Skip to main content
Log in

Effect of thermal fluctuations on magneto-optic rotation in \({\text {CuZnFe}}_2{\text {O}}_4\) ferrofluids

  • Research Article
  • Published:
Journal of Optics Aims and scope Submit manuscript

Abstract

We present results of a magneto optical rotation (MOR) of polarization of light by a suspension of \({\text {Cu}}_{0.8}{\text {Zn}}_{0.2}{\text {Fe}}_2{\text {O}}_4\) nanoparticles in water. Conventional MOR in a dielectric medium arises due to magnetic field induced anisotropy which, in turn leads to a birefringence. On the other hand, magneto optic effects in colloidal supsensions of magnetic nanoparticles arise due to different scattering of different polarizations—a form of dichroism. The differential scattering happens because the nanoparticles align along the magnetic field and polarizations along and perpendicular to field are scattered differently. However, thermal fluctuations affect the alignment of the nanoparticles and hence the resulting anisotropy. We show that an increased thermal fluctuation reduces the effective MOR. This sample also exhibits a hysteresis behaviour, which is consistent with the viscosity measurement—clearly indicating that the MOR effect is due to the same anisotropy caused by alignment of magnetic nanoparticles, which also affects the viscosity and all other parameters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. H.C. van de Hulst, Light Scattering by Small Particles (Dover Publications, N.Y., 1957)

    Google Scholar 

  2. A.T. Young, Rayleigh scattering. Appl. Opt. 4, 533 (1981)

    Article  ADS  Google Scholar 

  3. R.S. Krishnan, Reciprocity theorem in colloidal optics (case of orientated particles). Proc. Indian Acad. Sci. 1, 717 (1935)

    Article  Google Scholar 

  4. R.S. Krishnan, The reciprocity theorem in colloidal optics and its application. Proc. Indian Acad. Sci. 7, 21 (1938)

    Article  Google Scholar 

  5. J. Laskar, John Phillip, B. Raj, Experimental evidence for reversible zippering of chains in magnetic nanofluids under external magnetic fields. Phys. Rev. E 78, 031404 (2008)

    Article  ADS  Google Scholar 

  6. M. Shalini, D. Sharma, A.A. Deshpande, D. Mathur, Hema Ramachandran, N. Kumar, Light scattering from a magnetically tunable dense random medium with dissipation: ferrofluid. Eur. Phys. J. D 66, 30 (2012)

    Article  ADS  Google Scholar 

  7. R.V. Mehta, Polarization dependent extinction coefficients of superparamagnetic colloids in transverse and longitudinal configurations of magnetic field. Opt. Mater. 35, 1436 (2013)

    Article  CAS  ADS  Google Scholar 

  8. Z. Qi, W. JianHua, Z. Hexun, Light scattering from ferrofluids in strong magnetic fields. J. Colloid Interface Sci. 172, 155 (1995)

    Article  ADS  Google Scholar 

  9. Q. Majorana, Sur la biréfringence magnétique. C.R. Acad. Sci. Paris 135, 159 (1902)

    Google Scholar 

  10. B.J. Lemaire, P. Davidson, J.F.J.-P. Jamet, D. Petermann, Pierre Panine, I. Dozov, D. Stoenescuc, J.-P. Jolivet, The complex phase behaviour of suspensions of goethite (a-FeOOH) nanorods in a magnetic field. Faraday Discuss. 128, 271 (2005)

    Article  CAS  PubMed  ADS  Google Scholar 

  11. H. Davies, P. Llewellyn, Magneto-optic effects in ferrofluids. J. Phys. D Appl. Phys. 13, 2327 (1980)

    Article  CAS  ADS  Google Scholar 

  12. T. Haider, A review of magneto-optic effects and its application. Int. J. Electromagn. Appl. 7, 17 (2017)

    Google Scholar 

  13. N.A. Yusuf, I.O. Abu-Aljarayesh, Magneto-optical and magneto-dielectric anisotropy effects in magnetic fluids. Jordan J. Phys. 2, 1 (2009)

    Google Scholar 

  14. R. Karthick, K. Ramachandran, R. Srinivasan, Study of Faraday effect on Co\(_{1-x}\)Zn\(_x\)Fe\(_2\)O\(_4\) nanoferrofluids. Nanosyst. Phys. Chem. Math. 7, 624 (2016)

