Abstract
The mineralogy and origin of the schist hosted manganite and sandstone hosted goethite mineralizations west of Zuru schist belt Nigeria was investigated. A total of five goethite and ten manganite samples were selected. Half of each samples were pulverized and subjected to geochemical analysis for the major oxides, trace and rare earth elemental compositions using X-ray fluorescence while the other halves were polished for their mineralogical analyses through Raman spectroscopy. The result of the Raman spectroscopy showed that the manganites were made up essentially of psilomelane, todorokite and brookite, while the goethites were dominantly goethite, rutile and ilmenite. The result of the elemental analysis was subjected to Principal Component Analysis (PCA) using SPSS 22 software and discriminating plots using TriPlot software. The results of the discriminating plots showed that the goethites were related to hydrothermal processes whereas the manganite ores related to detrital-diagenetic processes. The conclusion drawn from the integration of field evidences, geochemical results, mineralogy, cluster analysis and discriminating plots was that the manganite ores were products of supergene enrichment, while in contrast, the goethites were formed primarily from hydrothermal processes but have been remobilized to its present position as a result of changing Eh-pH conditions in Kaoje and its environs.
Similar content being viewed by others
References
Ajibade AC, Woakes M, Rahaman MA (1987) Proterozoic crustal development in the Precambrian regime of Nigeria. In: Kroner A (ed) Proterozoic lithospheric evolution, geodynamics series. American Geophysical Union, Washington, D.C., pp 259–271
Akande SO, Kinnaird J (1992) Characterization and origin of ore forming fluids in the Nigerian mineral belts. In: Maurice Y (ed) Symposium vol. International Assoc. on the Genesis of Ore Deposits (I.A.G.O.D.). Schweizerbatsche Press, Stuttgart, pp 199–218
Andrew-Jones DA (1968) The application of geochemical techniques to mineral exploration. Colombia School of Mines, Mineral Industry Bulletin 11(6):1–31
Barton MD, Johnson DA (2000) Alternative brine sources for Fe-oxide (-Cu-Au) systems: implications for hydrothermal alteration and metals. In: Porter TM (ed) Hydrothermal iron oxide copper-gold and related deposits: a global perspective. Australian Mineral Foundation, Adelaide, pp 43–60
Bassey C, Eminue O (2014) Preliminary evaluation of major and trace elements content of Cretaceous–Palaeogene Formation of the Sokoto Basin, northwestern Nigeria. Nafta 65(1):69–76
Beura D, Singh P, Satpathy B, Behera S, Nanda SK (2016) Field relationship among the three iron ore groups of iron ore super group encircling the North Odisha Iron Ore Craton, India: a comparison study. J Geosci Geomat 4(3):53–60
Bonatti E, Kraemer T, Rydell H (1972) Classification and genesis of submarine iron-manganese deposits. In: Horn D (ed) Ferromanganese deposits on the ocean floor: international decade on ocean exploration. National Science Foundation, Washington, D.C., pp 149–166
Crerar DA, Namson J, Chyi MS, Williams L, Feigenson IM (1982) Manganiferous cherts of the Fransiscan assemblage: I. General geology, ancient and modern analogues, and implications for hydrothermal convection at oceanic spreading centers. Econ Geol 77:519–540
Curtis LH (2008) Modification to Goldschmidt’s geochemical classification of elements to include arsenic, mercury and lead as biophile elements in: concepts and applications in environmental geochemistry. Editted by D. Sarkar, R. Datta and R. Hannigan. Elsevier Ltd, UK. In: 9–31
Danbatta UA, Garba ML (2007) Geochemistry and petrogenesis of Precambrian amphibolites in the Zuru schist belt, northwestern Nigeria. J Min Geol 43(1):23–30
