Abstract
The aim of this research is to provide a potential reserve of claystone suitable for ordinary Portland cement (OPC) industry using clay from the geological formation instead of the recent clay currently being exploited with negatively affects the environment as they reduce the agricultural soil. For this purpose, the thick exposed bed of Late Miocene clays of Injana Formation was targeted and evaluated in terms of mineralogy and geochemistry. Many laboratory experiments resulted in the production of clinker which was also assessed and passed successfully for the OPC. The main raw materials required for cement production are limestone and clay. The over-consumption of the recent clay for OPC participated in the stimulation the use of Late Miocene claystones alternatively which are added to the raw mixture (RM) of cement at a certain ratio. The Late Miocene Injana claystones are composed of kaolinite, illite, and chlorite, quartz, calcite, feldspar, and gypsum. The raw material composed of claystones to limestones (1:3 volume) has provided a cement mixture of Silica Ratio (SR = 2.8), Alumina Ratio (AR = 1.94), Silica Saturation Factor (SSF = 0.9), Lime Saturation Factor (LSF = 90.2), and a clinker composes mainly of alite (51. 67), belite (26. 65), aluminate (9.65), and ferrite (8. 4). Among the most important conclusions of this study is the validity of the clay studied for the cement industry, and with this conclusion, this research has proven that there is a huge reserve that can be used for OPC and encourage to save the agricultural lands without extraction.
Similar content being viewed by others
References
Abou Elmagd K, Emam A, Ali-Bik MW, Hazem M (2018) Geochemical assessment of Paleocene limestones of Sinn El-Kaddab plateau, South Western Desert of Egypt, for industrial uses. Arab J Geosci 11(13):355
Al Khafaji ZS, Ruddock F (2018) Study the retardant effect of using different sugar’s types on setting time and temperature of cement paste. Int J Civ Eng Technol 9(1)
Al-Auweidy M (2013) Qualitative, quantitative and radiological assessment of marl layer in the Euphrates Formation for Portland cement industry in Kufa cement quarry at Al-Najaf Governorate. Unpublished M SC thesis, University of Baghdad, College of Science, 136 pp
Al-Dabbas M, Awadh SM, Zaid AA (2013) Mineralogy, geochemistry, and reserve estimation of the Euphrates limestone for Portland cement industry at Al-Najaf area, South Iraq. Arab J Geosci 6(2):491–503
Al-Dabbas MA, Awadh SM, Zaid AA (2014) Facies analysis and geochemistry of the Euphrates formation in Central Iraq. Arab J Geosci 7(5):1799–1810
Ali KK, Awadh SM, Al-Auweidy MR (2014) Assessment natural radioactivity of marl as raw material at Kufa cement quarry in Najaf governorate. Iraqi Journal of Science 55(2):454–462
Al-Mamoori SK, Al-Maliki LA, Al-Sulttani AH, El-Tawil K, Hussain HM, Al-Ansari N (2020) Horizontal and vertical geotechnical variations of soils according to USCS classification for the city of an-Najaf, Iraq using GIS. Geotech Geol Eng 38:1919–1938
Awadh SM (2010) Geochemistry of termite hills as a tool for geochemical exploration of glass sand in the Iraqi Western Desert. Int J Geosci 1(03):130–138
Awadh SM (2014) Stable carbon and nitrogen isotopes and elemental composition and origin of organic matter from the Neogene Euphrates, Injana and Dibdibba formations in Iraq: discrimination between marine and terrestrial environments. Geol Q 58(4):729–736. https://doi.org/10.7306/gq.1174
Awadh SM, Abdullah HH (2011) Mineralogical, geochemical, and geotechnical evaluation of Al-Sowera soil for the building brick industry in Iraq. Arab J Geosci 4(3–4):413–419
Awadh SM, Ahmed RM (2013) Hydrochemistry and pollution probability of selected sites along the Euphrates River, Western Iraq. Arab J Geosci 6(7):2501–2518
Awadh SM, Abood ZS, Eisa MJ (2013a) Chemical and physical control processes on the development of caves in the Injana formation, Central Iraq. Arab J Geosci 6(10):3765–3772
Awadh SM, Ali KK, Alazzawi AT (2013b) Geochemical exploration using surveys of spring water, hydrocarbon and gas seepage, and geobotany for determining the surface extension of Abu-Jir fault zone in Iraq: a new way for determining geometrical shapes of computational simulation models. J Geochem Explor 124:218–229
