Abstract
During continuous casting process of low carbon micro-alloyed steel containing vanadium, the evolution of strand surface microstructure and the precipitation of secondary phase particles (mainly V(C, N)) are significantly influenced by cooling rate. In this paper, influence of cooling rate on the precipitation behavior of proeutectoid α-ferrite at the γ-austenite grain boundary and in the steel matrix are in situ observed and analyzed through high temperature confocal laser scanning microscopy. The relationship between cooling rate and precipitation of V(C, N) from steel continuous casting bloom surface microstructure is further studied by scanning electron microscopy and electron dispersive spectrometer. Relative results have shown the effect of V(C, N) precipitation on α-ferrite phase transformation is mainly revealed in two aspects: (i) Precipitated V(C, N) particles act as inoculant particles to promote proeutectoid ferrite nucleation. (ii) Local carbon concentration along the γ-austenite grain boundaries is decreased with the precipitation of V(C, N), which in turn promotes α-ferrite precipitation.
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References
W. Derda and J. Wiedermann, Arch. Metall. Mater. 57, 303 (2012).
Z. Mohamed, Mater. Sci. Eng. A 326, 255 (2002).
B. Mintz, ISIJ Int. 39, 833 (1999).
M. Bobadilla, J. M. Jolivet, J. Y. Lamant, and M. Larrecq, Mater. Sci. Eng. A 173, 275 (1993).
F. J. Ma, G. H. Wen, P. Tang, X. Yu, J. Y. Li, G. D. Xu, and F. Mei, Ironmak. Steelmak. 37, 73 (2010).
K. R. Carpenter, R. Dippenaar, and C. R. Killmore, Metall. Mater. Trans. A 40, 573 (2009).
B. Mintz, Mater. Sci. Tech. 24, 112 (2008).
F. J. Ma, G. H. Wen, and W. L. Wang, Steel Res. Int. 84, 370 (2013).
J. G. Jung, J. S. Park, J. Y. Kim, and Y. K. Lee, Mater. Sci. Eng. A 528, 5529 (2011).
M. Arribas, B. López, and J. M. Rodriguez-Ibabe, Mater. Sci. Eng. A 485, 383 (2008).
A. A. D. Santos and R. Barbosa, Steel Res. Int. 80, 632 (2009).
H. Ohta, R. Inoue, and H. Suito, ISIJ Int. 48, 294 (2008).
J. Chen, M. Y. Lv, S. Tang, Z. Liu, and G. Wang, Mater. Sci. Eng. A 594, 389 (2014).
J. S. Park, Y. S. Ha, S. J. Lee, and Y. K. Lee, Metall. Mater. Trans. A 40, 560 (2009).
S. S. Xie, J. D. Lee, U. S. Yoon, and C. H. Yim, ISIJ Int. 42, 708 (2002).
W. J. Liu, Metall. Mater. Trans. A 26, 1641 (1995).
V. S. A. Challa, W. H. Zhou, R. D. K. Misra, and R. O’Malley, Mater. Sci. Eng. A 595, 143 (2014).
H. Yin, T. Emi, and H. Shibata, Acta Mater. 47, 1523 (1999).
H. Yin, T. Emi, and H. Shibata, ISIJ Int. 38, 794 (1998).
S. Kimura, K. Nakajima, S. Mizoguchi, and H. Hasegawa, Metall. Mater. Trans. A 33, 427 (2002).
H. Hasegawa, K. Nakajima, and S. Mizoguchi, Tetsu-to-Hagané 87, 433 (2001).
S. Zhao, D. Wei, R. Li, and L. Zhang, Mater. Trans. 55, 1274 (2014).
Z. P. Xiong, A. G. Kostryzhev, N. E. Stanford, and E. V. Pereloma, Mater. Sci. Eng. A 651, 291 (2016).
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Dou, K., Meng, L., Liu, Q. et al. Influence of cooling rate on secondary phase precipitation and proeutectoid phase transformation of micro-alloyed steel containing vanadium. Met. Mater. Int. 22, 349–355 (2016). https://doi.org/10.1007/s12540-016-2676-6
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DOI: https://doi.org/10.1007/s12540-016-2676-6