Abstract
The pristine epoxy resin exhibited its low fracture toughness and low thermal stability. The using of functionalized liquid rubber led to an improvement of fracture toughness along with a reduction of thermal stability of epoxy resin. So to simultaneously improve both the fracture toughness and the thermal stability of epoxy resin the silica/PANI core-shell particles have been used as an additive. The core/shell particles were prepared by decorating the surface of silica with polyaniline via a chemical oxidation reaction. The silica was extracted from rice husk via some simple steps. The high-speed mechanical stirring was utilized to enhance the uniform dispersion of core/shell particles in epoxy resin. The composite was formed at room temperature using DETA as a curing agent. The mechanical characteristics and thermal stability of composite were examined including tensile strength, flexural strength, fracture toughness, and TGA. The tensile strength was improved by 16,16% from 40,9 MPa to 47,51 MPa by adding core/shell particles to epoxy resin. The thermal stability of epoxy resin was also improved with presence of core/shell particles. In particular, the fracture toughness was improved by 52,8% from 1,12 MPa.m−1/2 to 1,87 MPa.m−1/2. The electrical conductivity of epoxy resin with SiO2@PANI Core/Shell increased by 178 times when compared with pristine epoxy. The SEM image was also used to provide the evidence for the improvement in fracture toughness, and mechanism.
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This research is funded by Le Quy Don Technical University Research Fund under the grand number 23.1.04.
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This research is funded by Le Quy Don Technical University Research Fund under the grand number 23.1.04.
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Cuong Manh Vu wrote the manuscript; analysis; chemical synthesis Tung Van Vu revise the manuscript; do experimental; testing.
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Vu, C.M., Van Vu, T. Influence of SiO2@PANI Core/Shell Particles on Mechanical Properties, Electrical Properties, and Thermal Aging of Epoxy Resin. Silicon 16, 25–33 (2024). https://doi.org/10.1007/s12633-023-02649-3
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DOI: https://doi.org/10.1007/s12633-023-02649-3