Abstract
Nowadays, the use of protective products against mosquitoes is growing. The exploration of efficient protective textiles, which can be extensively utilized to save an individual from bacteria, mosquitoes, and UV rays, is highly desired in textile industries. The demand for natural dyed textile substrates is gradually growing due to the increased public awareness about sustainable textiles. Catechu and henna are well-known for their pharmaceutical importance among all-natural dyes. The present study reports the functionalization of cellulosic fiber (cotton) through the azoic dyeing method. To prepare the azoic dyes, diazotized 4-amino N,N-diethyl-meta-toluamide was coupled with the extracts of catechu and henna. The coloration and functional properties (mosquito repellency, antibacterial, and UV protection) of dyed cotton were analyzed. FTIR analysis of azo dyes and TGA of in-situ dyed fabrics were also performed. The dyed fabrics were obtained with 100% mosquito-repellency, more than 87% antibacterial activity, and good to excellent UV protection. The wash-durable, functional effects offered by dyed textile substrates were also confirmed.
Similar content being viewed by others
Data Availability Statement
The research data is provided in the manuscript. No additional data is available.
References
S.S. Nadim, I. Ghosh, M. Martcheva, J. Chattopadhyay, Math. Biosci. 325, 108366 (2020)
S. Afaf Farag, H. Osama, R. Mohamed, H. Mohamed, Mater. Sci. Appl. 2(3), 200 (2011). https://doi.org/10.4236/msa.2011.23025
M.M. Miro Specos, J.J. Garcia, A.C. Gutierrez, L.G. Hermida, J. Text. Inst. 108, 1454 (2017)
A.A. El-Sayed, A. Amr, O.M.H.M. Kamel, M.M.T. El-Saidi, A.E. Abdelhamid, Cellulose 27, 8429 (2020)
N. Singh, J. Sheikh, Cellulose 28, 2599 (2021)
Z. Tariq, F. Izhar, Z. Gmd, A. Zulfiqar, M.H. Malik, M. Oneeb, A. Khan, Ind. Crops Prod. 190, 115878 (2022)
M. Pavan, A. Rani, T. Jhang, S.P. Singh, Mater. Today Proc. 78(Part 4), 900 (2023). https://doi.org/10.1016/j.matpr.2022.12.191
F. Anwar, M. Abbas, M.H. Malik, A.A. Cheema, S. Tariq, W. Afzal, A. Khan, ChemEngineering. 7(4), 64 (2023). https://doi.org/10.3390/chemengineering7040064
A. Al Parvez, M.J. Hossain, M.Z. Hossain, M.S.H. Sohan, F. Hoque, M.H. Ahsan, M.S. Hoque, Heliyon 9, e15944 (2023)
S. Boominathan, G. Magesh, S. Balakrishnan, J. Nat. Fibers 19, 4707 (2022)
M. Degennaro, Fly (Austin) 9, 45 (2015)
B. Fei, J.H. Xin, N. Am. Soc. Trop. Med. Hyg. 77, 52 (2007)
P. Nostro, L. Fratoni, P. Baglioni, J. Incl. Phenom. 44, 423 (2002)
J. Mokhtari, A. Shams-Nateri, P. Ferdosi, Fibers Polym. 15, 1369 (2014)
M.D. Teli, P.P. Chavan, J. Text. Inst. 108, 1 (2016)
M.D. Teli, P.P. Chavan, J. Text. Inst. 108, 1097 (2017)
M.D. Teli, P.P. Chavan, J. Text. Inst. 109, 427 (2018)
A. Singh, J. Sheikh, J. Mol. Struct. 1232, 129988 (2021)
A. Singh, J. Sheikh, Carbohydr. Polym. 290, 119466 (2022)
A. Singh, J. Sheikh, Arab. J. Chem. 15, 104339 (2022)
A. Umar, ChemSearch J. 11, 126 (2020)
A. Nazari, J. Text. Inst. 108, 755 (2017)
A. Davulcu, H. Benli, Y. Şen, M.İ Bahtiyari, Cellulose 21, 4671 (2014)
M. Gorjanc, A. Savić, L. Topalić-Trivunović, M. Mozetič, R. Zaplotnik, A. Vesel, D. Grujić, Cellulose 23, 2221 (2016)
K.H. Hong, J.H. Bae, S.R. Jin, J.S. Yang, Cellulose 19, 507 (2012)
S. Baseri, Cellulose 5, 10407 (2020)
