Skip to main content
Log in

Electrospun Spandex Nanofiber Webs with Ionic Liquid for Highly Sensitive, Low Hysteresis Piezocapacitive Sensor

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

Electrospun Spandex nanofiber webs having very high amount of nano-sized open cell can be used as a piezocapacitive sensor for monitoring both static and dynamic pressures due to excellent electrospinnability and very good elastic properties. Compared to our previously reported SBS and TPU electrospun nanoweb, Spandex showed relatively linear increase of capacitance with applied pressure and restored its initial thickness when the pressure was released due to the improved resilience and elasticity. Moreover, small amount of ionic liquid (IL) was added in Spandex dope solution to increase the sensitivity of sensor to pressure, which induced very large amount of capacitance change with pressure, as well as reducing the capacitance-pressure hysteresis. In this work, hysteresis of the sensor was assessed through measuring the capacitance values during 20 cyclic loading and unloading and was improved significantly from 7.5 % to 1.8 %. Creep and stress relaxation behaviors were also tested through measuring capacitance under the constant loading and loading under the constant capacitance as a function of time respectively, using a dynamic pressure tester and an LCR meter. The results are reported in detail.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C. Li, P.-M. Wu, S. Lee, A. Gorton, M. J. Schulz, and C. H. Ahn, J. Microelectromechan. Syst., 17, 334 (2008).

    Article  CAS  Google Scholar 

  2. G. Cannata, M. Maggiali, G. Metta, and G. Sandini, In Proceedings of IEEE Intl. Conf. on Multisensor Fusion and Integration for Intelligent Syst., Seoul, Korea, 434–438, Aug. 20–22, 2008.

    Google Scholar 

  3. A. Zribi and J. Fortin, “Functional Thin Films and Nanostructures for Sensors: Synthesis, Physics and Application”, Ch.2, pp.978–387, Springer, 2009.

    Book  Google Scholar 

  4. M. N. H. Nishiyama, IEEE Trans., 17, 477 (1994).

    Google Scholar 

  5. F. He, Q.-A. Huang, and M. Qin, Sens. Actuators, A, 135, 507 (2007).

    Article  CAS  Google Scholar 

  6. M. Jian, C. Wang, Q. Wang, H. Wang, K. Xia, Z. Yin, M. Zhang, X. Liang, and Y. Zhang, Sci. China Mater., 57, 1 (2017).

    Google Scholar 

  7. Y. J. Jeong, T. I. Oh, E. J. Woo, and K. J. Kim, “Integration of Piezo-capacitive and Piezo-electric Nanoweb Based Pressure Sensors for Imaging of Static and Dynamic Pressure Distribution”, 2017 39th Annual Intl. Conf. of the IEEE Engineering in Medicine and Biology Society (EMBC), pp.21–24, Seogwipo, Jeju, South Korea, Jul. 11–15, 2017.

    Google Scholar 

  8. B. Nie, R. Li, J. D. Brandt, and T. Pan, Lab Chip, 14, 1107 (2014).

    Article  CAS  PubMed  Google Scholar 

  9. T.-H.-N. Dinh, E. Martincic, E. Dufour-Gergam, and P.-Y. Joubert, J. Sensors, 2017, Article ID 8235729 (2017).

    Google Scholar 

  10. K. J. Kim, Y. J. Ahn, S. Y. Lee, and S. Yoon, 2nd Intl. Conf. on Electrospinning-2012, 70, Jeju, Korea, May 29-June 1, 2012.

    Google Scholar 

  11. T. H. N. Dinh, P.-Y. Joubert, E. Martincic, and E. Dufour-Gergam, Sensors, 2014 IEEE, pp.855–858, Valencia, Spain, Nov. 2–5, 2014.

    Book  Google Scholar 

  12. M.-Q. Liu, C. Wang, and N.-Y. Kim, Sensors, 17, 284 (2017).

    Article  CAS  Google Scholar 

  13. T. Senthil, G. George, and A. Srinivasan in “Advances in Polymer Materials and Technology”, 1st ed. (A. Srinivasan and S. Bandyopadhyay Eds.), Ch.5, pp.149–218, CRC Press, 2016.