Awadh SM, Al-Bahadily HA, Al-Ankaz ZS (2018) Interpreting the tectonics of the Abu Jir fault, Karbla–Najaf plateau using mineralogical and geophysical data. Iraqi Bulletin of Geology and Mining 14(1):47–63
Bond JE, Coursaux R, Worthington RL (2000) Blending systems and control technologies for cement raw materials. IEEE Ind Appl Mag 6(6):49–59
Chatterjee KK (2009) Uses of industrial minerals, rocks and freshwater. Nova Science Publishers,
Duda WH (1988) Cement-data-book: Rohmaterial für die Zementherstellung, vol 3. Bauverlag,
Jassim SZ, Goff JC (2006) Geology of Iraq. DOLIN, sro, distributed by Geological Society of London
Kebede MA (2010) Investigation of calcite and volcanic ash for their utilization as cement filling and additive materials. Unpublished M Sc Thesis Addis Ababa University School of Graduate Studies
Kosmatka SH, Kerkhoff B, Panarese WC (2002) Design and control of concrete mixtures, vol 5420. Portland Cement Association Skokie, IL
Li Z (2011) Advanced concrete technology. John Wiley & Sons
Majdi HS, Shubbar A, Nasr MS, Al-Khafaji ZS, Jafer H, Abdulredha M, Al Masoodi Z, Sadique M, Hashim K (2020) Experimental data on compressive strength and ultrasonic pulse velocity properties of sustainable mortar made with high content of GGBFS and CKD combinations. Data in Brief
Marzouki A, Lecomte A, Beddey A, Diliberto C, Ouezdou MB (2013) The effects of grinding on the properties of Portland-limestone cement. Constr Build Mater 48:1145–1155
Mirza TA, Fatah CM (2018) Evaluating the suitability of Avroman limestone, Halabja governorate for cement industry. Iraqi Bulletin of Geology and Mining 14(1):103–120
Newman J, Choo BS (2003) Advanced concrete technology set. Elsevier
Ono Y (1981) Microscopical observation of clinker for the estimation of burning condition, grindability and hydraulic activity. In: Proceedings of the Third International Conference on Cement Microscopy. pp 198–210
Qi C, Chen Q, Dong X, Zhang Q, Yaseen ZM (2020) Pressure drops of fresh cemented paste backfills through coupled test loop experiments and machine learning techniques. Powder Technol 361:748–758
Qureshi M, Varshney K (1991) Inorganic ion exchangers in chemical analysis. CRC press
Rao D, Vijayakumar T, Prabhakar S, Raju GB (2011) Geochemical assessment of a siliceous limestone sample for cement making. Chin J Geochem 30(1):33–39
Ridi F (2010) Hydration of cement: still a lot to be understood. La Chim L’Industria 3:110–117
Schneider M, Romer M, Tschudin M, Bolio H (2011) Sustainable cement production—present and future. Cem Concr Res 41(7):642–650
Shah M, Fayez A, Ali L (2007) Chemical study of the raw material in Gandghar range, district Haripur, NWFP, for Portland cement manufacturing. J Chem Soc Pak 29(2)
Sissakian V, AbdulJabbar M, Al-Ansari N, Knutsson S (2015) The origin of tar Al-Say’ed and tar Al-Najaf, Karbala-Najaf vicinity, Central Iraq. Journal of Civil Engineering and Architecture 9(4):446–459
Taylor S, Rankin G, Cleland D (2001) Arching action in high-strength concrete slabs. Proceedings of the Institution of Civil Engineers-Structures and Buildings 146(4):353–362
Unegbu AO, Okanlawon A (2015) Direct foreign investment in Kurdistan region of Middle-East: non-oil sector analysis. arXiv preprint arXiv:150200218
Zainab S, Zainab A, Jafer H, Dulaimi A, Atherton W (2018) The effect of using fluid catalytic cracking catalyst residue (FC3R) “as a cement replacement in soft soil stabilisation”. Int J Civ Eng Technol 9(4):522–533
Acknowledgments
The authors are grateful to the geochemistry staff in the Department of Geology, College of Science, University of Baghdad for their assistance. Our deep thanks also go to the field work team and the staff of the laboratories of the Building Research Center at the Ministry of Construction and Housing- Iraq for their fruitful assistance. Authors are very grateful to the staff of the ALS, laboratory group, Spain, staff for their admirable efforts done for chemical analysis and thankful for the Iraq-Germany Lab staff for their help in XRF analysis.
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible Editor: Amjad Kallel
Rights and permissions
About this article
Cite this article
Awadh, S.M., Awad, A.M. Manufacture of Portland cement from Late Miocene claystone, Injana formation, Central Iraq. Arab J Geosci 13, 1008 (2020). https://doi.org/10.1007/s12517-020-06032-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12517-020-06032-z