Skip to main content

Advertisement

SpringerLink
Log in

Thermal, Electrical and Physical Properties of Glasses Based on Basaltic Rocks

  • Original Paper
  • Published:
Silicon Aims and scope Submit manuscript

Abstract

Six glass compositions based on basaltic rocks and some industrial wastes, Batches were melted in an electric furnace at temperature 1400 °C for 2 h and then casted into rods and discs shapes. Many important techniques were used in the present study including X- ray fluorescence, thermal expansion, dielectric properties, indentation micro hardness, bending strength, density and chemical durability, The expansion coefficient in the temperature range 25–300 °C lies in the range between 48.78 to 59.76 × 10−7 /°C and the temperatures of Tg started at 668.79 °C and ranging between 668.79–632.34 °C and Ts started at 737 °C and lies in the range and 737–711.6 °C respectively. The lower expansion glasses have higher transition and softening temperatures and vice versa. Bending strength and Vickers micro hardness show a gradual decrease from 118 to 56 MPa and 6120–4020 MPa respectively with increasing cement dust content. In the same time the density increases from 2.79 to 2.96 g/cm3 by increasing cement dust content.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Litus AA, Sinitsyn IN, Artemenko SE, Zemljansky AA (2008) Noise-attenuating and sound-proof materials on the basis of basalt fibers. J Plasticheskiye Massy N1:25–27

    Google Scholar 

  2. Nikoghosyan SK, Sahakyan AA, Gavalyan VB, Harutyunyan VV, Hovanisyan AS, Yeritsyan HN, Atoyan AV, Puskulyan KI, Gerchikov M, Hakobyan NV, Hovhannisyan AV (2010) Electro-physical properties of super-thin basalt fibers on the basis of Armenian basalt rocks before and after chlorohydric acid treatment. Am J Phys 3(3):187–194

    CAS  Google Scholar 

  3. Nikoghosyan SK, Sahakyan AA, Gavalyan VB, Harutyunyan VV, Hovanisyan AS, Yeritsyan HN, Atoyan VA, Puskulyan KI, Gerchikov M, Hakobyan NV, Hovhannisyan AV (2011) Electro-physical Properties of Super-thin Basalt Fiber Chemically Modified by Hydrochloric or Sulphuric Acid. J Mod Phys 2(12):1450–1454

    Article  CAS  Google Scholar 

  4. Artemenko SE, Sinitsyn IN, Ustinov NA, Seredishkin AP (2008) Research of hydromechanical characteristics of basalt filter elements. J Plasticheskiye Massy N1:21–25

    Google Scholar 

  5. Ojovan MI, Lee WE (2007) New development in glassy nuclear waste forms. J. Nova Sci. Pub., New York

  6. Poznyak AI, Levitskii IA, Barantseva SE (2012) Basaltic and granitic rocks as components of ceramic mixes for interior wall tiles. J Glass and Ceramics 69(8):17–25

    Google Scholar 

  7. Khater GA (2006) Use of bypass cement dust for production of glass ceramic materials. J Adv in App Ceram 105(2):107–111

    Article  CAS  Google Scholar 

  8. Khater GA (2010) Glass-ceramics in the CaO-MgO-Al2O3-SiO2 system based on industrial waste materials. J Non-cryst Sol 356:3066–3070

    Article  CAS  Google Scholar 

  9. Albertini AVP, Silva JL, Freire VN, Santos RP, Martins JL, Cavada BS, Cadena PG, Rolim Neto PJ, Pimente MCB, Martínez CR, Porto ALF, Lima Filho JL (2013) Immobilized invertase studies on glass-ceramic support from coal fly ashes. Chem Eng J 214:91–96

    Article  CAS  Google Scholar 

  10. Khater GA (2002) The use of Saudi slag for the production of glass-ceramic materials. J Ceram Int 28(1):59–67

    Article  CAS  Google Scholar 

  11. Khater GA, Nabawy BS, Kank J, Mahmoud MA (2018) Dielectric properties of basaltic glass and glass-ceramics: modeling and applications as insulators and semiconductors. J Silicon 11:579–592. https://doi.org/10.1007/s12633-018-9963-4

