Skip to main content
Log in

Effect of Precipitate State on Mechanical Properties, Corrosion Behavior, and Microstructures of Al–Zn–Mg–Cu Alloy

  • Published:
Metals and Materials International Aims and scope Submit manuscript

Abstract

The mechanical properties, corrosion behavior and microstructures of the Al–Zn–Mg–Cu alloy under various ageing treatments were investigated comparatively. The results show that the tensile strength and corrosion resistance are strongly affected by the precipitate state. Massive fine intragranular precipitates contribute to high strength. Discontinuous coarse grain boundary precipitates containing high Cu content, as well as the narrow precipitate free zone, result in low corrosion susceptibility. After the non-isothermal ageing (NIA) treatment, the tensile strength of 577 MPa is equivalent to that of 579 MPa for the T6 temper. Meanwhile, the stress corrosion susceptibility rtf and the maximum corrosion depth are 97.8% and 23.5 μm, which are comparable to those of 92.8% and 26.7 μm for the T73 temper. Moreover, the total ageing time of the NIA treatment is only 7.25 h, which is much less than that of 48.67 h for the retrogression and re-ageing condition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. H. Queudet, S. Lemonnier, E. Barraud, J. Ghanbaja, N. Allain, E. Gaffet, Mater. Sci. Eng. A 685, 71 (2017)

    Article  Google Scholar 

  2. J.Z. Chen, L. Zhen, S.J. Yang, W.Z. Shao, S.L. Dai, Mater. Sci. Eng. A 500, 34 (2009)

    Article  Google Scholar 

  3. K.K. Ma, T. Hu, H. Yang, T. Topping, A.L. Yousefiani, E.J. Lavernia, J.M. Schoenung, Acta Mater. 103, 153 (2016)

    Article  Google Scholar 

  4. T. Marlaud, B. Malki, C. Henon, A. Deschamps, B. Baroux, Corros. Sci. 53, 3139 (2011)

    Article  Google Scholar 

  5. M. Puiggali, A. Zielinski, J.M. Olive, E. Renauld, D. Desjardins, M. Cid, Corros. Sci. 40, 805 (1998)

    Article  Google Scholar 

  6. L.P. Huang, K.H. Chen, S. Li, M. Song, Scripta Mater. 56, 305 (2007)

    Article  Google Scholar 

  7. P.K. Rout, M.M. Ghosh, K.S. Ghosh, Mater. Sci. Eng. A 604, 156 (2014)

    Article  Google Scholar 

  8. J. Wloka, T. Hack, S. Virtanen, Corros. Sci. 49, 1437 (2007)

    Article  Google Scholar 

  9. J.F. Chen, X.F. Zhang, L.C. Zou, Y. Yua, Q. Li, Mater. Charact. 114, 1 (2016)

    Article  Google Scholar 

  10. W.C. Yang, S.X. Ji, Q. Zhang, M.P. Wang, Mater. Des. 85, 752 (2015)

    Article  Google Scholar 

  11. Y.C. Lin, J.L. Zhang, G. Liu, Y.J. Liang, Mater. Des. 83, 866 (2015)

    Article  Google Scholar 

  12. P.K. Rout, M.M. Ghosh, K.S. Ghosh, Mater. Charact. 104, 49 (2015)

    Article  Google Scholar 

  13. B.M. Cina, US Patent 3856584, (1974)

  14. J.-P. Immarigeon, R.T. Holt, A.K. Koul, L. Zhao, W. Wallace, J.C. Beddoes, Mater. Charact. 35, 41 (1995)

    Article  Google Scholar 

  15. A.F. Oliveira Jr., M.C. de Barros, K.R. Cardoso, D.N. Travessa, Mater. Sci. Eng. A 379, 321 (2004)

    Article  Google Scholar 

  16. Z.H. Li, B.Q. Xiong, Y.G. Zhang, B.H. Zhu, F. Wang, H.W. Liu, J. Mater. Process. Technol. 209, 2021 (2009)

    Article  Google Scholar 

  17. J.T. Staley, Durham US Patent, 0237113Al, (2007)

  18. J.T. Jiang, Q.J. Tang, L. Yang, K. Zhang, S.J. Yuan, L. Zhen, J. Mater. Process. Technol. 227, 110 (2016)

    Article  Google Scholar 

  19. D.M. Jiang, Y. Liu, S. Liang, W.L. Xie, J. Alloys Compd. 681, 57 (2016)

    Article  Google Scholar 

  20. J.T. Jiang, W.Q. Xiao, L. Yang, W.Z. Shao, S.J. Yuan, L. Zhen, Mater. Sci. Eng. A 605, 167 (2014)

    Article  Google Scholar 

  21. Y. Liu, D.M. Jiang, B.Q. Li, W.S. Yang, J. Hu, Mater. Des. 57, 79 (2014)

    Article  Google Scholar 

  22. Y. Liu, D.M. Jiang, W.J. Li, J. Alloys Compd. 671, 408 (2016)

    Article  Google Scholar 

  23. X.Y. Peng, Q. Guo, X.P. Liang, Y. Deng, Y. Gua, G.F. Xu, Zhimin Yin, Mater. Sci. Eng., A 688, 146 (2017)

    Article  Google Scholar 

  24. GB 7998-2005, National standard of China

  25. O.N. Senkov, S.V. Senkova, M.R. Shagiev, Effect of Sc on aging kinetics in a direct chill cast Al–Zn–Mg–Cu alloy. Metall. Mater. Trans. A 39, 1034 (2008)

