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In Situ Mineralization of Akageneite (β-FeOOH) on Cotton for Water Purification via Fenton-Like Reaction

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Abstract

Immobilization of photocatalysts on supported materials is the key to achieving the efficiency and stability for wastewater treatment. However, developing high dispersion photocatalysts with high stability and durability is still a great challenge in practical application. Hence, this work reports a facile synthesis for inorganic–organic compound semiconductor nanomaterials using natural cotton substrates and in situ mineralization of β-FeOOH nanorods. In this strategy, abundant hydroxyl groups on cotton fibers as an intermediate bridge anchor Fe3+ for mineralization of β-FeOOH nanorods, forming strong coordination complexes. This resultant fabric, labeled as Cot-FeOOH, has been shown that the mineralized β-FeOOH nanorods covered the cotton fabric perfectly. The Cot-FeOOH displayed efficient photocatalytic activity for antibiotics and dye under visible light irradiation in the presence of hydrogen peroxide (H2O2). Moreover, the stability and durability of Cot-FeOOH were evaluated by multiple recycles and laundering durability tests, demonstrating the satisfactory performance of stability and durability. Our study offers a simple and easy strategy to decorate conventional cotton for versatile applications in environmental remediation.

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References

  1. E. Jafari Ozumchelouei, A.H. Hamidian, Y. Zhang, M. Yang, Water Environ. Res. 92, 177 (2020)

    CAS  PubMed  Google Scholar 

  2. L. Xu, H. Zhang, P. Xiong, Q. Zhu, C. Liao, G. Jiang, Sci. Total Environ. 753, 141975 (2021)

    CAS  PubMed  Google Scholar 

  3. X. Lou, Z. Liu, C. Fang, Y. Tang, J. Guan, Y. Guo, X. Zhang, Y. Shi, D. Huang, Y. Cai, Environ. Res. 204, 111958 (2022)

    CAS  PubMed  Google Scholar 

  4. X. Chen, Y. Yang, Y. Ke, C. Chen, S. Xie, Sci. Total Environ. 814, 152852 (2022)

    CAS  PubMed  Google Scholar 

  5. I.O. Saheed, W.D. Oh, F.B.M. Suah, J. Hazard Mater. 408, 124889 (2021)

    CAS  PubMed  Google Scholar 

  6. Q.N. Ho, M. Fettweis, K.L. Spencer, B.J. Lee, Water Res. 213, 118147 (2022)

    CAS  PubMed  Google Scholar 

  7. S. Feijoo, M. Kamali, Q.-K. Pham, A. Assoumani, F. Lestremau, D. Cabooter, R. Dewil, Chem. Eng. J. 446, 137114 (2022)

    CAS  Google Scholar 

  8. C. Ling, X. Liu, H. Li, X. Wang, H. Gu, K. Wei, M. Li, Y. Shi, H. Ben, G. Zhan, C. Liang, W. Shen, Y. Li, J. Zhao, L. Zhang, Angew. Chem. Int. Ed. Engl. 61, e202200670 (2022)

    CAS  PubMed  Google Scholar 

  9. B. Song, Z. Zeng, E. Almatrafi, M. Shen, W. Xiong, C. Zhou, W. Wang, G. Zeng, J. Gong, Water. Res. 211, 118048 (2022)

    CAS  PubMed  Google Scholar 

  10. L. Liu, S.Y. Lim, C.S. Law, B. Jin, A.D. Abell, G. Ni, A. Santos, ACS Appl. Mater. Interfaces 12, 57079 (2020)

    CAS  PubMed  Google Scholar 

  11. A. Meng, L. Zhang, B. Cheng, J. Yu, Adv Mater 31, e1807660 (2019)

    PubMed  Google Scholar 

  12. W. Jiao, L. Zhang, R. Yang, J. Ning, L. Xiao, Y. Liu, J. Ma, N. Mahmood, X. Jian, Appl. Mater. Today 27, 101498 (2022)

    Google Scholar 

  13. H. Yang, F. Zheng, F. Liu, L. Lin, X. Huang, Y. Lin, S. Li, J. Phys. Chem. C 125, 23729 (2021)

    CAS  Google Scholar 

  14. Y. Yin, L. Shi, W. Li, X. Li, H. Wu, Z. Ao, W. Tian, S. Liu, S. Wang, H. Sun, Environ. Sci. Technol. 53, 11391 (2019)