  14. P. Sathiyanathan, A. A. Prabu, and K. J. Kim, Macromol. Res., 24, 670 (2016).

    Article  CAS  Google Scholar 

  15. Y. R. Wang, J. M. Zheng, G. Y. Ren, P. H. Zhang, and C. Xu, Smart Mater. Struct., 20, 7 (2011).

    CAS  Google Scholar 

  16. E. H. Kim and J. H. Kim, Text. Sci. Eng., 53, 75 (2016).

    Article  CAS  Google Scholar 

  17. S. B. Kim, S. Y. Lee, and H. S. Kim, Text. Sci. Eng., 53, 97 (2016).

    Article  Google Scholar 

  18. M. H. Kim, H. C. Kim, and W. H. Park, Text. Sci. Eng., 54, 97 (2017).

    Google Scholar 

  19. H. Zhuo, J. Hu, S. Chen, and L. Yeung, J. Appl. Polym. Sci., 109, 406 (2008).

    Article  CAS  Google Scholar 

  20. R. Iani, M. Kotaki, and S. Ramakrishna, Nanotechnology, 16, 208 (2005).

    Article  CAS  Google Scholar 

  21. Z. M. Huang, Y. Z. Zhang, M. Kotaki, and S. Ramakrishna, Compos. Sci. Technol., 63, 2223 (2003).

    Article  CAS  Google Scholar 

  22. H. J. Qi and M. C. Boyee, Mech. Mater., 37, 23 (2005).

    Article  Google Scholar 

  23. S. Lee, Y. Ahn, A. A. Prabu, and K. J. Kim, J. Fiber Bioeng. Inform., 6, 369 (2013).

    Article  Google Scholar 

  24. S. Lambour, F. Mechin, and J. P. Pascault, Polym. Eng. Sci., 42, 68 (2002).

    Article  CAS  Google Scholar 

  25. R. T. Selvan, M. K. Yoo, S. K. Hong, H. Kim, K. J. Kim, “2016 Fall Joint Meeting of Korea Fiber Society and the Korean Society of Dyers and Finishers”, p.147, BEXCO, Busan, Korea, Nov. 3–4, 2016.

    Google Scholar 

  26. A. Sahnoune, “Forming and Applications of Thermoplastic Vulcanizates”, The 5th Intl. Conf. on New Opportunities for Thermoplastic Elastomers (TPE 2002), p.141, Brussels, Belgium, June 24–25, 2002.

    Google Scholar 

  27. H. J. Kim and H. G. Jeon, Patent Application Publication, US, 0187348 A1, Jul. 3, 2014.

    Google Scholar 

  28. C. Hepburn Ed., “Polyurethane Elastomers”, 2nd ed., Chap.1, pp.1–27, Elsevier Appled Science, 2012.

  29. J. Bai, H. Li, Z. Shi, M. Tian, and J. Yin, J. RSC Adv., 5, 45376 (2015).

    Article  CAS  Google Scholar 

  30. M. S. Reza, M. K. Yoo, H. Kim, and K. J. Kim, Intl. Conf. on Adv. Polym. for Sci. and Technol. (APST-2016), p.49, Vellore, India, Oct. 24–26, 2016.

    Google Scholar 

  31. M. S. Reza, M. K. Yoo, K. J. Kim, and H. Kim, 2017 Spring Conference of Korea Fiber Society, p.170, Daejeon, Korea, Apr. 27–28, 2017.

  32. E. S. Guerra and E. V. Lima, “Handbook of Polymer Synthesis, Characterization, and Processing”, John Wiley & Sons Inc., Hoboken, New Jersey, USA, 2013.

    Book  Google Scholar 

  33. P. K. Behera, K. M. Usha, P. K. Guchhait, D. Jehnichen, A. Das, B. Voit, and N. K. Singha, RCS Adv., 6, 99404 (2016).

    CAS  Google Scholar 

  34. M. L. Jin, S. Park, Y. Lee, J. H. Lee, J. Chung, J. S. Kim, J.-S. Kim, S. Y. Kim, E. Jee, D. W. Kim, J. W. Chung, S. G. Lee, D. Choi, H.-T. Jung, and D. H. Kim, Adv. Mater., 29, 1605973 (2017).

    Article  CAS  Google Scholar 

  35. S. Y. Kim, E. Jee, J. S. Kim, and D. H. Kim, RSC Adv., 7, 23820 (2017).

    Article  Google Scholar 

  36. H. Zhou, H. Wang, H. Niu, and T. Lin, Sci. Rep., 5, 15683 (2015).

    Article  CAS  Google Scholar 

  37. A. G. Chakespari, A. Rajabipour, and Mobi, Adv. J. Food Sci. Technol., 2, 200 (2010).

    Google Scholar 

  38. E. Rainde, R. Diaz-Callejo, M. G. Prolongo, R. M. Masegosa, and C. Salom, “Polymer Viscoelasticity”, p.392, CRC Press, 1999.

    Book  Google Scholar 

  39. American Fiber Manufacturers Association, Inc., Spandex (Alternatively Elastane).

  40. P. Lunkenheimer, V. Bobnar, A. V. Pronin, A. I. Ritus, A. A. Volkov, and A. Loidl, Phys. Rev. B, 66, 052105 (2002).

    Article  CAS  Google Scholar 

  41. E. Thoms, P. Sippel, D. Reuter, M. Weiß, A. Loidl, and S. Krohns, Sci. Rep., 7, 7463 (2017).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Kap Jin Kim or Hongdoo Kim.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Reza, M.S., Ayag, K.R., Yoo, M.K. et al. Electrospun Spandex Nanofiber Webs with Ionic Liquid for Highly Sensitive, Low Hysteresis Piezocapacitive Sensor. Fibers Polym 20, 337–347 (2019). https://doi.org/10.1007/s12221-019-8778-2

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-019-8778-2

Keywords

Navigation