Y. Zhang, Q. Zhou, L.J. Rather, Q. Li, Ind. Crops Prod. 169, 113633 (2021)
N. Kandasamy, K. Kaliappan, T. Palanisamy, Ind. Crops Prod. 171, 113969 (2021)
X. Yan, L. Hong, S. Pei, A. Hamilton, H. Sun, R. Yang, A. Liu, L. Yang, Ind. Crops Prod. 171, 113968 (2021)
K. Amutha, S. Grace Annapoorani, N. Sudhapriya, Ind. Crops Prod. 148, 112303 (2020)
O. Akaranta, D.E. Efanga, J. Natl. Sci. Counc. Sri Lanka 25, 121 (1997)
A.B. Pawar, S.P. More, R.V. Adivarekar, Nat. Prod. Bioprospect. 8, 23 (2018)
A. Singh, J. Sheikh, J. Nat. Fibers 19, 14 (2021)
R. Yadav, Anubhav, P. Mathur, J. Sheikh, Cellul. Chem. Technol. 53, 357 (2019)
R. Pradhan, P. Dandawate, A. Vyas, S. Padhye, B. Biersack, R. Schobert, A. Ahmad, F.H. Sarkar, Curr. Drug Targ. 13, 1777 (2012)
O. Kamal Alebeid, T. Zhao, A.I. Seedahmed, Fibers Polym. 16, 1303 (2015)
N.A. Udeani, Int. J. Chem. Mol. Eng. 9, 1459 (2015)
O.K. Alebeid, T.A.O. Zhao, Int. J. Adv. Sci. Eng. Technol. 5, 19 (2016)
M.A. Rahman Bhuiyan, A. Ali, A. Islam, M.A. Hannan, S.M. Fijul Kabir, M.N. Islam, Fash. Text. 5, 2 (2018)
O.K. Alebeid, L. Pei, W. Zhou, J. Wang, Environ. Chem. Lett. 18, 489 (2020)
S. Ali, T. Hussain, R. Nawaz, J. Clean. Prod. 17, 61 (2009)
M.A.R. Bhuiyan, A. Islam, S. Islam, A. Hossain, K. Nahar, Text. Cloth. Sustain. 3, 1 (2017)
S. M’Garrech, F. Ncib, Appl. Radiat. Isot. 67, 2003 (2009)
M.S. Amudhan, V.H. Begum, K.B. Hebbar, Int. J. Pharm. Sci. Res. 3, 4151 (2012)
S.D. Bhattacharya, A.K. Shah, J. Soc. Dye. Colour. 116, 10 (2000)
X. Hou, L. Wei, X. Zhang, H. Wu, Q. Zhou, S. Yuan Wang, Res. J. Text. Appar. 12, 32 (2008)
P.S. Vankar, R. Shanker, Desalination 230, 62 (2008)
M.D. Teli, J. Sheikh, P. Shastrakar, J. Text. Sci. Eng. 4(2), 1 (2014)
ISO manual 2006. ISO Technical manual, Geneva, Switerzland (2006)
AATCC Technical Manual 2007 (Association of Textile Chemists and Colorists (AATCC), Research Triangle Park, NC, USA, 2007)
AS/NZS 4399:1996, Sun protective clothing—evaluation and Classification (Standards Australia, Sydney and Standards, New Zealand, Wellington, 1996)
M. Xenikaki, M. Tsanakopoulou, M. Chatzistefanou, D. Hadjipavlou-Litina, Tetrahedron 71, 5650 (2015)
M. Sonawane, S.K. Sahoo, J. Singh, N. Singh, C.P. Sawant, A. Kuwar, Inorg. Chim. Acta 438, 37 (2015)
F.A. Bernal, L.L. Orduz-Diaz, C. Guerrero-Perilla, E.D. Coy-Barrera, Food Anal. Methods 9, 411 (2016)
K.K. Al-rubiay, N.N. Jaber, L.K. Alrubaiy, Oman Med. J. 23(4), 253 (2008)
S. Kalayci, S. Demirci, F. Sahin, World J. Microbiol. Biotechnol. 30, 407 (2014)
B.S. Negi, B.P. Dave, Indian J. Microbiol. 50, 369 (2010)
Acknowledgements
Authors gratefully acknowledge Central Research Facility (CRF) of IIT Delhi (India) for providing characterization facilities.
Author information
Authors and Affiliations
Contributions
AS: Conceptualization; methodology; investigation; writing—original draft. JS: Supervision; project administration; validation; visualization; writing—review and editing.
Corresponding author
Ethics declarations
Conflict of interest
There are no conflicts to declare.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Singh, A., Sheikh, J. Valorization of Henna and Catechu Natural Dye in Preparation of Mosquito-Repellent Multifunctional Cotton. Fibers Polym 25, 211–219 (2024). https://doi.org/10.1007/s12221-023-00425-z
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-023-00425-z