    Article  CAS  Google Scholar 

  15. J.P. Llewellyn, Form birefringence in ferrofluids. J. Phys. D Appl. Phys. 16, 95 (1983)

    Article  CAS  ADS  Google Scholar 

  16. S. Küçükdermenci, D. Kutluay, Ibrahim Avgin, Synthesis of a Fe3O4/PPA-based magnetic fluid for Faraday-rotation measurements. Mater. Technol. 47, 71 (2013)

    Google Scholar 

  17. S. Wang, C. Sun, D. Lin, C. Yao, Yong Yang, Reciprocity of Faraday effect in ferrofluid: comparison with magneto-optical glass. Optik 123, 553 (2012)

    Article  CAS  ADS  Google Scholar 

  18. B. Issa, I.M. Obaidat, B.A. Albiss, Y. Haik, Magnetic nanoparticles: surface effects and properties related to biomedicine applications. Int. J. Mol. Sci. 14, 21266 (2013)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  19. A.A. Velásquez, J.P. Urquijo, Implementation and automation of a Faraday experiment for the magneto-optical characterization of ferrofluids. Meas. Sci. Technol. 27, 015303 (2016)

    Article  ADS  Google Scholar 

  20. D. Lin, W. Shibin, L. Sen, Dynamic Faraday magneto-optical properties of the water-based Fe3O4 magnetic fluids, in IEEE Annual Report Conference on Electrical Insulation and Dielectic Phenomena (2010)

  21. John Philip, J.M. Laskar, Optical properties and applications of ferrofluids-a review. J. Nanofluids 1, 3 (2012)

    Article  CAS  Google Scholar 

  22. C.Z. Fan, G. Wang, J.P. Huang, Magnetocontrollable photonic crystals based on colloidal ferrofluids. J. Appl. Phys. 103, 094107 (2008)

    Article  ADS  Google Scholar 

  23. V. Mahendran, John Philip, Nanofluid based optical sensor for rapid visual inspection of defects in ferromagnetic materials. Appl. Phys. Lett. 100, 073104 (2012)

    Article  ADS  Google Scholar 

  24. Ibrahim Sharifi, H. Shokrollahi, S. Amiri, Ferrite-based magnetic nanofluids used in hyperthermia applications. J. Magn. Magn. Mater. 324, 903 (2012)

    Article  CAS  ADS  Google Scholar 

  25. P. Trivedi, Rajesh Patel, K. Parekh, R.V. Upadhyay, R.V. Mehta, Magneto-optical effects in temperature-sensitive ferrofluids. Appl. Opt. 43, 3619 (2004)

    Article  CAS  PubMed  ADS  Google Scholar 

  26. N. Gautam, G. Thirupathi, R. Singh, Magnetoviscosity of paraffin-based barium ferrite ferrofluid. IEEE Trans. Magn. 52, 4600204 (2016)

    Article  Google Scholar 

  27. N. Gautam, G. Thirupathi, Rajender Singh, Magneto-viscosity of hydrothermal synthesized Cu–Zn ferrite ferrofluids. AIP Adv. 7, 056727 (2017)

    Article  ADS  Google Scholar 

  28. Nisha Gautam, R. Singh, Magneto-viscosity of stable colloidal solutions of barium–strontium hexaferrite ferrofluid. Mater. Res. Express 6, 084012 (2019)

    Article  CAS  ADS  Google Scholar 

  29. T. Kruse, H.-G. Krauthäuser, A. Spanoudaki, Rolf Pelster, Agglomeration and chain formation in ferrofluids: two-dimensional x-ray scattering. Phys. Rev. B 67, 094206 (2003)

    Article  ADS  Google Scholar 

  30. J. Masajada, Marcin Bacin, S. Drobczyński, Cluster formation in ferrofluids induced by holographic optical tweezers. Opt. Lett. 38, 3910 (2013)

    Article  PubMed  ADS  Google Scholar 

  31. A.M. Biller, O.V. Stolbov, Y.L. Raikher, Modeling of particle interactions in magnetorheological elastomers. J. App. Phys. 116, 114904 (2014)

    Article  ADS  Google Scholar 

Download references

Acknowledgements

We sincerely thank UGC-Networking Resource Center, School of Physics, University of Hyderabad for use of characterization facilities. AC thanks Ministry of Tribal Affairs, Govt. of India, for financial support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ashok Vudayagiri.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Challam, A., Nandikonda, M., Gautam, N. et al. Effect of thermal fluctuations on magneto-optic rotation in \({\text {CuZnFe}}_2{\text {O}}_4\) ferrofluids. J Opt 53, 328–335 (2024). https://doi.org/10.1007/s12596-023-01274-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12596-023-01274-y

Keywords

Navigation