Abstract
In order to assess the impact of fluoride-rich groundwater of Shasilair Vagu watershed on groundwater regime, more than hundred groundwater samples for pre- and post-monsoon seasons were collected from bore wells/dug wells and analyzed for major ions. Water quality analysis of major ion chemistry shows elevated concentration of fluoride in groundwater samples. The fluoride concentration ranges from 1.4 to 5.9 mg/l and 1.5 to 5.8 mg/l in pre- and post-monsoons, respectively. The result clearly shows that the seasonal variation of fluoride in groundwater is due to recharge of rain water during monsoon. The water quality data was analyzed by hydrochemical facies (Piper diagram), Gibbs plot, and various plots. Plots of Na versus Cl, Ca versus SO4, and (Na+Cl)-(SO4+HCO3) versus (Na+K-Cl) shows positive and negative values, indicating that their source of high concentration are aquifer, evapotranpiration, and other anthropogenic sources. Saturation index of halite and gypsum shows that all groundwater samples were undersaturated and suggests that carbonate minerals influence the concentration. Using multivariate statistical techniques, viz., principal component (factor analysis and cluster analysis), the analysis brought out impact of intensity of excess use of fertilizers and excess withdrawal of groundwater regime. Multivariate statistical techniques are potential tools and provide greater precision for identifying contaminant parameter linkages.
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Abu Rukah Y, Alsokhny K (2004) Geochemical assessment of groundwater contamination with special emphasis on fluoride concentration in North Jordan. Chem Erde 64:171–181
Apambire WM, Boyle DR, Michel FA (1997) Genesis and health implications of fluori-ferous groundwater in the upper regions of Ghana. Environ Geol 35(1):13–24
APHA. American Public Health Association (1995) Standard methods for the examination of water and waste water. 19 th edition. Washington DC
Appelo CAJ, Postma D (1996) Geochemistry, groundwater and pollution. Balkema, Rotterdam, p 536
Ashley RP, Lloyd JW (1978) An example of the use of factor analysis and cluster analysis in groundwater chemistry interpretation. Jour Hydrology 39:355–364
Ayoob S, Gupta AK (2006) Fluoride in drinking water: a review on the status and stress effects. Crit Rev Environ Sci Technol 36(6):433–437
Bengraine K, Marhaba TF (2003) Using principal component analysis to monitor spatial and temporal changes in water quality. Jour Hazardous Mat B100:179–195
BIS (1998) Drinking Water Specifications (revised 2003). Bureau of Indian Standards IS: 10500
Brown E, Skougstad MW, Fishmen MJ (1983) Method for collection and analyzing of water samples for dissolved minerals and gases (p.75). U.S. Govt. Printing Office, Washington DC, USA
Coetsiers M, Walraevens K (2006) Chemical characterization of the Neogene aquifer, Belgium. Hydrogeol J 14:1556–1568
Danielsson A, Cato I, Carman R, Rahm L (1999) Spatial clustering of metals in the sediments of the Skagerrak/Kattegat. Appl Geochem 14:689–706
Davis JC (1986): Statistics and Data Analysis in Geology, 2nd ed., 563–565
Dhakate R, Mahesh J, Sankaran S, Gurunadha Rao VVS (2013) Multivariate statistical analysis for assessment of groundwater quality in Talcher coalfield area, Odisha. Journal of Geological Society of India 82:403–412
Drever JI (1997) The geochemistry of natural waters. Prentice-Hall, New Jersey, p 436
Edmunds WM, Smedley PL (2005) Fluoride in natural waters. In: Selinus O (ed) Essentials of medical geology. Elsevier Academic Press, London, pp 301–329
Farnham I, Smiecinski A, Singh AK (1998) Handling chemical data below detection limits for multivariate analysis of groundwater. First International Conference on Remediationof Chlorinated and Recalcitrant Compounds, Monterey, CA, pp.99–104.
