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Corrosion Protective Performance of "Green" Organic Compounds and Organosilane Films on Steel

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Abstract

In this study, for the first time, the combination "green" organic compounds that obtained from waste tomato processing and organosilanes (3-Aminopropyltriethoxysilane) was followed for obtaining the mixed volatile corrosion inhibitor (VCI). Such compositions can be used as polymer-type corrosion inhibitors for steel. The developed blend VCI based on tomato pomace extract (TPE) and organosilane provide a long-term protection from corrosion processes under the model conditions of carbon steel. The results show that the inhibition efficiency of the film reaches 96.97%. The tomato pomace extract chemical composition was analyzed by Head Space-Solid Phase Micro Extraction-Gas Chromatography-Mass Spectrometry (HS-SPME-GC–MS). The major volatile compounds ot the TPE include alcohols, esters, aldehydes, ketones and terpene compounds as described by panelists of HS-SPME-GC–MS. Electrochemical studies reveal decreased corrosion current densities from 4.29 × 10−4 to 0.65 × 10−4 A cm−2 and increased polarization resistance from in the under conditions of periodic moisture condensation. FT-IR absorption peak obtained at 954, 1142, 1230 cm−1 revealed the formation of Fe–O-Si, Si–O-Si and Si–O-C bonds. The protective film consesed of silane and extract offered the highest corrosion resistance since the corrosion protective barrier minimized the oxygen access and prevent corrosion of mild steel to a greater extent where the EDX analysis showed a high intense signal of Si and C.

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Acknowledgements

This work was supported by the Ministry of Education and Science of Ukraine [grant no. 2403, 2021].

Funding

This work was supported by the Ministry of Education and Science of Ukraine [grant no. 2403, 2021].

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Authors and Affiliations

  1. Department of Chemical Technology, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, building 4, 37, Peremohy avenue, Kiev, Ukraine

    Viktoria Vorobyova & Julia Zaporozhets

  2. Department of Inorganic Materials Technology and Ecology, Ukrainian State University of Chemical Technology, Dnipro, 49005, Ukraine

    Margarita Skiba & Ihor Kovalenko

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  1. Viktoria Vorobyova
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  2. Margarita Skiba
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  3. Julia Zaporozhets
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  4. Ihor Kovalenko
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Contributions

Victoria Vorobyova: conceptualization, methodology, investigation, writing-original draft; Margarita Skiba: writing-review and editing draft formal analysis; Julia Zaporozhets: investigation; Ihor Kovalenko: draft formal analysis.

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Correspondence to Viktoria Vorobyova.

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Vorobyova, V., Skiba, M., Zaporozhets, J. et al. Corrosion Protective Performance of "Green" Organic Compounds and Organosilane Films on Steel. Silicon 14, 12733–12752 (2022). https://doi.org/10.1007/s12633-022-01968-1

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