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Fluid evolution and ore genesis of the Lianhuashan lode gold deposit, northern North China Craton: evidence from fluid inclusions and H–O–C–S–Pb isotopes

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Abstract

The Lianhuashan Au deposit, located in the northern margin of North China Craton, is hosted in the metamorphic rocks of Neoarchean Wulashanyan Group along NNW- to N-trending faults, with pyrite as the predominant ore mineral. The mineralization process can be divided into four stages, involving stage I quartz-pyrite, stage II quartz-magnetite-chalcopyrite, stage III quartz-marcasite-pyrite, and stage IV quartz-calcite. Three types of fluid inclusions (FIs) have been identified, namely, pure carbonic inclusions (PC-type), aqueous-carbonic inclusions (AC-type), and aqueous inclusions (A-type). Stage I auriferous quartz veins host all three types of FIs, inclusions from stage II quartz are AC- and A-type, and only A-type FIs are recognized in stage III quartz and stage IV calcite veins. The FIs of stages I to IV were homogenized at temperatures of 300–360 °C, 275–326 °C, 252–289 °C, and 220–264 °C, with salinities of 4.0–11.7 wt%, 3.4–9.3 wt%, 2.1–7.0 wt%, and 1.4–3.1 wt% NaCl eqv., respectively. The ore-forming fluids belong to a medium-temperature, low-salinity H2O–NaCl–CO2 system. Gold deposition was likely caused by fluid immiscibility. The δDH2O and δ18OH2O values of ore fluids vary from −121.1 to −112.4‰ and from 2.8 to 6.2‰, respectively, within the range of enriched mantle-derived fluids in the North China Craton. The carbon isotope compositions of calcite (δ13CPDB = −2.87 to −2.38‰) show the features of mantle carbon. S-Pb isotope compositions of pyrite (δ34S = 2.58-3.96, 206Pb/204Pb = 16.077-16.119, 207Pb/204Pb = 15.329-15.332, and 208Pb/204Pb = 37.305-37.338) reveal that the ore-forming materials may have originated from crustal rocks. Based on the geological and geochemical observations, we suggest that the Lianhuashan deposit can be classified as an orogenic gold deposit.

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Acknowledgements

We thank Xueli Ma, He Yang, Gesine Preuß, Tobias Kluge, Dominik Gudelius, Mu Liu, and Dewei Kong for their help in the field and analytical work. We gratefully acknowledge an anonymous reviewer for constructive comments and Federico Lucci for editorial handling.

Funding

This study is supported by the Opening Foundation of MNR Key laboratory of Mineral Resources Evaluation in Northeast Asia (DBY-KF-18-08).

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  1. MNR Key Laboratory of Mineral Resources Evaluation in Northeast Asia, College of Earth Sciences, Jilin University, Changchun, 130061, China

    Kaituo Shi, Keyong Wang & Rui Wang

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  1. Kaituo Shi
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Correspondence to Keyong Wang.

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Supplementary Information

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12517_2021_8850_MOESM1_ESM.docx

Supplementary file1 Fig. S1. Representative single-spot LA-ICPMS analytical signals of pyrite from Lianhuashan Au deposit, showing the element assemblages of Au-Ag-As-Te-Bi-Pb-Cu in the pyrite lattice. Note: The LA-ICP-MS spot analyses were carried out at the Institute of Applied Geosciences, Karlsruhe Institute of Technology, Germany, using a Teledyne Analyte Excite+ 193 nm laser coupled to a Thermo Element XR ICP-MS. (DOCX 2179 KB)

12517_2021_8850_MOESM2_ESM.docx

Supplementary file2 Table S1: Comparison between the Lianhuashan Au deposit and typical orogenic gold deposits worldwide. (DOCX 22 KB)

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Shi, K., Wang, K. & Wang, R. Fluid evolution and ore genesis of the Lianhuashan lode gold deposit, northern North China Craton: evidence from fluid inclusions and H–O–C–S–Pb isotopes. Arab J Geosci 14, 2529 (2021). https://doi.org/10.1007/s12517-021-08850-1

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