Freeze RA, Cherry JA (1979) Groundwater. Prentice–Hall, Englewod-Cliffs
Gangopadhyay S, Gupta AS, Nachabe MH (2001) Evaluation of groundwater monitoring network by principal component analysis. Ground Water 39(2):181–191
Garrels R, Mackenzie F (1967) Origin of the chemical compositions of some springs and lakes. In: Ground RF (ed) Equilibrium concepts in natural water systems. American Chemical Society Publications, Washington
Genxu W, Guodong C (2001) Fluoride distribution in water and the governing factors of environment in arid north-west China. Journal of the Arid Environment 49:601–614
Gibbs RJ (1970) Mechanisms controlling world’s water chemistry. Science:1089–1090
Grande JA, Gonzalez A, Beltran R, Sanchez-Rodas D (1996) Application of factor analysis to the study of contamination in the aquifer system of Ayamonte-Huelva. Ground Water 34(1):155–161
Guler C, Thyne GD, McCray JE, Turner AK (2002) Evaluation of graphical and multivariate statistical methods for classification of water chemistry data. Hydrogeol J 10:455–474
Jacks G, Bhattacharya P, Choudhary V, Singh KP (2005) Controls on the genesis of some high fluoride ground waters in India. Appl Geochem 20:221–228
Kaiser HF (1960) The application of electronic computers to factor analysis. Educ Psychol Meas 20:141–151. doi:10.1177/001316446002000116
Kim JH, Kim RH, Lee J, Cheong TJ, Yum BW, Chang HW (2005) Multivariate statistical analysis to identify the major factors governing groundwater quality in the coastal area of Kimje, South Korea. Hydrol Process 19:1261–1276
Kim K, Jeong GY (2005) Factors influencing natural occurrence of fluoride-rich ground-waters: a case study in the southeastern part of the Korean Peninsula. Chemosphere 58:1399–1408
Kouping C, Jiu JJ, Jianmin H (2006) Multivariate statistical evaluation of trace elements in groundwater in a coastal area in Shenzhen, China. Environ Pollution 147:771–780
Kundu N, Panigrahi MK, Triparthy S, Munshi S, Powell MA, Hart BR (2001) Geochemical appraisal of fluoride contamination of groundwater in the Nayagarh District of Orissa, India. Environ Geology 41:451–460
Kuppusamy MR, Giridhar V (2006) Factor analysis of water quality characteristics including trace metal speciation in the coastal environment system of Chennai. Environ Internat 32:174–179
Langmuir D (1997) Aqueous environmental geochemistry,” Prentice Hall, Inc., pp. 601
Liu CW, Jang CH, Chen CP, Lin CN, Lou KL (2008) Characterization of groundwater quality in Kinmen Island using multivariate analysis and geochemical modeling. Hydrol Process 22:376–383
Mandel S, Shiftan ZL (1980) Ground water resources investigation and development. Academic Press, New York
Martinez Lopez J, Borrajo JL, De Miguel EG, Arrans JR, Hidalgo Estevez MC, Astillo AJS (2008) Multivariateanalysis of contamination in the mining district of Linares (Jaén, Spain). Appl Geochem 23:2324–2336
Mathew G, Dalton S, Upchurch B (1978) Interpretation of hydrochemical facies by factor analysis. Ground Water 16(4):228–233
May AL, Loucks MD (1995) Solute and isotope geochemistry and groundwater flow in the Central Wasatch Range, Utah. Journal of Hydrobiology 170:795–840
Nordstrom DK, Jenne EA (1977) Fluorite solubility equilibria in selected geothermal waters. Geochimica Cosmochimica Acta 41:175–188
Nura Umar K, Mohammad FR, Wan Nur AS, Shaharin Ibrahim Ahmad ZA, Adamu M (2013) Evaluation of factors influencing the groundwater chemistry in a small tropical island of Malaysia. Int J Environ Res Public Health 10(5):1861–1881. doi:10.3390/ijerph10051861
