Abstract
The influence of different pre-oxidation temperatures and pre-oxidation degrees on the reduction and fluidization behaviors of magnetite-based iron ore was investigated in a hydrogen-induced fluidized bed. The raw magnetite-based iron ore was pre-oxidized at 800 and 1000°C for a certain time to reach a partly oxidation and deeply oxidation state. The structure and morphology of the reduced particles were analyzed via optical microscope and scanning electron microscopy (SEM). The reaction kinetic mechanism was determined based on the double-logarithm analysis. The results indicate that the materials with higher oxidation temperature and wider particle size range show better fluidization behaviors. The lower oxidation temperature is more beneficial for the reduction rate, especially in the later reduction stage. The pre-oxidation degree shows no obvious influence on the fluidization and reduction behaviors. Based on the kinetic analysis, the reduction progress can be divided into three stages. The reduction mechanism was discussed combing the surface morphology and phase structure.
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Acknowledgements
The authors gratefully acknowledge the funding support of K1-MET GmbH, metallurgical competence center. The research program of the K1-MET competence center is supported by COMET (Competence Center for Excellent Technologies), the Austrian program for competence centers. COMET is funded by the Federal Ministry for Climate Action, Environment, Energy, Mobility, Innovation and Technology, the Federal Ministry for Digital and Economic Affairs, the provinces of Upper Austria, Tyrol and Styria, and the Styrian Business Promotion Agency (SFG). In addition, the research work is partially financed by Montanuniversitaet Leoben. Heng Zheng greatly acknowledges the financial support from the program of China Scholarship Council (No. 201908420284).
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Zheng, H., Daghagheleh, O., Wolfinger, T. et al. Fluidization behavior and reduction kinetics of pre-oxidized magnetite-based iron ore in a hydrogen-induced fluidized bed. Int J Miner Metall Mater 29, 1873–1881 (2022). https://doi.org/10.1007/s12613-022-2511-7
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DOI: https://doi.org/10.1007/s12613-022-2511-7