    CAS  PubMed  Google Scholar 

  15. Y. Wang, Y. He, J. Yu, L. Zhang, S. Li, H. Li, Sep. Purif. Technol. 287, 120569 (2022)

    CAS  Google Scholar 

  16. X. Bao, Q. Liu, J. Yang, F. Wang, F. Yu, J. Yu, Y. Yang, J Membrane Sci 660, 120866 (2022)

    CAS  Google Scholar 

  17. X. Hou, X. Huang, F. Jia, Z. Ai, J. Zhao, L. Zhang, Environ. Sci. Technol. 51, 5118 (2017)

    CAS  PubMed  Google Scholar 

  18. C. Zhang, H.C. Yang, L.S. Wan, H.Q. Liang, H. Li, Z.K. Xu, ACS Appl. Mater. Interfaces 7, 11567 (2015)

    CAS  PubMed  Google Scholar 

  19. N. Liu, R. Qu, Y. Chen, Y. Cao, W. Zhang, X. Lin, Y. Wei, L. Feng, L. Jiang, Nanoscale 8, 18558 (2016)

    CAS  PubMed  Google Scholar 

  20. Y. Lv, C. Zhang, A. He, S.J. Yang, G.P. Wu, S.B. Darling, Z.K. Xu, Adv. Funct. Mater. 27, 1700251 (2017)

    Google Scholar 

  21. H. Lan, A. Wang, R. Liu, H. Liu, J. Qu, J Hazard Mater 285, 167 (2015)

    CAS  PubMed  Google Scholar 

  22. Y. Wang, T. Yang, J. Chen, S. Wen, D. Li, B. Wang, Q. Zhang, Sep. Purif. Technol. 298, 121557 (2022)

    CAS  Google Scholar 

  23. M. Tahir, A. Raza, A. Nasir, T. Yasin, Radiat. Phys. Chem. 179, 109259 (2021)

    CAS  Google Scholar 

  24. M.J.P. Macedo, G.S. Silva, M.C. Feitor, T.H.C. Costa, E.N. Ito, J.D.D. Melo, J Mater. Res. Technol. 9, 2467 (2020)

    CAS  Google Scholar 

  25. N. Koutroumanis, A.C. Manikas, P.N. Pappas, F. Petropoulos, L. Sygellou, D. Tasis, K. Papagelis, G. Anagnostopoulos, C. Galiotis, Compos. Sci. Technol. 157, 178 (2018)

    CAS  Google Scholar 

  26. I. Ahmad, C.W. Kan, Z. Yao, RSC Adv. 9, 18106 (2019)

    CAS  PubMed  PubMed Central  Google Scholar 

  27. K. Panwar, M. Jassal, A.K. Agrawal, Cellulose 25, 2711 (2018)

    CAS  Google Scholar 

  28. H. Yang, Q. Zhang, Y. Chen, Y. Huang, F. Yang, Z. Lu, Carbohyd. Polym. 201, 162 (2018)

    CAS  Google Scholar 

  29. Y. Wang, X. Ding, P. Zhang, Q. Wang, K. Zheng, L. Chen, J. Ding, X. Tian, X. Zhang, Ind. Eng. Chem. Res. 58, 3978 (2019)

    CAS  Google Scholar 

  30. J. Manna, S. Goswami, N. Shilpa, N. Sahu, R.K. Rana, ACS Appl. Mater. Interfaces 7, 8076 (2015)

    CAS  PubMed  Google Scholar 

  31. Y. Mi, D. Wu, Y. Li, X. Cheng, X. Yang, S. Lan, Z. Cao, Fiber Polym 23, 1284 (2022)

    CAS  Google Scholar 

  32. Y. Yang, H. Chen, R. Zhang, J. Huang, Z. Bai, and S. Xiao, Fiber Polym, (2022).

  33. D. Pang, C.C. Wang, P. Wang, W. Liu, H. Fu, C. Zhao, Chemosphere 254, 126829 (2020)

    CAS  PubMed  Google Scholar 

  34. M. Wang, Z. Xu, Y. Hou, P. Li, H. Sun, Q.J. Niu, Sep. Purif. Technol. 249, 117159 (2020)

    CAS  Google Scholar 

  35. C. Lyu, D. He, Z. Mou, X. Yang, Sci Total Environ 693, 133589 (2019)

    PubMed  Google Scholar 

  36. V.G. Chandrashekhar, T. Senthamarai, R.G. Kadam, O. Malina, J. Kašlík, R. Zbořil, M.B. Gawande, R.V. Jagadeesh, M. Beller, Nat. Catal. 5, 20 (2021)

    Google Scholar 

  37. A. Xie, J. Cui, J. Yang, Y. Chen, J. Dai, J. Lang, C. Li, Y. Yan, J. Mater. Chem. A 7, 8491 (2019)

    CAS  Google Scholar 

  38. H. Lin, Q. Fang, W. Wang, G. Li, J. Guan, Y. Shen, J. Ye, F. Liu, Appl. Catal. B Environ. 273, 119047 (2020)

    CAS  Google Scholar 

  39. B. Yang, C. Wang, X. Cheng, Y. Zhang, W. Li, J. Wang, Z. Tian, W. Chu, G.V. Korshin, H. Guo, Water Res. 202, 117379 (2021)

    CAS  PubMed  Google Scholar 

  40. Y. Yin, W. Li, C. Xu, L. Shi, L.-C. Zhang, Z. Ao, M. Liu, M. Lu, X. Duan, S. Wang, S. Liu, H. Sun, Environ. Sci. Nano 7, 2595 (2020)

    CAS  Google Scholar 

  41. C. Liu, H. Dai, C. Tan, Q. Pan, F. Hu, X. Peng, Appl. Catal. B Environ. 310, 121326 (2022)

    CAS  Google Scholar 

  42. X. Tian, T. Luo, Y. Nie, J. Shi, Y. Tian, D.D. Dionysiou, Y. Wang, Environ. Sci. Technol. 56, 5542 (2022)

    CAS  PubMed  Google Scholar 

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Acknowledgements

We greatly appreciate supports from the Sino-Swiss Science and Technology Cooperation program with ETH Zurich, and State Key Laboratory of NBC Protection for Civilian (Grant No. 21976089).

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Correspondence to Jiangtao Hu or Minglei Wang.

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Jiang, J., Liang, Y., Wang, H. et al. In Situ Mineralization of Akageneite (β-FeOOH) on Cotton for Water Purification via Fenton-Like Reaction. Fibers Polym 24, 1641–1648 (2023). https://doi.org/10.1007/s12221-023-00154-3

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