Pathak H, Limaye SN (2011) Study of seasonal variation in groundwater quality of Sagar City (India) by principal component analysis. E-Journal of Chemistry 8(4):2000–2009
Parinet B, Antoine L, Bernald L (2004) Principal component analysis an Appriate tool for water quality evaluation and management-application to a tropical Lake system. Ecological Modeling 178:295–311
Piper AM (1944) A graphical procedure in the geochemical interpretation of water analysis. Trans Am Geophysical Union 25:914–923
Pophare MA, Dewalkar SM (2007) Groundwater quality in eastern and south eastern parts of Rajura Tehsil, Chendrapur district, Maharashtra, Gondwana Geological Magazine Special, 11:119–129
Raghunath R, Sreedhara Murthy TR, Raghavan BR (2002) The utility of multivariate statistical techniques in hydrogeochemical studies: an example from Karnataka, India. Water Res 36:2437–2442
Ramesham V, Rajagopalan K (1985) Fluoride ingestion into the natural waters of hardrock areas, Peninsular India. J Geol Soc India 26:125–132
Reddy DV, Nagabhushanam P, Sukhija BS, Reddy AGS (2009) Understanding hydrological processes in a highly stressed granitic aquifer in southern India. Hydrol Process 23:1282–1294
Reddy DV, Nagabhushanam P, Sukhija BS, Reddy AGS, Smedley PL (2010) Fluoride dynamics in the granitic aquifer of the Wailapally watershed, Nalgonda District, India. Chem Geol 269(3–4):278–289
Reimann RC, Filzmoser P, Garrett RG, Dutter R (2008) Statistical data analysis explained: applied environmental statistics with John Wiley & Sons, Ltd
Senthilkumar G, Ramanathan AL, Nainwal HC, Chidarribaram S (2008) Evaluation of the hydrogeochemistry of groundwater using factor analysis in the Cuddalore coastal region, TamilNadu, India. Indian Jour Marine Sci 37(2):181–185
Singh KP, Malik A, Mohan D, Sinha S (2004) Multivariate statistical techniques for the evaluation of spatial and temporal variations in water quality of Gomathi River (India)—a case study. Water Res 38:3980–3992
Shaji E, Bindu J, Viju Thambi DS (2007) High fluoride in groundwater of Palghat district, Kerala. Curr Sci 92:240–245
Stallard RF, Edmond JM (1983) Geochemistry of the Amazon, the influence of geology and weathering environment on the dissolved load. Jou Geophy Research 88:9671–9688
Stetzenbach Claus J, Irene MF, Vernon FH, Kevin HJ (1999) Using multivariate statistical analysis of groundwater major cation and trace element concentrations to evaluate groundwater flow in a regional aquifer. Hydrol Process 13:2655–2673
Sundaray SK (2010) Application of multivariate statistical techniques in hydrogeochemical studies—a case study: Bhramhani-Koel River (India). Environment Monitoring Assessment 164:297–310
Szaboles I, Darab C (1964) The influence of irrigation water of high sodium carbonate content of soils. In Proceedings of 8th international congress of ISSS, Trans, II (pp. 803–812)
Todd DK (2001) Groundwater hydrology. John Wiley and Sons Publication, Canada, pp 280–281
Yidana SM, Ophori D, Yakubo BB (2008) A multivariate statistical analysis of surface water chemistry data—the Ankobra Baisn. Ghana Jour Environ Management 86:80–87
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Sudheer Kumar, M., Dhakate, R., Yadagiri, G. et al. Principal component and multivariate statistical approach for evaluation of hydrochemical characterization of fluoride-rich groundwater of Shaslar Vagu watershed, Nalgonda District, India. Arab J Geosci 10, 83 (2017). https://doi.org/10.1007/s12517-017-2863-x
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DOI: https://doi.org/10.1007/s12517-017-2863-x