    Article  CAS  Google Scholar 

  12. Braunger ML, Escanhoela CA, Fier I, Walmsley L, Ziemath EC (2012) Electrical conductivity of silicate glasses with tetravalent cations substituting Si. J Non-Cryst Sol 358:2855–2861

    Article  CAS  Google Scholar 

  13. Dutta A, Sinha TP, Jena P, Adak S (2008) Ac conductivity and dielectric relaxation in ionically conducting. Soda–lime–silicate glasses. J Non-Cryst Solids 354(33):3952–3957

    Article  CAS  Google Scholar 

  14. Gomaa MM, Kassab M (2016) Pseudo random renormalization group forward and inverse modeling of the electrical properties of some carbonate rocks. J Appl Geochem 135:144–154

    Google Scholar 

  15. Ibrahim S, Gomaa MM, Darwish H (2014) Influence of Fe2O3 on the physical, structural and electrical properties of sodium lead borate glasses. J Adv Ceram 3(2):155–164

    Article  CAS  Google Scholar 

  16. Zeng Q, Li W, Shi JL, Guo JK, Zuo MW, Wu WJ (2006) A new microwave dielectric ceramic for LTCC applications. J Am Ceram Soc 89(5):1733–1735

    Article  CAS  Google Scholar 

  17. Umemura R, Ogawa H, Yokoi A, Ohsato H, Kan A (2006) Low-temperature sintering-microwave dielectric property relations in Ba3(VO4)2 ceramic. J Alloys Compd 424:388–393

    Article  CAS  Google Scholar 

  18. Ehrt D, Flügel S (2018) Electrical conductivity and viscosity of phosphate glasses and melts. J Non-Cryst Sol 498:461–469

    Article  CAS  Google Scholar 

  19. Sołtys M, Górny A, Pisarska J, Pisarski WA (2018) Electrical and optical properties of glasses and glass-ceramics. J Non-Cryst Sol 498:352–363

    Article  Google Scholar 

  20. Ziemath EC, Escanhoela CA, Braunger ML (2017) Comparison of activation energies for the electrical conductivity of silicate glasses obtained by dc and ac techniques. J Sol St Ion 301:146–151

    Article  CAS  Google Scholar 

  21. Souissi FZ, Ettoumi H, Barré M, Toumi M (2018) Preparation and electrical conductivity of potassium phosphate glasses containing Al2O3. J Non-cryst Sol 481:585–589

    Article  CAS  Google Scholar 

  22. Takahashi K (1953) Thermal expansion coefficient and the structure of glass. J Soc of Glass Tech 37:3

    Google Scholar 

  23. Uhlmann DR (1965) The energetics of nucleation. J IndEngChem 57:19–31

    Google Scholar 

  24. Stanwarth JE (1948) On the structure of glass. J Soc Glass Tech 32:154–172

    Google Scholar 

  25. William MH (2011) CRC handbook of chemistry and physics. (92nd ed.) CRC Press, Hoboken, p 14–48

Download references

Acknowledgments

This work was done within the framework of the research project No. 10060401 entitled “Utilization of Sinai Basaltic Rocks for the Production of Construction Materials” sponsored by National Research Centre.

Author information

Authors and Affiliations

  1. National Research Centre, Glass Research Department, Cairo, Egypt

    G. A. Khater & M. A. Mahmoud

  2. Geophysical Sciences Department, National Research Centre, Cairo, Egypt

    Mohamed M. Gomaa

  3. School of Materials Science and Engineering University of Jinan, Jinan, 250022, China

    Junfeng Kang & Yunlong Yue

Authors
  1. G. A. Khater
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mohamed M. Gomaa
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Junfeng Kang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yunlong Yue
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. A. Mahmoud
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. A. Khater.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Khater, G.A., Gomaa, M.M., Kang, J. et al. Thermal, Electrical and Physical Properties of Glasses Based on Basaltic Rocks. Silicon 12, 645–653 (2020). https://doi.org/10.1007/s12633-019-00142-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12633-019-00142-4

Keywords

Search

Navigation