysics, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh, 492010, India

    D. P. Bisen, N. Brahme & Chitrkant Belodhiya

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  1. Ganesh Ram Banjare
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  2. D. P. Bisen
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  3. N. Brahme
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  4. Chitrkant Belodhiya
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Correspondence to Ganesh Ram Banjare.

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Banjare, G.R., Bisen, D.P., Brahme, N. et al. Spectroscopic investigation by incorporation of charge compensator ions in CaBaSiO4: Dy3+ phosphors for solid-state lighting applications. Indian J Phys (2024). https://doi.org/10.1007/s12648-024-03165-9

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