    Article  Google Scholar 

  26. R. Goswami, S. Lynch, N.J. Henry Holroyd, S.P. Knight, R.L. Holtz, Metall. Mater. Trans. A 44, 1268 (2013)

    Article  Google Scholar 

  27. J.Z. Liu, J.H. Chen, X.B. Yang, S. Ren, C.L. Wu, H.Y. Xu, J. Zou, Scripta Mater. 63, 1061 (2010)

    Article  Google Scholar 

  28. L. Hadjadj, R. Amira, D. Hamana, A. Mosbah, J. Alloys Compd. 462, 279 (2008)

    Article  Google Scholar 

  29. L.K. Berg, J. Gjønnes, V. Hsnsen, X.Z. Li, M. Knutson-Wedel, G. Waterloo, D. Schryvers, L.R. Wallenberg, Acta Mater. 49, 3443 (2001)

    Article  Google Scholar 

  30. E. Arzt, Acta Metall. 46, 5611 (1998)

    Google Scholar 

  31. J.M. Fragomeni, B.M. Hillberry, Acta Mech. 138, 185 (1999)

    Article  Google Scholar 

  32. J.F. Li, N. Birbilis, C.X. Li, Z.Q. Jia, B. Cai, Z.Q. Zheng, Mater. Charact. 35, 1334 (2009)

    Article  Google Scholar 

  33. K.S. Ghosh, K. Das, U.K. Chatterjee, Mater. Corros. 3, 181 (2007)

    Article  Google Scholar 

  34. Y. Deng, Z.M. Yin, K. Zhao, J.Q. Duan, J. Hu, Z.B. He, Corros. Sci. 65, 288 (2012)

    Article  Google Scholar 

  35. S.Y. Chen, K.H. Chen, G.S. Peng, L. Jia, P.X. Dong, Mater. Des. 35, 93 (2012)

    Article  Google Scholar 

  36. R.G. Song, M.K. Tseng, B.J. Zhang, J. Liu, Z.H. Jin, K.S. Shin, Acta Mater. 44, 3241 (1996)

    Article  Google Scholar 

  37. R.G. Song, W. Dietzel, B.J. Zhang, W.J. Liu, M.K. Tseng, Acta Mater. 52, 4727 (2004)

    Article  Google Scholar 

  38. J.R. Pickens, T.J. Langan, Metall. Trans. A 18, 1735 (1987)

    Article  Google Scholar 

  39. D. Najjar, T. Magnin, T.J. Warner, Mater. Sci. Eng. A 238, 293 (1997)

    Article  Google Scholar 

  40. X.Y. Sun, B. Zhang, H.Q. Lin, Y. Zhou, L. Sunb, J.Q. Wang, E.H. Han, W. Ke, Corros. Sci. 77, 103 (2013)

    Article  Google Scholar 

  41. Y.J. Shi, Q.L. Pan, M.J. Li, X. Huang, B. Li, Mater. Sci. Eng. A 621, 173 (2015)

    Article  Google Scholar 

  42. K. Rajan, W. Wallace, J.C. Beddoes, J. Mater. Sci. 17, 2817 (1982)

    Article  Google Scholar 

  43. G.A. YoungJr, J.R. Scully, Metall. Mater. Trans. A 33, 1167 (2002)

    Article  Google Scholar 

  44. T. Ramgopal, P.I. Gouma, G.S. Frankel, Corros. 58, 687 (2002)

    Article  Google Scholar 

  45. T. Marlaud, A. Deschamps, F. Bley, W. Lefebvre, B. Baroux, Acta Mater. 58, 248 (2010)

    Article  Google Scholar 

  46. S.P. Knight, N. Birbilis, B.C. Muddle, A.R. Trueman, S.P. Lynch, Corros. Sci. 52, 4073 (2010)

    Article  Google Scholar 

  47. N. Birbilis, R.G. Buchheit, J. Electro. Soc. 152, 140 (2005)

    Article  Google Scholar 

  48. M.B. Kannan, V.S. Raja, J. Mater. Sci. 42, 5458 (2007)

    Article  Google Scholar 

  49. T. Ramgopal, P. Schmutz, G.S. Frankel, J. Electro. Soc. 148, 348 (2001)

    Article  Google Scholar 

  50. Y. Deng, R. Ye, G.F. Xu, J.D. Yang, Q.L. Pan, B. Peng, X.W. Cao, Y.L. Duan, Y.J. Wang, L.Y. Lu, Z.M. Yin, Corros. Sci. 90, 359 (2015)

    Article  Google Scholar 

  51. H. Qi, X.Y. Liu, S.X. Liang, X.L. Zhang, H.X. Cui, L.Y. Zheng, F. Gao, Q.H. Chen, J. Alloys Compd. 657, 318 (2016)

    Article  Google Scholar 

Download references

Acknowledgements

This investigation was financially supported by the Fundamental Research Funds for the Central Universities of Central South University (No. 2015zzts023) and the Guangdong Province Science and Research Plan Project (2016B090931004).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guofu Xu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Peng, X., Li, Y., Xu, G. et al. Effect of Precipitate State on Mechanical Properties, Corrosion Behavior, and Microstructures of Al–Zn–Mg–Cu Alloy. Met. Mater. Int. 24, 1046–1057 (2018). https://doi.org/10.1007/s12540-018-0057-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12540-018-0057-z

Keywords

Navigation