Fillie S (2014a) Genesis and paragenesis of the tetravalent Mn ores and Mn-Fe ores in secondary banded iron formations from Nigeria. Proceedings of the 3rd World Conference on Applied Sciences, Engineering and Technology, Kathmandu, Nepal. 318–328
Fillie S (2014b) Chemical mineralogy of supergene ores in Banded Iron Formations from Northern and South-Central Nigeria. Proceedings of the 3rd World Conference on Applied Sciences, Engineering and Technology, Kathmandu, Nepal, 329–339
Goldschmidt VM (1937) The principles of distribution of chemical elements in minerals and rocks. J Chem Soc 1937:655–673
Hein JR, Marjorie SS, Gein LM (1992) Central Pacific cobalt rich ferromanganese crusts. Historical perspective and regional variability. In: Keating BH, Balton BR (eds) Geology and offshore mineral resources of the Central Pacific basin, Circum Pacific Council for Energy and Mineral Resources. Earth Science Series 14. Springer Verlag, New York
Ibrahim HK, Rehab AS (2014) Geochemistry of manganese-iron ores at Um Bogma area, West Central Sinai, Egypt. Int J Adv Sci Tech Res 6(4):258–282
Jensen ML, Bateman AM (1981) Economic mineral deposits, 3rd edn. John Wiley and Sons, US 593p
Krauskopf KB, Bird DK (1995) Introduction to geochemistry, 3rd edn. McGraw-Hill, Boston 646p
Levinson AA (1981) Introduction to exploration geochemistry. Applied Publishing Ltd, Wilmete, USA 613p
Lucilia AR, de Oliveira1, Carlos AR, Francisco JR, Sandra A, de Moraes R (2015) Chemical fingerprint of iron oxides related to iron enrichment of banded iron formation from the Cauê Formation-Esperança Deposit, Quadrilátero Ferrífero, Brazil: a laser ablation ICP-MS study. Braz J Geol 45(2):193–216
McHardy WJ, Thompson AP (1971) Condition for formation of Bayerite and gibbsite. Mineral Mag 38:358–368
Nicholson K (1992) Contrasting mineralogical-geochemical signatures of manganese oxides; guides to metallogenesis. Econ Geol 87:1253–1264
Öksüz N, Okuyucu N (2014) Mineralogy, geochemistry, and origin of Buyukmahal manganese mineralization in the Artova ophiolitic complex, Yozgat, Turkey. J Chem 2014:1–11
Olobaniyi SB (1997) Geological and geochemical studies of the basement rocks and associated iron-formation of Isanlu area in Egbe-Isanlu schist belt, Southwestern Nigeria. Ph.D. Thesis submitted to University, of Ilorin, Ilorin, Nigeria. 240p
Peters T (1988) Geochemistry of manganese-bearing cherts associated with Alpineophiolites and the Hawasina formations in Oman. Mar Geol 84:229–238
Prochaska W (2016) Genetic concepts on the formation of the Austrian magnesite and siderite mineralizations in the Eastern Alps of Austria. Geologia Croatica. https://doi.org/10.4154/gc.2016.03:31-38
Rona PA (1978) Criteria for recognition of hydrothermal mineral deposits in Oceanic crust. Econ Geol 73:135–160
Saad N, Zidan BI, Khalil KI (1994) Geochemistry and origin of the manganese deposits in the Urn Bogma region, west central Sinai, Egypt. J Afr Earth Sci 1911(2):109–116
Siddiquie FN, Burhamuddin K, Shaif M, Alam S (2015) Manganese ore minerals assemblages and mineral paragenesis with the help of ore petrography and XRD studies of Balaghat District, (M.P.) India. Global Journal of Science Frontier Research: Environment & Earth Sci 15(3):21–34
Simmonds V, Ghasemi F (2007) Investigation of manganese mineralization in Idahlu and Jokandy, southwest of Hashtrood, NW Iran. BHM Berg-und Hüttenmännische Monatshefte 152(8):263–267
Toth JR (1980) Deposition of submarine crusts rich in manganese and iron. Geol Soc Am Bull 91:44
Zwicker WK, Groeneveld Meijer WO, Jaffe HW (1962) Nsutite—a widespread manganese oxide mineral. The American Mineralogist 47:246–266
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bamigboye, O.S., Adekeye, J.I.D., Kadioglu, Y.K. et al. Geochemistry and origin of Fe-Mn oxide mineralization in Kaoje-Derena and their environs, northwestern Nigeria. Arab J Geosci 11, 570 (2018). https://doi.org/10.1007/s12517-018-3872-0
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12517-018-3872-0