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Carbon and Silicon Nano-Clusters as Anode Electrodes of Metal Ion Batteries

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Abstract

The ability of silicon nanocage (Si78) and carbon nanocage (C72) in batteries are examined in order to propose novel nano materials as anode in batteries with high performances. The B15C57, Al15C57, B36Si42 and Al36Si42 nanocages are the most stable structures. The Gad of B15C57, Al15C57, B36Si42 and Al36Si42 as anodes of lithium-ion (Li-ion) battery are higher than other batteries. The Vcell of B doped nanocages as anodes of Zn-ion and Mg-ion batteries are higher than Al doped nanocages. The B and Al adoption of C72 and Si78 can increase the Vcell of Zn-ion and Mg-ion batteries. The B and Al adoption of C72 and Si78 can improve the electrochemistry properties of metal-ion batteries. The B15C57 and B36Si42 as effective anodes in metal-ion batteries are suggested.

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Acknowledgements

We thank our university for computational help.

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Authors and Affiliations

  1. Hulunbuir Vocational Technical College, Hulunbuir, 021000, Inner Mongolia, China

    Xia Wang

  2. Coal Gangue Heat and Power Plant of Inner Mongolia Mengtai Buliangou Coal Industry Co. Ltd, Ordos, 010321, Inner Mongolia, China

    Zhiguo Yin

  3. Chifeng Industrial Vocational Technical College, Chifeng, 024000, Inner Mongolia, China

    Feng Hao

  4. Independent researcher, Liaoyang, 111003, Liaoning, China

    Tiejun Xu

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  1. Xia Wang
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  2. Zhiguo Yin
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  3. Feng Hao
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Wang (Funding acquisition, Investigation, Methodology), Yin (Project administration, Resources, Software), Hao (Supervision, Validation, Visualization), Xu (Conceptualization, Data curation, Formal analysis).

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Correspondence to Zhiguo Yin or Tiejun Xu.

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Wang, X., Yin, Z., Hao, F. et al. Carbon and Silicon Nano-Clusters as Anode Electrodes of Metal Ion Batteries. Silicon 15, 1273–1282 (2023). https://doi.org/10.1007/s12633-022-02092-w

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